Issue 54, 2023

Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization

Abstract

A series of linear oligo(p-phenylene iminoboranes), which are BN-modified congeners of oligo(p-phenylene vinylenes), featuring pendent ferrocene groups have been prepared. Stoichiometric reaction of a bis-silylamine with a bisborane led to selective formation of an unprecedented macrocycle, without the use of a template.

Graphical abstract: Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization

Supplementary files

Article information

Article type
Communication
Submitted
13 אפר 2023
Accepted
12 יונ 2023
First published
12 יונ 2023

Chem. Commun., 2023,59, 8408-8411

Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization

J. S. Schneider, I. Krummenacher, H. Braunschweig and H. Helten, Chem. Commun., 2023, 59, 8408 DOI: 10.1039/D3CC01825C

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