High energy density lithium battery systems: from key cathode materials to pouch cell design

Chengrong Xu, Bo Peng, Wujie Yang, Jiaming Tian and Haoshen Zhou

Chem. Soc. Rev., 2025, 54, 10245
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Lattice-coherent epitaxial surface engineering in highly stable Co-free ultrahigh-Ni cathodes

Fuqiren Guo, Liangchi Yang, Shuli Zheng, Xianyan Qiao, Heng Zhang, Yong Ming, Fang Wan, Zhenguo Wu, Lang Qiu and Xiaodong Guo

Energy Environ. Sci., 2026, 19, 1159
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Electrolyte design weakens lithium-ion solvation for a fast-charging and long-cycling Si anode

Min Li, Shuai Li, Dong Yan, Yuhao Ma, Xiaobin Niu and Liping Wang

Chem. Sci., 2025, 16, 2609
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An asymmetric functional gel polymer electrolyte enables superior interfacial compatibility for wide temperature lithium metal batteries

Haixia Yang, Jiaxin Yan, Shuyang Gao, Xin Chen, Yuanheng Wang, Hua Huo, Chuankai Fu, Chunyu Du and Pengjian Zuo

Energy Environ. Sci., 2025, 18, 9854
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Establishing a long-term stable cathode–electrolyte interphase through multi-cationic competitive coordination for 4.6 V LiCoO2

Yujie Wang, Tingting Cui, Netanel Shpigel, Zihao Meng, Fuhui Liang, Tianju Fan and Yonggang Min

J. Mater. Chem. A, 2025, 13, 14972
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An all-fluorinated electrolyte based on a fluorinated cosolvent toward a high-voltage LRMO cathode

Yuyu Ban, Feng Hai, Weicheng Xue, Wentao Yan, Yunxiao Yang, Xin Gao and Mingtao Li

J. Mater. Chem. A, 2025, 13, 32391
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Molecular tailoring of electrolyte solvents for high-performance lithium–metal batteries beyond temperature and voltage boundaries

Dejie Qu, Youlong Sun, Tao Liu, Guicun Li, Yuewei Yan, Tiantian Dong, Lang Huang, Gaojie Xu, Aobing Du, Lei Hu, Shanmu Dong, Bo Tang and Guanglei Cui

Mater. Horiz., 2026, 13, 1203
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Conjugated topologically confined composite electrolytes for robust high-voltage and high-temperature semi-solid-state lithium metal batteries

Wang Xu, Yongbiao Mu, Yaoyu Yin, Anjun Hu, Yuanjian Li, Jian Wang, Qi Liu, Jianping Long, Lin Zeng and Shimou Chen

Energy Environ. Sci., 2026, 19, 384
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Mechanistic Insights into Tris(trimethylsilyl) Phosphite as an Electrolyte Additive: Acid Scavenging and Triggering of FEC Degradation

Yiyang Pan, Tairan Wang, Ruru Song, Cuili Zhang, Lang Wang, Shengbo Lu, Tracy Chenmin Liu, Shihan Qi, Weiguo Huang, Jingjing Liu, Guannan Zhu and Jun Fan

J. Phys. Chem. C, 2025, 129, 15597
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A Non‐Concentrated Gradient‐Solvation Electrolyte Enables a High‐Voltage Lithium Metal Battery with 447.6 Wh Kg−1

Hao Wang, Dong Yan, Hongyu Liu, Shuai Li, Xiaobin Niu, Chuying Ouyang, Hong Li and Liping Wang

Advanced Materials, 2025, 37
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Mitigating Surface Irreversible Layer‐To‐Spinel Phase Transition for Stable and Ultrahigh‐Capacity LiCoO2 Cathodes

Haocong Yi, Wenguang Zhao, Yutong Lin, Zijian Li, Shengyu Wu, Hengyu Ren, Yuhao Du, Xiaohu Wang, Chengkai Yang, Zirui Lou, Feng Pan and Qinghe Zhao

Small, 2025, 21
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Cyano-Enriched Auxiliary Salts Mitigating Corrosion-Induced Crosstalk in Sulfonimide Salt Electrolytes toward Long-Life High-Safety Lithium Metal Batteries

Shenghang Zhang, Fu Sun, Xiangchun Zhuang, Lixuan Yang, Rongxian Wu, Bin Xie, Jiedong Li, Shitao Wang, Lixin Qiao, Jinzhi Wang, André Hilger, Ingo Manke, Shanmu Dong, Zili Cui, Gaojie Xu and Guanglei Cui

ACS Energy Lett., 2026, 11, 864
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The design of novel lithium salt additives: 4-benzonitrile-1,3-double (trimethylboric acid) lithium (LBTA) to endow inherent superior stability in high voltage lithium ion batteries

Lucheng Li, Meiling Liu, Peng Yang, Wenfeng Yuan and Jun Chen

Chemical Engineering Journal, 2025, 511, 162078
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Precise Fluorination Strategy of Solvent via Local‐to‐Global Design Toward High‐Voltage and Safe Li‐Ion Batteries

Yuting Wang, Li Yang, Guan Wu, Heng Dong, Ruitao Sun, Junfei Li, Weijie Ding, Jinjin Zhu and Chao Yang

Carbon Energy, 2025, 7
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Unexpected Planar Gliding and Microcracking Induced by Neutron Irradiation in Single-Crystalline LiCoO2 Cathodes

Kang Wu, Lihua Mo, Tiancheng Yi, Zhigang Zhang, Yoshihiro Kuroiwa, Sangwook Kim, Peilin Ran, Wen Yin, Fangwei Wang, Quanzhi Yu, Tianjiao Liang, Jinkui Zhao and Enyue Zhao

ACS Energy Lett., 2025, 10, 2701
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Achieving Uniform Ti/P Co‐Modifications for Optimized Li+ Transport Kinetics of LiCoO2

Changfa Sun, Hengyu Ren, Xiaohu Wang, Haocheng Ji, Haocong Yi, Wenguang Zhao, Lin Zhou, Qinghe Zhao and Feng Pan

Adv Funct Materials, 2025, 35
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In situ Crystal Structure Growth and Control for Enhancing Comprehensive Performance in Ultra‐High Nickel‐Layered Lithium Cathodes

Yingshuang Sun, Congcong Li, Jun Chen, Kejun Zhang, Wenhai Ji, Rui Wang, Maolin Yang, Ping Miao, Zijian Wang, Ziwei Chen and Qinghua Zhang

Angew Chem Int Ed, 2026, 65
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Electrolyte Design Strategies for High‐Energy‐Density Li/Na/K‐Metal Batteries Toward Grid‐Scale Energy Storage: From Liquid to Solid

Hui Shao, Zhiwei Ni and Jinkui Feng

Energy & Environ Materials, 2026
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A Weakly‐Solvating Propylene Carbonate Electrolyte for High‐Voltage and Low‐Temperature Lithium‐Ion Batteries

Chaonan Wang, Shaoyun Zhou, Zetai Xu, Jiaxuan She, Qiang Xiao, Rong Huang, Yi Cui, Yuhao Lu, Hongchang Jin and Hengxing Ji

Angewandte Chemie, 2025, 137
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In situ Crystal Structure Growth and Control for Enhancing Comprehensive Performance in Ultra‐High Nickel‐Layered Lithium Cathodes

Yingshuang Sun, Congcong Li, Jun Chen, Kejun Zhang, Wenhai Ji, Rui Wang, Maolin Yang, Ping Miao, Zijian Wang, Ziwei Chen and Qinghua Zhang

Angewandte Chemie, 2026, 138
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Ethylene carbonate-free electrolytes toward better lithium-ion batteries

Yu Wu, Zhaochen Ran, Yalun Li, Yong Peng, Lihong Gao, Dongsheng Ren, Zhuang Ma, Chengshan Xu, Xuning Feng, Li Wang, Languang Lu, Jitao Chen, Xiangming He and Minggao Ouyang

Joule, 2026, 10, 102274
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Simultaneous enhancement of cathode and anode interfacial stability in high-voltage LiCoO₂–Si/C batteries through a hydrogen-free multi-cyano ligand inorganic salt electrolyte additive

Haoyi Yang, Pan Luo, Nan Sun, Sichen Jiao, Jinming Yue, Bowei Cao, Junjie Song, Quan Li, Xiqian Yu, Hong Li and Xuejie Huang

Energy Storage Materials, 2025, 83, 104703
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Interphase engineering via nucleophilic reaction for ultra-stable 4.8 V Li-rich Mn-based batteries with 520 Wh kg-1

Xianggang Gao, Xiaozhi Jiang, Lei Wang, Juanlang Guo, Bowen Zhu, Yi Zhang, Yaxuan Fu, Zhendong Yang, Jian Zhao, Fangyan Liu, Tsz-woon Benedict Lo, Cong Lin, Shu Hong, Bo Hong, Yanqing Lai and Zhian Zhang

Energy Storage Materials, 2026, 88, 105079
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Additive‐Regulated Interface Chemistry Enables Depolarization for Ultra‐High Capacity LiCoO2

Guorui Zheng, Hengyu Ren, Jimin Qiu, Haowen Ding, Likun Chen, Yuhang Li, Shunning Li, Ming Liu and Feng Pan

Advanced Materials, 2025, 37
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Reinvented sodium anode by creating a metal-bulk storage matrix with an expanded 3D plating/stripping mechanism

Chutao Wang, Kun Wang, Hongbin Ni, Congcong Du, Xiaoting Yin, Jingmin Fan, Ruming Yuan, Yuxin Tang, Jiawei Yan, Mingsen Zheng and Quanfeng Dong

Sci. Adv., 2025, 11
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Enhancing stability and rate performance of Li 2DHBQ cathodes in lithium-ion batteries via FEC-derived cathode–electrolyte interphase

Yonglin Wang, Zhe Huang and Yuning Li

Nano Research, 2025, 18, 94907761
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Defect‐Mediated Heteroepitaxial Co‐Regeneration Strategy for Direct Regeneration of Spent Cathodes Materials

Le Tian, Fanbin Hu, Enhua Dong, Jinhua Shi, Yun Luo, Qingfeng Liu, Yingjie Zhang, Zitong Fei, Qi Meng and Peng Dong

Advanced Energy Materials, 2025, 15
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Propyl propionate enabling stable operation of 4.55 V LiCoO2/graphite pouch cells at various temperatures via solvation and interface modulation

Shiran Li, Yu Zhang, Xiao-Zhong Fan, Xiaomeng Wang, Gupei Ding, Weiguo Li, Xu-Feng Zang, Miaomiao Han and Long Kong

Chemical Engineering Journal, 2026, 536, 175767
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In situ multifunctional surface design for high-performance 4.6 V LiCoO2

Shiyou Wu, Tongxing Lei, Zhiyu Ding, Jun Wei and Junwei Wu

Chemical Engineering Journal, 2025, 515, 163516
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A Weak-Fluorine-Bond Molecule Stabilizes Hard Carbon Anodes for Practical Sodium-Ion Batteries

Yaqi Liao, Han Liu, Yangqian Zhang, Jiayi Yang, Haijin Ji, Donghai Wang, Lixia Yuan, Yunhui Huang and Yang Ren

ACS Nano, 2025, 19, 30466
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Surface Reconstruction Enables High‐Voltage, Long‐Life All‐Solid‐State Batteries

Hang Liu, Wei Mao, Chuanchao Sheng, Peng Wang, Sixie Yang, Ping He and Haoshen Zhou

Adv Funct Materials, 2026, 36
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Molecular engineering of cyano-functionalized biopolymer binders enabling interfacial stabilization of 4.6-V LiCoO2 cathodes under high-areal-capacity

