Issue 3, 2017

Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

Abstract

A highly tunable phosphine–imine ligand family is introduced. Following metallation with ruthenium, deprotonation of the ligand affords a phosphine–enamido species. Complexes with the ligand in both the imine and enamido forms are active toward acceptorless dehydrogenation reactions.

Graphical abstract: Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

Supplementary files

Article information

Article type
Communication
Submitted
24 אוק 2016
Accepted
22 נוב 2016
First published
28 נוב 2016

Dalton Trans., 2017,46, 647-650

Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

J. M. Stubbs, K. F. Firth, B. J. Bridge, K. J. Berger, R. J. Hazlehurst, P. D. Boyle and J. M. Blacquiere, Dalton Trans., 2017, 46, 647 DOI: 10.1039/C6DT04088H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements