Issue 49, 2023

A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

Abstract

A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ2-hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium.

Graphical abstract: A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

Supplementary files

Article information

Article type
Communication
Submitted
31 מרץ 2023
Accepted
23 מאי 2023
First published
31 מאי 2023

Chem. Commun., 2023,59, 7627-7630

A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

F. Seifert, H. Görls, S. Kupfer and R. Kretschmer, Chem. Commun., 2023, 59, 7627 DOI: 10.1039/D3CC01608K

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