Syntheses and polymerization of monoterpene-based (meth)acrylates: IBO(M)A as a relevant monomer for industrial applications

Abstract

Monoterpenes, a class of natural compounds that occur as secondary plant metabolites, have received increasing attention as promising starting materials for the synthesis of (meth)acrylate monomers. This review addresses the synthesis, polymerization, and diverse applications of monoterpene (meth)acrylates and provides a comprehensive overview of the progress in this field in recent decades. Various synthetic routes and techniques are discussed, highlighting the adaptability of monoterpenes as starting materials. The different material properties, due to the diverse chemical structures, are examined in the context of different polymerization methods. The potential for tailoring polymer properties through the selection of appropriate monomers and polymerization techniques is demonstrated. The wide range of applications for such polymers, including their use in adhesives, coatings, biomedical materials and beyond, will be highlighted. Innovative applications are presented to highlight the practical relevance of these materials in various industries. This review is intended to offer researchers a comprehensive resource on the synthesis, polymerization, and applications of monoterpene (meth)acrylates. It highlights the versatile nature of these compounds, which offer a promising avenue for the development of environmentally friendly and high-performance polymeric materials.