Issue 28, 2009

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

Abstract

A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.

Graphical abstract: Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

Supplementary files

Article information

Article type
Communication
Submitted
23 מרץ 2009
Accepted
26 מאי 2009
First published
11 יונ 2009

Chem. Commun., 2009, 4266-4268

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

V. Subbarayan, J. V. Ruppel, S. Zhu, J. A. Perman and X. P. Zhang, Chem. Commun., 2009, 4266 DOI: 10.1039/B905727G

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