Issue 67, 2016

Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

Abstract

The efficient copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides has been developed under mild conditions with moderate to good yields. Significantly, this provides an alternative method to synthesise arylthioquinone derivatives. This is the first time that arylthioquinones with arylsulfonyl chlorides as starting material have been prepared, which avoids the use of the awful smelling thioalcohols and thiophenols.

Graphical abstract: Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

Supplementary files

Article information

Article type
Communication
Submitted
02 मई 2016
Accepted
21 जून 2016
First published
23 जून 2016

RSC Adv., 2016,6, 62298-62301

Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

X. Yu, Q. Wu, H. Wan, Z. Xu, X. Xu and D. Wang, RSC Adv., 2016, 6, 62298 DOI: 10.1039/C6RA11301J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements