Issue 25, 2015

Formation and in situ reactions of hypervalent iodonium alkynyl triflates to form cyanocarbenes

Abstract

The conversion of readily available silylalkynes, iodobenzene diacetate, and azide anions was utilized to form and react cyanocarbenes. A copper(II)-catalyzed reaction was found to react in a different manner. Both of these methods benefit from the formation and in situ reaction of hypervalent iodonium alkynyl triflates in O–H insertion reactions.

Graphical abstract: Formation and in situ reactions of hypervalent iodonium alkynyl triflates to form cyanocarbenes

Supplementary files

Article information

Article type
Communication
Submitted
01 नवम्बर 2014
Accepted
17 दिसम्बर 2014
First published
05 जनवरी 2015

Chem. Commun., 2015,51, 5287-5289

Author version available

Formation and in situ reactions of hypervalent iodonium alkynyl triflates to form cyanocarbenes

I. F. Dempsey Hyatt, D. J. Nasrallah, M. A. Maxwell, A. C. F. Hairston, M. M. Abdalhameed and M. P. Croatt, Chem. Commun., 2015, 51, 5287 DOI: 10.1039/C4CC08676G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements