Issue 74, 2024

Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

Abstract

A novel photocatalytic cascade has been engineered for the transformation of diketimines into 1,3-dinitrogen heterocycles, ingeniously repurposing methylamine a typically utilized sacrificial additive as a dual-function reagent, serving simultaneously as an electron donor and a methyl source. This innovation champions atom economy and underscores a commitment to sustainable chemical synthesis.

Graphical abstract: Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

Supplementary files

Article information

Article type
Communication
Submitted
22 जुलाई 2024
Accepted
21 अगस्त 2024
First published
22 अगस्त 2024

Chem. Commun., 2024,60, 10164-10167

Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

F. Guo, J. Zhu and X. Fan, Chem. Commun., 2024, 60, 10164 DOI: 10.1039/D4CC03666B

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