Issue 14, 2020

Temperature stable Li2Ti0.75(Mg1/3Nb2/3)0.25O3-based microwave dielectric ceramics with low sintering temperature and ultra-low dielectric loss for dielectric resonator antenna applications

Abstract

Microwave dielectric ceramics are considered to be one of the key materials of dielectric resonators/filters and have wide application prospects in fifth generation (5G) mobile communication systems. Here we prepared two kinds of low-sintering temperature and high-performance microwave dielectric ceramics with monoclinic rock salt structure by adding a small amount of V2O5 and 0.6CuO–0.4B2O3 sintering aids to Li2Ti0.75(Mg1/3Nb2/3)0.25O3 (LTMN0.25). The sintering temperature of LTMN0.25 ceramics with 2 wt% V2O5 and 1 wt% 0.6CuO–0.4B2O3 additions could be effectively reduced from 1170 °C to below 910 °C due to the liquid phase effects resulting from the additives. Typically, high performance microwave dielectric properties can be obtained in the LTMN0.25 + 2 wt% V2O5 ceramic sintered at 910 °C for 2 h, with a εr ∼ 20.7, a Q × f ∼ 60 460 GHz and a TCF ∼ +4.3 ppm °C−1. The best dielectric properties of εr ∼ 19.9, a Q × f ∼ 60 950 GHz and a TCF ∼ −6.1 ppm °C−1 were obtained for the samples with 1 wt% 0.6CuO–0.4B2O3 sintered at 870 °C for 2 h. A prototype dielectric resonator antenna (DRA) was fabricated by LTMN0.25 + 1 wt% 0.6CuO–0.4B2O3 ceramic. The antenna resonated at 10.02 GHz with a bandwidth ∼175 MHz at −10 dB transmission loss (S11). Moreover, the chemical compatibility with Ag powder suggests that the LTMN0.25 + 2 wt% V2O5 and LTMN0.25 + 1 wt% 0.6CuO–0.4B2O3 ceramics may be suitable candidates for low temperature co-fired ceramic technology applications.

Graphical abstract: Temperature stable Li2Ti0.75(Mg1/3Nb2/3)0.25O3-based microwave dielectric ceramics with low sintering temperature and ultra-low dielectric loss for dielectric resonator antenna applications

Article information

Article type
Paper
Submitted
17 जनवरी 2020
Accepted
17 फरवरी 2020
First published
18 फरवरी 2020

J. Mater. Chem. C, 2020,8, 4690-4700

Temperature stable Li2Ti0.75(Mg1/3Nb2/3)0.25O3-based microwave dielectric ceramics with low sintering temperature and ultra-low dielectric loss for dielectric resonator antenna applications

H. Guo, D. Zhou, C. Du, P. Wang, W. Liu, L. Pang, Q. Wang, J. Su, C. Singh and S. Trukhanov, J. Mater. Chem. C, 2020, 8, 4690 DOI: 10.1039/D0TC00326C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements