Issue 91, 2016

Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry

Abstract

A heterochiral 1,3,5-benzene tricarboxamide (BTA) monomer, derived from valine dodecyl ester, forms long rods in cyclohexane whilst its homochiral analogue assembles into dimers only at the same concentration. This highly original assembly behaviour is related to the destabilization of the dimeric structure containing the two heterochiral monomers as corroborated by a combined experimental and computational study.

Graphical abstract: Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry

Supplementary files

Article information

Article type
Communication
Submitted
07 ספט 2016
Accepted
20 אוק 2016
First published
20 אוק 2016

Chem. Commun., 2016,52, 13369-13372

Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry

X. Caumes, A. Baldi, G. Gontard, P. Brocorens, R. Lazzaroni, N. Vanthuyne, C. Troufflard, M. Raynal and L. Bouteiller, Chem. Commun., 2016, 52, 13369 DOI: 10.1039/C6CC07325E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements