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Defluorinative alkylation of 1-trifluoromethyl alkenes with alkyl radicals derived from visible light-induced deoxygenation of xanthate salts: synthesis of gem-difluoroalkenes

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Tripleipso-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols: access to fluoroalkylated orthoestersviaC(sp3)–F bond cleavage

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Chemodivergent alkylation of trifluoromethyl alkenes via photocatalytic coupling with alkanes

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Green Chem., 2024, 26, 11196
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Photoinduced allylic defluorinative alkylation of trifluoromethyl alkenes with Katritzky salts under catalyst- and metal-free conditions

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Green Chem., 2022, 24, 6830
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Visible light-inducedgem-difluoroallylation of [1.1.1]propellane to accessgem-difluoroallylic bicyclo[1.1.1]pentanes

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Radical-mediated [3 + 2 + 1] annulation of α-polyfluoromethyl alkenes with arylisocyanates enabled by C(sp3)–F activation

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Photochemical and electrochemical strategies in C–F bond activation and functionalization

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Org. Chem. Front., 2022, 9, 853
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Defluorinative C–C Bond-Forming Reaction of Trifluoromethyl Alkenes with gem-(Diborylalkyl)lithiums

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Review on catalytic significance of 3d-transition metal-carbonyl complexes for general and selective organic reactions

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Synthesis of 2‐(β‐Trifluoromethyl‐β‐arylethylthio)pyridine through DBU‐Mediated Regioselective Addition of Pyridine‐2(1H)‐thione Onto α‐(Trifluoromethyl)styrenes

Pai Zheng, Yupian Deng, Jingjing He, Zhudi Sun, Ying Liu, Xutong Fan and Song Cao

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Transition-Metal-Free Late-Stage Decarboxylative gem-Difluoroallylation of Primary Alkyl Acids

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J. Org. Chem., 2024, 89, 15234
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Zinc-Mediated Radical-Type Cross-Electrophile Couplings of Trifluoromethyl Alkenes with Alkyl Iodides for Accessing gem-Difluoroalkenes in Aqueous Media

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J. Org. Chem., 2025, 90, 12807
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Recent progress of decacarbonyldimanganese catalysis

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Site-Selective Synthesis of Aryl Sulfides via Oxidative Aromatization of Cyclohexanones with Thiophenols

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J. Org. Chem., 2022, 87, 512
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Photocatalyzed Defluorinative Dichloromethylation of α-CF3 Alkenes Using CHCl3 as the Radical Source

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Transition‐Metal‐Free Allylic Defluorination Cross‐Electrophile Coupling Employing Rongalite

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Highly Regioselective Synthesis of N‐β‐trifluoromethyl 2‐pyridones via anti‐Markovnikov Hydroamination of α‐(trifluoromethyl)styrenes with 2‐pyridones

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Chemistry An Asian Journal, 2023, 18
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Oxalates as Activating Groups for Tertiary Alcohols in Photoredox-Catalyzed gem-Difluoroallylation To Construct All-Carbon Quaternary Centers

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J. Org. Chem., 2022, 87, 8237
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Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [Mn2(CO)10]

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Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α‐(Trifluoromethyl)styrenes

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ChemCatChem, 2023, 15
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Access to gem-Difluoroalkenes via Organic Photoredox-Catalyzed gem-Difluoroallylation of Alkyl Iodides

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J. Org. Chem., 2022, 87, 1574
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Visible-Light-Induced Synergistic W/Cr Catalyzed gem-Difluoroallylation of Unactivated Alkanes

Zhijie Zhang, Yue Zhang, Xinyu Xie, Hua-Wei Liu, Tianshuai Zhu, Jing-Jing Zhang, Meng-Yang Hu and Zhen Chen

Org. Lett., 2025, 27, 2016
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Aryl Carboxylic Acids as Structure-Tunable HAT Agents for Photochemical Site-Selective C(sp3)–H gem-Difluoroallylation of Amides

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Org. Lett., 2025, 27, 12223
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Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes

Cong Luo, Yang Zhou, Hang Chen, Ting Wang, Zheng-Bing Zhang, Pan Han and Lin-Hai Jing

Org. Lett., 2022, 24, 4286
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Facile Synthesis of β‐trifluoromethyl thioethers via DBN‐catalyzed Hydrothiolation of α‐(Trifluoromethyl)styrenes with Thiols

Yupian Deng, Jiaqi Huang, Yuhao Qian, Zhudi Sun, Qingchun Huang and Song Cao

Chemistry An Asian Journal, 2024, 19
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Photocatalytic Reactions of α-CF3 Alkenes with Alcohols by Controllable Non-, Mono- and Dual-Defluorination

Meixue Gan, Shuyue Zhang, Wenting Ye, Lei Zhou and Weiyu Li

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Recent Advances in C-F Bond Cleavage Enabled by Visible Light Photoredox Catalysis

Lei Zhou

Molecules, 2021, 26, 7051
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Photoredox Activation of Organozinc Reagents: Barbier-Type Reaction of Alkyl Halides with α-(Trifluoromethyl)styrenes

Anton A. Gladkov, Grigory N. Chernov, Vitalij V. Levin, Vladimir A. Kokorekin and Alexander D. Dilman

Org. Lett., 2021, 23, 9645
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Defluorinative Alkylation of Trifluoromethyl Alkenes with Soft Carbon Nucleophiles Enabled by a Catalytic Amount of Base

Ya Gao, Wei Qin, Ming‐Qing Tian, Xuefei Zhao and Xu‐Hong Hu

Adv Synth Catal, 2022, 364, 2241
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Electrochemical‐Induced Hydroxysulfonylation of α‐CF3 Alkenes to Access Tertiary β‐Hydroxysulfones

Xu Luo, Shengchun Wang and Aiwen Lei

Adv Synth Catal, 2022, 364, 1016
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Ni-Catalyzed Radical-Promoted Defluoroalkylborylation of Trifluoromethyl Alkenes To Access gem-Difluorohomoallylic Boronates

Jian Qiu, Cece Wang, Lu Zhou, Yixian Lou, Kai Yang and Qiuling Song

Org. Lett., 2022, 24, 2446
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