A more sustainable and efficient access to IMes·HCl and IPr·HCl by ball-milling

Audrey Beillard; Xavier Bantreil; Thomas-Xavier Métro; Jean Martinez; Frédéric Lamaty

doi:10.1039/C7GC03539J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A more sustainable and efficient access to IMes·HCl and IPr·HCl by ball-milling†

Audrey Beillard,^a Xavier Bantreil,

*^a Thomas-Xavier Métro,

*^a Jean Martinez

^a and Frédéric Lamaty

*^a

Author affiliations

* Corresponding authors

^a Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS, Université de Montpellier, ENSCM, Campus Triolet, Place Eugène Bataillon, 34095 Montpellier cedex 5, France
E-mail: xavier.bantreil@umontpellier.fr, thomas-xavier.metro@umontpellier.fr, frederic.lamaty@umontpellier.fr

Abstract

Herein is described a mechanochemical one-pot two-step procedure giving access to various NHC (N-heterocyclic carbene) precursors. This original approach enabled the production of the widely used IPr·HCl, IMes·HCl, Io-Tol·HCl and ICy·HCl in much better yields than conventional solvent-based procedures, while the environmental impact was drastically reduced.

This article is part of the themed collection: 2018 Green Chemistry Hot Articles

Download options Please wait...

Supplementary files

Supplementary information PDF (2093K)

Article information

DOI: https://doi.org/10.1039/C7GC03539J
Article type: Communication
Submitted: 23 नवम्बर 2017
Accepted: 27 दिसम्बर 2017
First published: 02 जनवरी 2018

Download Citation

Green Chem., 2018,20, 964-968

Permissions

Request permissions

A more sustainable and efficient access to IMes·HCl and IPr·HCl by ball-milling

A. Beillard, X. Bantreil, T. Métro, J. Martinez and F. Lamaty, Green Chem., 2018, 20, 964 DOI: 10.1039/C7GC03539J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Green Chemistry

A more sustainable and efficient access to IMes·HCl and IPr·HCl by ball-milling†

Abstract

Supplementary files

Article information

Download Citation

Permissions

A more sustainable and efficient access to IMes·HCl and IPr·HCl by ball-milling

Social activity

Search articles by author

Spotlight

Advertisements