Orientational self-sorting: formation of structurally defined Pd4L8 and Pd6L12 cages from low-symmetry dipyridyl ligands

Ru-Jin Li; Adam Marcus; Farzaneh Fadaei-Tirani; Kay Severin

doi:10.1039/D1CC03828A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Orientational self-sorting: formation of structurally defined Pd₄L₈ and Pd₆L₁₂ cages from low-symmetry dipyridyl ligands†

Ru-Jin Li,^a Adam Marcus,^b Farzaneh Fadaei-Tirani

^a and Kay Severin

*^a

Author affiliations

* Corresponding authors

^a Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
E-mail: kay.severin@epfl.ch

^b Institute of Mathematics, EPFL, 1015 Lausanne, Switzerland

Abstract

Tetra- and hexanuclear coordination cages were obtained in reactions of [Pd(CH₃CN)₄](BF₄)₂ with low-symmetry dipyridyl ligands. In both cases, only one structurally defined complex was formed out of a vast pool of potential isomers.

This article is part of the themed collection: Host-Guest Chemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1CC03828A
Article type: Communication
Submitted: 15 יול 2021
Accepted: 03 ספט 2021
First published: 10 ספט 2021

Download Citation

Chem. Commun., 2021,57, 10023-10026

Permissions

Request permissions

Orientational self-sorting: formation of structurally defined Pd₄L₈ and Pd₆L₁₂ cages from low-symmetry dipyridyl ligands

R. Li, A. Marcus, F. Fadaei-Tirani and K. Severin, Chem. Commun., 2021, 57, 10023 DOI: 10.1039/D1CC03828A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications