Issue 86, 2021

Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

Abstract

Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3 nanoprisms with cobalt–porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt–porphyrin nanocages have been characterized in CoI, CoII, and CoIII states.

Graphical abstract: Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

Supplementary files

Article information

Article type
Communication
Submitted
31 אוג 2021
Accepted
06 אוק 2021
First published
06 אוק 2021

Chem. Commun., 2021,57, 11342-11345

Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

P. T. Blackburn, I. F. Mansoor, K. G. Dutton, A. M. Tyryshkin and M. C. Lipke, Chem. Commun., 2021, 57, 11342 DOI: 10.1039/D1CC04860K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements