In situ construction of solid-electrolyte interfaces for metallic Zn anodes in aqueous zinc batteries

Xiaoxin Nie, Yujiao Yang, Junwu Hu, Du Yuan, Lei Hu and Li-Feng Chen

J. Mater. Chem. A, 2025, 13, 41443
DOI: 10.1039/D5TA07474F

Interface engineering via in situ constructed zincophilic gradient interphases for high-performance zinc-ion batteries in wide temperature ranges

Yi-Yang Bi, Song-Lin Tian, Yang Yu, Yu Zhang, Lian-Shan Sun, Jian Li, Wan-Qiang Liu, Kai Li and Gang Huang

Green Chem., 2025, 27, 13413
DOI: 10.1039/D5GC03908H

Charge gradient separator regulating ion transport towards stabilizing Zn metal anodes

Zhikai Li, Wenjie Fan, Xinlei Yu, Xingjie Wang, Yanying Dong, Haisheng Huang, Weiqian Tian and Jingyi Wu

J. Mater. Chem. A, 2026, 14, 2295
DOI: 10.1039/D5TA07750H

An electrochemically paralleled biomass electrolyte additive facilitates the integrated modification of multi-dimensional Zn metal batteries

Kefeng Ouyang, Sheng Chen, Lidong Yu, Hongyu Qin, Ao Liu, Youfa Liu, Quan Wu, Bingjie Ran, Shubing Wei, Fei Gao, Kun Zhang, Jin Hu and Yan Huang

Energy Environ. Sci., 2025, 18, 4416
DOI: 10.1039/D5EE00237K

Chain-length engineered interfacial architecture enables dendrite-free aqueous zinc-ion batteries

Jiaqi Yang, Zhengxiao Ji, Miaoran Deng, Chaocang Weng, Xusheng Wang, Min Xu, Likun Pan and Jinliang Li

Mater. Horiz., 2025, 12, 6383
DOI: 10.1039/D5MH00668F

Interfacial chemistry regulation by orbital hybridization for superior kinetics of hard carbon in an ester-based electrolyte

Lu Liu, Jianhua Zhu, Guohui Chen, Zhuosen Wang, Liu Wang, Chengkun Guo, Yunfeng Chao, Xinwei Cui and Caiyun Wang

Chem. Sci., 2025, 16, 17630
DOI: 10.1039/D5SC04111B

Side reactions at the Zn anode: what we know and how we deal with them

Gao Weng, Shuang Chen, Yang Xiang, Yufan Xia, Zhen Luo, Xuan Zhang, Muhammad Wakil Shahzad, Linhua Zhu, Ben Bin Xu, Mi Yan, Hongge Pan and Yinzhu Jiang

Chem. Soc. Rev., 2026, 55, 2396
DOI: 10.1039/D5CS01269D

Ion flux regulation in aqueous zinc-ion batteries

Zihan Xu, Mei Han and Jian Zhi

J. Mater. Chem. A, 2025, 13, 22324
DOI: 10.1039/D5TA01379H

Uniformly dispersed zincophilic Cu sites on copper mesh enable a dendrite-free Zn metal anode

Dandan Liu, Qi Wang, Wanying Fang, Ge Tian, Xiaobo Chen, Huijuan Yue and Shouhua Feng

J. Mater. Chem. A, 2025, 13, 15118
DOI: 10.1039/D5TA00563A

A Janus-type quasi-solid-state electrolyte enabling dual-ion relay for long lifespan of nonaqueous zinc batteries

Shunshun Zhao, Sinian Yang, Xuanrui Huang, Xinwei Wang, Haojie Xu, Qing Ma, Yong Chen, Guoxiu Wang and Shimou Chen

Energy Environ. Sci., 2025, 18, 8618
DOI: 10.1039/D5EE03224E

Several concerns about aqueous zinc metal batteries: from components to unit cells

