Issue 36, 2019

How flexible is the disulfide linker? A combined rotational–computational investigation of diallyl disulfide

Abstract

The symmetrically substituted diallyl disulfide adopts a non-symmetric conformation in the gas-phase, as observed with supersonic-jet rotational spectroscopy. The determination of the equilibrium structure with a predicate mixed regression illustrates both the benefits of the mass-dependent method for moderately large molecules and the structural peculiarities of the disulfide bridge.

Graphical abstract: How flexible is the disulfide linker? A combined rotational–computational investigation of diallyl disulfide

Supplementary files

Article information

Article type
Communication
Submitted
03 मई 2019
Accepted
03 जून 2019
First published
03 जून 2019

Phys. Chem. Chem. Phys., 2019,21, 19732-19736

How flexible is the disulfide linker? A combined rotational–computational investigation of diallyl disulfide

J. Demaison, N. Vogt, R. T. Saragi, M. Juanes, H. D. Rudolph and A. Lesarri, Phys. Chem. Chem. Phys., 2019, 21, 19732 DOI: 10.1039/C9CP02508A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements