Issue 5, 2016

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

Abstract

A facile and divergent synthetic process for converting tertiary allylic alcohols to multiply substituted allylic boronates is reported. This methodology is especially effective for tertiary alcohol substrates, providing the corresponding allylic boronates in moderate to good yields.

Graphical abstract: Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

Supplementary files

Article information

Article type
Research Article
Submitted
09 ינו 2016
Accepted
23 פבר 2016
First published
01 מרץ 2016

Org. Chem. Front., 2016,3, 565-569

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

K. Harada, M. Nogami, K. Hirano, D. Kurauchi, H. Kato, K. Miyamoto, T. Saito and M. Uchiyama, Org. Chem. Front., 2016, 3, 565 DOI: 10.1039/C6QO00009F

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