Mingzhu Li, Shuquan Liang and Guozhao Fang

EES Batteries, 2026, 2, 60
DOI: 10.1039/D5EB00159E

Rational design of artificial solid electrolyte interphases for stable zinc metal anodes: mechanistic insights, construction strategies, and practical implementation

Tianyu Zhang, Yuexin Liu, Feng Yang, Chengcheng Dong, Wenzhuo Gao, Hongfei Wang and Yong Hu

Coordination Chemistry Reviews, 2026, 553, 217586
DOI: 10.1016/j.ccr.2026.217586

Amino-functionalized electrospinning separator tailors desolvation kinetics and Zn2+ transport for high-performance aqueous zinc-ion batteries

Zhuoqun Liu, Luxin Yu, Zhenying Zhang, Yang Feng, Bin Li, Yingqiao Jiang, Ningning Zhao, Jing Zhu, Lei Dai, Ling Wang and Zhangxing He

Chemical Engineering Journal, 2025, 526, 171373
DOI: 10.1016/j.cej.2025.171373

An artificial MXene/TiO2 heterojunction coating layer enabling highly reversible Zn anodes

Yong Liu, Penghui Zhai, Fei Wang, Binrui Xu, Mingliang He, Bo Zhao, Yifei Pei, Jian Cui, Xiaobin Sun, Cheng Zhang, Fengzhang Ren and Wanhong Zhang

Journal of Electroanalytical Chemistry, 2026, 1007, 119916
DOI: 10.1016/j.jelechem.2026.119916

(101) Facet growth directed by MXene-based quantum dots: A pathway to high-performance zinc-ion batteries

Shaokang Xu, Jingyuan Qiao, Ye Chen, Jie Wei, Wei Zhang, Guangji Xu, Tomasz Wejrzanowski, Wei He and ZhengMing Sun

Journal of Energy Storage, 2025, 132, 117627
DOI: 10.1016/j.est.2025.117627

In-situ constructed organic-copper bilayer SEI for exceptional cycling stability of Zn anodes

Jingwen Liu, Xinghui Liu, Teng Yu, Meiting Fu, Yibo Ma, Wenxiang Sun, Zhen Hong, Tianyi Ma, Lei Wang and Caixia Li

Chemical Engineering Journal, 2026, 530, 173559
DOI: 10.1016/j.cej.2026.173559

Light-Induced NH4+ Deprotonation Drives NH4+/H+ Hybrid Storage Toward Near-Theoretical Capacity in NH4V4O10 Electrodes

Jiazheng Nan, Yurong You, Wenwen Zha, Linhong Xia, Qiushi Ruan and ZhengMing Sun

J. Am. Chem. Soc., 2026, 148, 1347
DOI: 10.1021/jacs.5c17886

Tailored fluoroborate-based electrolyte with fast interphase formation kinetics toward stable Ah-level zinc batteries

Jiangtao Huang, Yunpeng Zhong, Najla AlMasoud, Taghrid S. Alomar, Yiman Xie, Bingan Lu, Shuquan Liang, Zeinhom M. El-Bahy, Siyu Tian and Jiang Zhou

Advanced Powder Materials, 2025, 4, 100306
DOI: 10.1016/j.apmate.2025.100306

Anion screening in ether-based electrolytes for boosted sodium storage at low-temperature

Shaocong Tang, Jiabao Li, Quan Yuan, Chengyin Wang, Tian Wang, Weiwei Xiang, Ya Xiao, Shenqiu Xu and Jae Su Yu

Energy Storage Materials, 2025, 81, 104459
DOI: 10.1016/j.ensm.2025.104459

Functional group engineering in electrolyte additives toward highly stable zinc-ion batteries

