This review highlights organoboron-based multiple-resonance compounds’ synthetic strategies classified as one-pot borylation, one-shot borylation, and late-stage functionalisation, and explores material structure–photophysical property correlations.
Synthesis of the anticancer drug tepotinib was achieved in only 5 steps (3 steps in the longest linear sequence), with an overall yield of 75%.
Chemistry in water, leveraging its solvent properties, provides a safer and more sustainable alternative to traditional organic solvent methods.
This review addresses the importance of Pd-catalyzed reactions in the synthesis of MR-TADF emitters, particularly Suzuki coupling and Buchwald–Hartwig cross-coupling reactions, and can provide enough ideas for the development of new MR emitters.
A new P3N ligand can be prepared quickly in gram quantities, combining PCl3 and n-Bu2NH to arrive at (n-Bu2N)3P, which complexes Pd and is effective for Suzuki–Miyaura and Heck–Cassar–Sonogashira couplings under aqueous micellar conditions.