Issue 18, 2018

Observation of current rectification by a new asymmetric iron(iii) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

Abstract

In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [FeIII(LN3O)(OMe)2], where (LN3O) is the deprotonated form of the new asymmetric ligand 2-((E)-((4,5-bis(2-methoxyethoxy)-2-(((E)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-tert-butyl-phenol. This species rectifies current when deposited as a Langmuir–Blodget film in a “EGaIn/Ga2O3|LB|Au” sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.

Graphical abstract: Observation of current rectification by a new asymmetric iron(iii) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

Supplementary files

Article information

Article type
Paper
Submitted
09 פבר 2018
Accepted
25 מרץ 2018
First published
03 אפר 2018

Dalton Trans., 2018,47, 6344-6350

Author version available

Observation of current rectification by a new asymmetric iron(III) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

M. S. Johnson, C. L. Horton, S. Gonawala, C. N. Verani and R. M. Metzger, Dalton Trans., 2018, 47, 6344 DOI: 10.1039/C8DT00562A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements