Issue 48, 2016
From the journal:

Chemical Communications

Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers†

Keren Zhang,a   Samantha J. Talley,a   Ya Peng Yu,b   Robert B. Moore,a   Mitsuhiro Murayamab  and  Timothy E. Long*a  

* Corresponding authors

a Department of Chemistry, Macromolecules Innovation Institute, Virginia Tech, Blacksburg, VA 24061, USA
E-mail: telong@vt.edu

b Department of Materials Science and Engineering, Virginia Tech, Blacksburg, VA, USA

Abstract

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates. Intermolecular hydrogen bonding formed thymine–adenine triplets and promoted self-assembly into well-defined lamellae consisting of poly(n-butyl acrylate) soft domains and complementary nucleobase hard domains, while thymine–adenine duplets contributed to superior mechanical properties.

Graphical abstract: Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CC03502G
Article type
Communication
Submitted
26 אפר 2016
Accepted
11 מאי 2016
First published
11 מאי 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 7564-7567

Permissions

Request permissions

Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers

K. Zhang, S. J. Talley, Y. P. Yu, R. B. Moore, M. Murayama and T. E. Long, Chem. Commun., 2016, 52, 7564 DOI: 10.1039/C6CC03502G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements