Issue 37, 2016

On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

Abstract

While β-diketiminate (BDI or ‘nacnac’) ligands have been widely adopted to stabilize a wide range of metal ions in multiple oxidation states and coordination numbers, in several occurrences these ligands do not behave as spectators and participate in reactivity. Besides unwanted decomposition processes, BDI redox non-innnocence and unusual metal–ligand cooperative activation of substrates yielding attractive reactivity have been reported. This feature article will provide a comprehensive analysis of the various transformations involving BDI ligand platforms in coordination compounds across the periodic table.

Graphical abstract: On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

Article information

Article type
Perspective
Submitted
19 मई 2016
Accepted
23 जून 2016
First published
29 जून 2016

Dalton Trans., 2016,45, 14462-14498

On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

C. Camp and J. Arnold, Dalton Trans., 2016, 45, 14462 DOI: 10.1039/C6DT02013E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements