Issue 71, 2013
From the journal:

Chemical Communications

Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions†

Wesley A. Hoffert,a   John A. S. Roberts,a   R. Morris Bullocka  and  Monte L. Helm*a  

* Corresponding authors

a Center for Molecular Electrocatalysis, Physical Sciences Division, Pacific Northwest National Laboratory, K2-57, Richland, WA 99352, USA
E-mail: Monte.Helm@pnnl.gov
Tel: +01-509-375-2331

Abstract

We report a synthetic nickel complex containing proton relays, [Ni(PPh2NC6H4OH2)2](BF4)2 (PPh2NC6H4OH2 = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclo-octane), that catalyzes the production of H2 in aqueous acetonitrile with turnover frequencies of 750–170 000 s−1 at experimentally determined overpotentials of 310–470 mV.

Graphical abstract: Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC43203C
Article type
Communication
Submitted
30 אפר 2013
Accepted
29 מאי 2013
First published
30 מאי 2013

Chem. Commun., 2013,49, 7767-7769

Permissions

Request permissions

Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions

W. A. Hoffert, J. A. S. Roberts, R. Morris Bullock and M. L. Helm, Chem. Commun., 2013, 49, 7767 DOI: 10.1039/C3CC43203C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements