Issue 48, 2019

Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

Abstract

The incorporation of metal carbonyl clusters into the backbone of coordination polymers represents an important field in contemporary chemistry. The development of metal carbonyl cluster-based polymers with or without inorganic/organic linkers is not only a challenging issue but also an opportunity for discovering novel types of materials, due to the intrinsic chemical/physical properties, versatile networks, and potential applications of these types of materials. This review provides an overview of recent developments in groups 6–10 carbonyl cluster-based coordination polymers, and in particular, focuses on polymers that are produced starting from pre-synthesized metal carbonyl clusters. This highlight presents a review and discussion of recent progress from our group as well as others, the diverse synthetic strategies for preparing such polymers, versatile network structures, structural transformations, and semiconducting and magnetic properties as well as other applications.

Graphical abstract: Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

Article information

Article type
Highlight
Submitted
30 ספט 2019
Accepted
01 נוב 2019
First published
02 נוב 2019

CrystEngComm, 2019,21, 7341-7364

Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

M. Shieh, Y. Liu, Y. Li and R. Y. Lin, CrystEngComm, 2019, 21, 7341 DOI: 10.1039/C9CE01539F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements