Elucidating the intercalation mechanism of zinc ions into α-MnO2 for rechargeable zinc batteries

Boeun Lee; Hae Ri Lee; Haesik Kim; Kyung Yoon Chung; Byung Won Cho; Si Hyoung Oh

doi:10.1039/C5CC02585K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Elucidating the intercalation mechanism of zinc ions into α-MnO₂ for rechargeable zinc batteries†

Boeun Lee,^a Hae Ri Lee,^a Haesik Kim,^a Kyung Yoon Chung,^a Byung Won Cho^a and Si Hyoung Oh*^a

Author affiliations

* Corresponding authors

^a Korea Institute of Science and Technology, Hwarang-ro 14-gil 5, Seongbuk-gu, Seoul, Korea
E-mail: sho74@kist.re.kr

Abstract

The intercalation mechanism of zinc ions into 2 × 2 tunnels of an α-MnO₂ cathode for rechargeable zinc batteries was revealed. It involves a series of single and two-phase reaction steps and produces buserite, a layered compound with an interlayer spacing of 11 Å as a discharge product.

This article is part of the themed collection: ChemComm 60th Anniversary Historic Papers from Japan and South Korea

Download options Please wait...

Supplementary files

Supplementary information PDF (1892K)

Article information

DOI: https://doi.org/10.1039/C5CC02585K
Article type: Communication
Submitted: 29 מרץ 2015
Accepted: 20 אפר 2015
First published: 21 אפר 2015

Download Citation

Chem. Commun., 2015,51, 9265-9268

Permissions

Request permissions

Elucidating the intercalation mechanism of zinc ions into α-MnO₂ for rechargeable zinc batteries

B. Lee, H. R. Lee, H. Kim, K. Y. Chung, B. W. Cho and S. H. Oh, Chem. Commun., 2015, 51, 9265 DOI: 10.1039/C5CC02585K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications