Issue 11, 2016

Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

Abstract

A highly efficient manganese-catalysed hydroperoxidation of carbon–carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through the direct incorporation of molecular oxygen present in air. The required catalytic loading of manganese(III) acetylacetonate is extremely low (generally 0.02–0.5 mol%, and a minimum of 0.001 mol%).

Graphical abstract: Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

Supplementary files

Article information

Article type
Research Article
Submitted
30 יונ 2016
Accepted
22 אוג 2016
First published
23 אוג 2016

Org. Chem. Front., 2016,3, 1420-1424

Author version available

Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

D. Yamamoto, M. Soga, H. Ansai and K. Makino, Org. Chem. Front., 2016, 3, 1420 DOI: 10.1039/C6QO00318D

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