Issue 30, 2020

New reflections on hard X-ray photon-in/photon-out spectroscopy

Abstract

Analysis of the electronic structure and local coordination of an element is an important aspect in the study of the chemical and physical properties of materials. This is particularly relevant at the nanoscale where new phases of matter may emerge below a critical size. X-ray emission spectroscopy (XES) at synchrotron radiation sources and free electron lasers has enriched the field of X-ray spectroscopy. The spectroscopic techniques derived from the combination of X-ray absorption and emission spectroscopy (XAS–XES), such as resonant inelastic X-ray scattering (RIXS) and high energy resolution fluorescence detected (HERFD) XAS, are an ideal tool for the study of nanomaterials. New installations and beamline upgrades now often include wavelength dispersive instruments for the analysis of the emitted X-rays. With the growing use of XAS–XES, scientists are learning about the possibilities and pitfalls. We discuss some experimental aspects, assess the feasibility of measuring weak fluorescence lines in dilute, radiation sensitive samples, and present new experimental approaches for studying magnetic properties of colloidal nanoparticles directly in the liquid phase.

Graphical abstract: New reflections on hard X-ray photon-in/photon-out spectroscopy

Article information

Article type
Paper
Submitted
10 मार्च 2020
Accepted
10 जुलाई 2020
First published
17 जुलाई 2020

Nanoscale, 2020,12, 16270-16284

Author version available

New reflections on hard X-ray photon-in/photon-out spectroscopy

S. Lafuerza, M. Retegan, B. Detlefs, R. Chatterjee, V. Yachandra, J. Yano and P. Glatzel, Nanoscale, 2020, 12, 16270 DOI: 10.1039/D0NR01983F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements