Issue 7, 2018

Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand

Abstract

Two extremely bulky amidinate ligands, [RC{N(Dip)}{N(Ar)}] (Dip = 2,6-diisopropylphenyl; Ar = C6H2{C(H)Ph2}2Pri-2,6,4; R = 1-adamantyl (LAd), tert-butyl (LtBu)) have been developed and utilised for the kinetic stabilisation of the strontium and magnesium hydride complexes, [LAdSr(μ-H)]2 and [LRMg(μ-H)]2 (R = Ad or But). The former represents the missing link in the series of dimeric systems, [LAe(μ-H)]2 (Ae = alkaline earth metal). The structure and bonding of the complexes have been studied by crystallographic, spectroscopic and computational techniques.

Graphical abstract: Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand

Supplementary files

Article information

Article type
Communication
Submitted
06 דצמ 2017
Accepted
02 ינו 2018
First published
02 ינו 2018

Chem. Commun., 2018,54, 786-789

Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand

C. N. de Bruin-Dickason, T. Sutcliffe, C. Alvarez Lamsfus, G. B. Deacon, L. Maron and C. Jones, Chem. Commun., 2018, 54, 786 DOI: 10.1039/C7CC09362D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements