Issue 98, 2016

Explosive enantiospecific decomposition of aspartic acid on Cu surfaces

Abstract

Aspartic acid adsorbed on Cu surfaces is doubly deprotonated. On chiral Cu(643)R&S its enantiomers undergo enantiospecific decomposition via an autocatalytic explosion. Once initiated, the decomposition mechanism proceeds via sequential cleavage of the C3–C4 and C1–C2 bonds each yielding CO2, followed by conversion of the remaining species into N[triple bond, length as m-dash]CCH3.

Graphical abstract: Explosive enantiospecific decomposition of aspartic acid on Cu surfaces

Supplementary files

Article information

Article type
Communication
Submitted
22 אוג 2016
Accepted
07 נוב 2016
First published
08 נוב 2016

Chem. Commun., 2016,52, 14125-14128

Explosive enantiospecific decomposition of aspartic acid on Cu surfaces

B. S. Mhatre, S. Dutta, A. Reinicker, B. Karagoz and A. J. Gellman, Chem. Commun., 2016, 52, 14125 DOI: 10.1039/C6CC06887A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements