Issue 13, 2018

Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Abstract

ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, 29Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.

Graphical abstract: Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Supplementary files

Article information

Article type
Communication
Submitted
20 אוק 2017
Accepted
16 נוב 2017
First published
20 נוב 2017

J. Mater. Chem. A, 2018,6, 5255-5259

Pressure-induced chemistry for the 2D to 3D transformation of zeolites

M. Mazur, Angel M. Arévalo-López, P. S. Wheatley, G. P. M. Bignami, S. E. Ashbrook, Á. Morales-García, P. Nachtigall, J. P. Attfield, J. Čejka and R. E. Morris, J. Mater. Chem. A, 2018, 6, 5255 DOI: 10.1039/C7TA09248B

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