Juping Wang, Kangcheng Zheng, Rongxing Xiao, Li Qian and Zijie Lin
Catal. Sci. Technol., 2022,12, 3498-3505
Abstract
The intermolecular catalytic mechanisms using Rh2(esp)2 and Rh2(OAc)4 are analogous and their large difference in aziridination-to-amination chemoselectivity stems from the steric effect.
Nikita M. Ankudinov, Nikita V. Alexeev, Evgeniya S. Podyacheva, Denis A. Chusov, Konstantin A. Lyssenko and Dmitry S. Perekalin
Chem. Sci., 2025,16, 6298-6306
Abstract
Catalytic insertion of nitrenes into B–H bonds produces unique compounds with chiral boron atoms.
Zhifan Wang, Beiqi Yang, Qi Yang and Yuanhua Wang
Org. Chem. Front., 2022,9, 3274-3280
Abstract
Using the single-electron oxidation cycle of a dirhodium catalyst, amination can form two primary C–N bonds in a one-step process.
Ze-Yu Yi, Na Sun, Peiming Gu, Yang Ji and Rui Li
New J. Chem., 2024,48, 9885-9889
Abstract
The three-component reaction of the diazo compound, azide and allylboronate for preparation of homoallylic amine derivatives was explored, and Rh2(esp)2 was utilized as the optimal catalyst.
Rui Wu, Dong Zhu and Shifa Zhu
Org. Chem. Front., 2023,10, 2849-2878
From themed collection:
2023 Organic Chemistry Frontiers Review-type Articles
Abstract
Dirhodium-catalyzed transformations, not limited to carbene and nitrene transfer reactions, are reviewed, including cycloisomerization, hetero-Diels–Alder (HDA) reactions, ene reactions, arylation, radical oxidation reactions and C–H activation, etc.