Le Zhang, Xijun Liu, Linhui Chang, Qiangchao Sun, Xionggang Lu and Hongwei Cheng

Energy Storage Materials, 2025, 81, 104508
DOI: 10.1016/j.ensm.2025.104508

Measurement of battery electrolyte transport properties: a review

Katherine Betts, Jessica Stott, Mir Hadi Banan Khojasteh and Zhange Feng

Nano Views, 2026, 2
DOI: 10.1080/30652669.2025.2605962

Hygroscopic Organic Complex Mutated Helmholtz Plane of Zn Anode for Outstanding Zinc Ion Battery

Abdelnaby M. Elshahawy, Yong Gao, Wenbo Zhao, Junwei Li, Haifeng Zhang and Ximeng Liu

Energy & Environ Materials, 2026, 9
DOI: 10.1002/eem2.70151

Small Additions Make Big Changes: Electrolyte Additives for Aqueous Zinc Metal Batteries

Shengyang Huang, Wen He, Yu Xu, Jungwon Park, Yutong Wu and Ho Seok Park

Adv Funct Materials, 2026
DOI: 10.1002/adfm.202530510

V2O3 with Se‐Enhanced d‐p Orbital Hybridization Toward Highly Stable Aqueous Zinc Batteries under 10 A g−1

Runmei Luo, Qingjun Yang, Lin Sun, Yu Liu, Longhua Li, Yong Lei and Weidong Shi

Advanced Materials, 2026, 38
DOI: 10.1002/adma.202516093

Anionic corrosion inhibitors facilitate preferential Zn (002) deposition in aqueous zinc-ion batteries

Jiaqi Yang, Meijia Qiu, Zhengxiao Ji, Peng Sun, Farzaneh Hekmat, Saeed Shahrokhian, Xiong Pu, Min Xu, Likun Pan and Jinliang Li

Nano Research, 2025, 18, 94907746
DOI: 10.26599/NR.2025.94907746

In-situ coordination defects in metal oxides: chemical perspectives and operando characterization for high-performance multivalent-ion energy storage

Nadeem Hussain Solangi, Rana R. Neiber, Jai Kumar, Soumia Zagad, Jingmeng Jiao, Maokuan Guo, Xingmei Lu, Victor Charles and Jun Lu

Coordination Chemistry Reviews, 2026, 559, 217793
DOI: 10.1016/j.ccr.2026.217793

Modification of zinc metal batteries with ethylene carbonate as an electrolyte additive

Meizi Li, Yunhan Li, Changzhe Cui and Cuimei Zhao

Journal of Physics and Chemistry of Solids, 2026, 212, 113558
DOI: 10.1016/j.jpcs.2026.113558

Self-assembled vertically aligned organic-inorganic interphase for dendrite-free and reversible zinc metal anodes

Yexing Wang, Zhehan Yi, Yueheng Feng, Pinxiang Li, Peng Li, Lichang Yin, Ji Liang and Feng Hou

Journal of Energy Chemistry, 2026, 113, 455
DOI: 10.1016/j.jechem.2025.09.020

Choreographing Orbital Hybridization Cascades to Unleash Selective Proton Storage in Aqueous Zinc‐Ion Batteries

Jinghua Yang, Xiaoke Li, Shiyu Wang, Ruilong Liu, Feike Zhang, Guixi Wang, Jun Wang, Weikun Ren, Jingyu Wu, Kang Ji, Yingjie Ji, Zhijie Chen, Bing‐Jie Ni, Zhiyu Yang, Ningning Wu and Yi‐Ming Yan

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202513512

Exploring the unknown relationship between additives and zinc anodes: from key challenges to enhancement mechanisms

Jing-Yu Wang, Yi-Han Zhao, Xin-Yu Liu, Peng-Fei Wang, Zong-Lin Liu, Qianyu Zhang, Jie Shu and Ting-Feng Yi

Coordination Chemistry Reviews, 2025, 545, 217019
DOI: 10.1016/j.ccr.2025.217019

Ultra-long and rapid operating zinc metal batteries enabled by multifunctional polarizable interface stabilizer

Song-Lin Tian, Li Lin, Si-Yu Jiang, Li-Na Song, Hai-Rui Wang, Ping Nie, Li-Min Chang and Wan-Qiang Liu

Chemical Engineering Journal, 2025, 522, 167659
DOI: 10.1016/j.cej.2025.167659

Oriented Zn(002) planar plating/stripping for high-capacity ultralong-life aqueous batteries

Yuxiao Wang and Weihua Tang

Journal of Energy Chemistry, 2025, 109, 89
DOI: 10.1016/j.jechem.2025.05.026

Chiral Coordination Interphase‐Mediated Ion Regulation and Shuttle Suppression for Stable Zinc–Iodine Batteries

Xinyue Lan, Hongbo Wu, Tao Yang, Rui Wang, Ouwei Sheng, Zhijin Ju, Jian Zhang, Rongkun Zheng, Chaofeng Zhang and Xuefeng Zhang

Adv Funct Materials, 2026
DOI: 10.1002/adfm.202600057

Orbital energy level engineering: 3d high-spin Mn's d-electron mediating electronic structure of VO2 boosting highly durable aqueous ammonium ion batteries

Zhenhua Zhou, Miao Cui, Tianming Lv, Jian Cao, Ziqi Ren, Yi Zhong, HongXin Zhao, Hongye zheng, Yifu Zhang, Yang Wang and Changgong Meng

Journal of Colloid and Interface Science, 2026, 702, 138826
DOI: 10.1016/j.jcis.2025.138826

Hierarchical Dendrite-Trapping 3D-Printed Polymer-Coated Zn Anode toward Ultra-Stable Cycling at High Current Densities

Yicheng Wang, Chenglong Chen, Ru Cheng, Tingting Xiang, Ruibo Wang, Fuzhan Song, Sanjay Mathur and Juan Yang

ACS Appl. Mater. Interfaces, 2026, 18, 6901
DOI: 10.1021/acsami.5c21740

Molecular fence on the inner Helmholtz plane for highly reversible zinc metal anodes

Ying Li, Zheng-Han Yang, Jia-Hao Li, Zong-Lin Liu, Peng-Fei Wang, Qianyu Zhang, Dongliang Chao, Yuping Wu and Ting-Feng Yi

eScience, 2026, 100556
DOI: 10.1016/j.esci.2026.100556

Ultrathin formvar film protective layer via simple dipping strategy for ultra-stable zinc-metal anodes

Lihong Dong, Chunhui Zhao and Linlin Li

Journal of Colloid and Interface Science, 2025, 700, 138457
DOI: 10.1016/j.jcis.2025.138457

Suppressing Jahn-Teller distortion in MnO2 via interlayer orbital hybridization for durable zinc storage

Dapeng Wang, Chang Wen, Tianyu Liu, Guangyue Zhu, Qiyue Xie, Youjian Zhu, Zijian Zhou and Zhengkai Tu

Journal of Energy Chemistry, 2026, 117, 800
DOI: 10.1016/j.jechem.2026.02.036

Bionic Nanogel Interfaces Unlock Long‐Term Stability in Zn Metal Electrodeposition‐Based Electrochromic Windows

Kai Wang, Feng Zhang, Xinwei Jiang, Wu Zhang, Lei Dai, Jichao Zhang, Zhaoling Li and Hao Jia

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202509980

Synergetic Effect of Multicomponent Phosphate and Rich Grain‐Boundary in Solid/Electrolyte Interphase Boosts Rapid Ion Transport Toward Fast Aqueous Zinc Metal Batteries

Ke Ye, Tian Qiu, Jinsong Wan, Jianping Chen, Jinlei Zhang, Shangyu Liu, Fanghua Ning, Jin Yi, Zhuanpei Wang, Zhenghui Pan and Xiaowei Yang

Advanced Energy Materials, 2025, 15
DOI: 10.1002/aenm.202502125

Lithium Metal Batteries Enabled by Ion Flux‐Regulating Coating on Separator

Ke Wang, Teng Zhao, Ruixin Lv, Wangming Tang, Tianyang Yu, Li Li, Feng Wu and Renjie Chen

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202508164

Harnessing Stable Electrode–Electrolyte Interface/Interphase Dynamics via Electrolyte Additives: Rationalized Pathways to Practical Aqueous Zinc‐Ion Batteries

Linhui Chang, Jiamin Li, Le Zhang, Qiangchao Sun, Xionggang Lu and Hongwei Cheng

Small, 2025, 21
DOI: 10.1002/smll.202507546

Hydrogen Atom Capture Toward Dense Solid Electrolyte Interface for Long‐Cycling Aqueous Zinc‐Ion Batteries

Yuxin Yuan, Jianping Chen, Tianyue Qian, Bowen Zhang, Ke Ye, Ruimin Li and Xiaowei Yang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202513722

Robust metal-based composite layer enabling enhanced interface stability for highly reversible zinc anodes

Chengwu Yang, Pattaraporn Woottapanit, Qizhi Hou, Zhiqiang Dai, Wanwisa Limphirat, Jiaqian Qin and Xinyu Zhang

Journal of Energy Chemistry, 2026, 117, 635
DOI: 10.1016/j.jechem.2026.02.045

Multiscale Interfacial Regulation for Stable Zinc Anodes: From Fundamental Mechanisms to Practical Applications

Yuexin Liu, Tianyu Zhang, Zian Li, Zhongqing Ma and Yong Hu

Advanced Energy Materials, 2026
DOI: 10.1002/aenm.70704

Electron‐Induced Molecular Programming Drives Interfacial Chemistry for Ah‐Level Zinc Batteries

Feifei Wang, Yuhang Zhuang, Jiwei Shi, Haojie Zhang, Peng Zhang, Songshan Bi, Hyejung Yang, Wenqiang Yang, Stuart S. P. Parkin, Chunpeng Yang, Quan‐Hong Yang, Ali Shaygan Nia and Xinliang Feng

Advanced Materials, 2026
DOI: 10.1002/adma.72891

Hydrogen Atom Capture Toward Dense Solid Electrolyte Interface for Long‐Cycling Aqueous Zinc‐Ion Batteries

Yuxin Yuan, Jianping Chen, Tianyue Qian, Bowen Zhang, Ke Ye, Ruimin Li and Xiaowei Yang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202513722

Smart Self‐Healing Anode/Electrolyte Interphases for Stabilizing Zn Anode

Haifeng Bian, Congcong Li, Ge Xue, Hao Wu, Biao Wang, Fengqi Li, Duan Bin, Hongbin Lu and Xiangkang Meng

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202505982

Rational Design of a Bilayer Interface for Long‐Term Stability of Zn Anodes and MnO2 Cathodes

Kaiping Zhu, Wubin Zhuang, Nanyang Wang, Kai Zhang, Lin Lin, Zhipeng Shao, Chaowei Li, Wenhui Wang, Shizhuo Liu, Peng Yang, Pan Xue, Qichong Zhang, Guo Hong and Yagang Yao

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202502366

Unveiling Ion Pairing Reorganization Mechanism of Oxygen Vacancy‐Rich Amorphous Molybdenum Oxide‐Based Solid‐Electrolyte Interphase for Fast Zn2+ Desolvation

Mingze Xu, Xiaoyang He, Shujie Xue, Xin Xiao, Jianying Wang, Shuo Meng, Qiang Xu and Zuofeng Chen

Advanced Energy Materials, 2026, 16
DOI: 10.1002/aenm.202503167

Dual-strategy stabilization of zinc anodes through solvation regulation and interfacial engineering in aqueous zinc ion batteries

Weilin Yan, Yifan Wang, Lufan Liu, Feiyu Tao, Yang Huang, Zhaoqian Li, Li'e Mo, Hong Zhang and Linhua Hu

Chemical Engineering Journal, 2025, 524, 168877
DOI: 10.1016/j.cej.2025.168877

Citric Acid Induced Dual‐Function Electric Double Layer for High Capacity and Stable Zinc Metal Batteries

Kexin He, Lifeng Zhang, Jin Zhang, Lei Wang, Chenxi Zhao and Xiaojuan Lai

Advanced Sustainable Systems, 2026, 10
DOI: 10.1002/adsu.202501683

Research progress on in-situ strategies for modulating the anode/electrolyte interface in zinc-ion batteries

Ruiqi Liu, Fu Wan, Da Yang, Yupeng Lin, Wenwei Yin and Weigen Chen

Applied Energy, 2026, 412, 127689
DOI: 10.1016/j.apenergy.2026.127689

3D-Printed Hierarchically Porous MOF-Derived Cathodes for Realizing High-Performance Flexible Quasi-Solid-State Aqueous Zinc–Cobalt Batteries

Ningning Chu, Tenghui Wang, Zhengyang Guo, Xueliang Li, Hui Wang, Tingting Xu, Jinhao Zang, Ye Wang, Xinjian Li, Yongsong Luo, Hui Ying Yang and Dezhi Kong

ACS Nano, 2025, 19, 29327
DOI: 10.1021/acsnano.5c05876

In Situ Construction of an Amorphous and Ultrathin Manganese Oxide Protective Layer for Highly Stable Zinc Anodes

Xianyu Liu, Binxin Song, Haoxuan Jing, Yingchun Xiao, Xinyu Wang, Hongmei Cao and Baojuan Xi

ACS Sustainable Chem. Eng., 2025, 13, 15007
DOI: 10.1021/acssuschemeng.5c05334

Construction of Metal‐Organic Interface Layers via Highly Expandable Wet Etching for High Stability Zinc Anode

Ziming Wan, Weihua Zhou, Zhuo Chen, Jian Wang, Haoyu Feng, Lin Sheng, Junrun Feng and Zhangxiang Hao

Small, 2025, 21
DOI: 10.1002/smll.202502128

High Stability Alkaline Zinc‐Ferricyanide Flow Battery With Multi‐Coordination Electrolyte Additive for Suppressing Zinc Pulverization

Yalu Xin, Chen Li and Wei Gao

Small, 2026, 22
DOI: 10.1002/smll.202506912

Trace metal diatomic interphase via microwave pyrolysis enables zinc binder-free anode

Ruiyu Zhu, Liyan Tian, Hua Zhang, Yewen Meng, Xiangyue Yan, Xi Ren and Jun Zhou

Chemical Engineering Journal, 2025, 520, 166334
DOI: 10.1016/j.cej.2025.166334

Building π–π-conjugated molecule adsorption layer on Zn anode for ultra-stable aqueous zinc-ion batteries

Haofan Weng, Yixin Zhang, Xinyi Zhou, Xiaoming Lou, Weihua Xu, Jin Tao and Huibing He

eScience, 2026, 100580
DOI: 10.1016/j.esci.2026.100580

Epitaxial Substrate Engineering Enables Ultrastable Zinc Anodes via Low‐Lattice‐Mismatch Interface‐Induced Dendrite Regulation

Ying Li, Yi‐Han Zhao, Jingyu Wang, Dinghao Xu, Yuange Wang, Pengfei Wang, Zonglin Liu, Qinzhi Lai, Jie Shu, Qianyu Zhang and Ting‐Feng Yi

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202509963

Cu-doped ZnO nanoarray trap enabling uniform Zn deposition for high-performance Zn-ion batteries

Lu Wu, Yurong Zhu, Yu Liu, Li Yang, Lin Xu and Liqiang Mai

Transactions of Materials Research, 2025, 1, 100097
DOI: 10.1016/j.tramat.2025.100097