Issue 12, 2015

Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

Abstract

An efficient method for the direct C–H olefination of sulfocoumarins with a wide range of alkenes is developed. Moreover, O2 was successfully utilized as the sole oxidant for the oxidative Heck reaction. This approach enables the rapid generation of various 3-alkenylated sulfocoumarins.

Graphical abstract: Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

Supplementary files

Article information

Article type
Research Article
Submitted
22 ספט 2015
Accepted
26 אוק 2015
First published
28 אוק 2015

Org. Chem. Front., 2015,2, 1621-1624

Author version available

Regioselective palladium(II)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

N. Kim, M. Min and S. Hong, Org. Chem. Front., 2015, 2, 1621 DOI: 10.1039/C5QO00294J

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