Issue 48, 2020

Quinoline- and isoquinoline-derived ligand design on TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) platform for fluorescent sensing of specific metal ions and phosphate species

Abstract

Rational molecular structure alterations of TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) produced variable fluorescent sensors for specific metal ions and phosphate species. Utilization of methoxy-substituted quinoline and isoquinoline chromophores, conformational restriction and multidentate coordination structure allow discrimination between Zn2+ and Cd2+. Pyrophosphate (P2O74−, PPi) and phosphate (PO43−) also are selectively detected with dinuclear Zn2+ complexes of tetrakisquinoline-based ligands. Differential stability and structure of the metal complexes, as well as resulting fluorescence enhancement mechanism, such as intramolecular excimer formation via change in coordination geometry, play key roles in the discrimination of target ions.

Graphical abstract: Quinoline- and isoquinoline-derived ligand design on TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) platform for fluorescent sensing of specific metal ions and phosphate species

Article information

Article type
Frontier
Submitted
29 अगस्त 2020
Accepted
09 अक्तूबर 2020
First published
12 अक्तूबर 2020

Dalton Trans., 2020,49, 17494-17504

Quinoline- and isoquinoline-derived ligand design on TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) platform for fluorescent sensing of specific metal ions and phosphate species

Y. Mikata, Dalton Trans., 2020, 49, 17494 DOI: 10.1039/D0DT03024D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements