Issue 9, 2018

Surface ligand modification of cesium lead bromide nanocrystals for improved light-emitting performance

Abstract

Cesium lead halide perovskite nanocrystals (NCs) possess excellent optical properties at visible wavelengths with great promise for applications in luminous display fields. We demonstrate a method to modify the surface ligand passivation of perovskite NCs for enhanced colloidal stability and emitting properties by incorporating didodecyl dimethyl ammonium bromide (DDAB). The photoluminescence quantum yield of the NC solution was improved to 96% from 70% and the perovskite film showed fewer trapped sites and enhanced carrier transport ability. The thus fabricated electroluminescent perovskite NC-LEDs exhibited a bright luminance of 11 990 cd m−2, corresponding to 4-times improved external quantum efficiency (EQE), compared to the control device using regular NCs without DDAB.

Graphical abstract: Surface ligand modification of cesium lead bromide nanocrystals for improved light-emitting performance

Supplementary files

Article information

Article type
Communication
Submitted
08 दिसम्बर 2017
Accepted
24 जनवरी 2018
First published
25 जनवरी 2018

Nanoscale, 2018,10, 4173-4178

Surface ligand modification of cesium lead bromide nanocrystals for improved light-emitting performance

H. Wu, Y. Zhang, M. Lu, X. Zhang, C. Sun, T. Zhang, V. L. Colvin and W. W. Yu, Nanoscale, 2018, 10, 4173 DOI: 10.1039/C7NR09126E

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