Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes

Volodymyr Levchenko; Cristiano Glessi; Sigurd Øien-Ødegaard; Mats Tilset

doi:10.1039/C9DT04472H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes†‡

Volodymyr Levchenko,

^a Cristiano Glessi,

^a Sigurd Øien-Ødegaard

^a and Mats Tilset

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Center for Materials Science and Nanotechnology (SMN), Faculty of Mathematics and Natural Sciences, University of Oslo, P.O. Box 1126 Blindern, NO-0318 Oslo, Norway
E-mail: mats.tilset@kjemi.uio.no
Tel: +47-22855502

Abstract

The synthesis and characterization of a series of N-heterocyclic carbene (NHC) complexes of Au(III), (NHC)AuCl₃, is described. High yields are obtained when the corresponding Au(I) species (NHC)AuCl are oxidized with inexpensive aqua regia. The oxidation is in some cases accompanied by substitution and/or anti addition of Cl₂ across the backbone C [double bond, length as m-dash] C bond of unsaturated NHC ligands.

This article is part of the themed collection: Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9DT04472H
Article type: Paper
Submitted: 20 נוב 2019
Accepted: 17 פבר 2020
First published: 18 פבר 2020

Download Citation

Dalton Trans., 2020,49, 3473-3479

Permissions

Request permissions

Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes

V. Levchenko, C. Glessi, S. Øien-Ødegaard and M. Tilset, Dalton Trans., 2020, 49, 3473 DOI: 10.1039/C9DT04472H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions

Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes†‡

Abstract

Supplementary files

Article information

Download Citation

Permissions

Organometallic chemistry in aqua regia: metal and ligand based oxidations of (NHC)AuCl complexes

Social activity

Search articles by author

Spotlight

Advertisements