Xiangyi Ye, Fei Song, Qiangqiang Zhang, Dejian Cheng, Guangzhao Zhang, Zhongbo Liu, Yong Zeng, Yinghao Xia, Siquan Cai, Hongbo Zeng, Yonghong Deng and Chaoyang Wang

Nano Energy, 2025, 145, 111416
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Electrolyte Chemistry Towards Ultra‐High Voltage (4.7 V) And Ultra‐Wide Temperature (−30 to 70 °C) LiCoO2 Batteries

Wenming Yang, Wen Chen, Hanqing Zou, Jiawei Lai, Xueyi Zeng, Yuping Zhang, Xing Zeng, Kui Ding, Shiwei Zhang, Liang Ma, Zhongliang Li and Qifeng Zheng

Angew Chem Int Ed, 2025, 64
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The role of flame-retardant electrolytes in lithium-ion batteries: Custom design for improved battery-level safety

Yaxuan Fu, Xiaozhi Jiang, Chenyang Shi, Long Chen, Zhendong Yang, Mengran Wang, Bo Hong, Faping Zhong and Yanqing Lai

Chinese Chemical Letters, 2026, 37, 110972
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Cation–Anion Regulation Engineering in a Flame-Retardant Electrolyte toward Safe Na-Ion Batteries with Appealing Stability

Yi-Hu Feng, Chengye Lin, Hanwen Qin, Guang-Xu Wei, Chao Yang, Yongwei Tang, Xu Zhu, Shuai Sun, Tian-Ling Chen, Mengting Liu, Hong Zheng, Xiao Ji, Ya You and Peng-Fei Wang

J. Am. Chem. Soc., 2025, 147, 16107
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Low‐Concentration Electrolyte Engineering for Rechargeable Batteries

Zijun Wang, Xiaolin Guo, Yueyao Dong, Wenjie Qu, Ke Wang, Liwei Dong, Chunhui Yang, Zuotao Lei and Jia‐Yan Liang

Advanced Materials, 2025, 37
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Stabilizing Cathode‐Electrolyte Interface by Low‐Cost Ethyl Methylsulfone Co‐Solvent for High‐Voltage Sodium‐ion Batteries

Xinran Hu, Wenxi Hu, Deda Peng, Xiaowei Liu, Xing Zhou, Meilong Wang, Yongyuan Zhou, Jin Han, Tiefeng Liu and Ya You

Batteries & Supercaps, 2025, 8
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Applications of advanced magnetic characterization techniques in energy storage

Fei Wang, Haining Liu, Mingyue Ruan and Qiang Li

Sci. China Chem., 2026
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Electrochemical Self‐Assembly of Boron‐Based Cathode‐Electrolyte Interphase to Stabilize 4.65 V LiCoO2

Hengyu Ren, Xiaohu Wang, Wangyang Ding, Chunyu Xu, Wenguang Zhao, Haocheng Ji, Haocong Yi, Zhaohuang Zhan, Yongli Song, Lin Zhou, Qinghe Zhao and Feng Pan

Adv Funct Materials, 2025, 35
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Localized Deep Eutectic Electrolytes for Durable 4.8 V Lithium Metal Batteries

Tongrui Zhang, Jiangtao Yu, Cheng Yang, Linrong Wu, Yang Feng, Libo Song, Boyuan Li, Limin Zhou, Weiwei Xie, Yong Lu, Tianjun Lu, Jun Chen and Kai Zhang

J. Am. Chem. Soc., 2026
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Non-monotonic engineering of isomeric solvents for high-voltage Li-ion batteries with Si/C anodes

Kerui Zhang, Dong Yan, Liping Wang, Shihong Qing, Jian Gao, Haining Ji and Xiaobin Niu

Journal of Colloid and Interface Science, 2026, 713, 140207
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Improve the Internal and Interface Stability of Sulfide‐Based Composite Electrolytes Through High Concentration Electrolyte and Continuous Li+ Conductive Frameworks

Jie Zhang, Chengshuai Bao, Jun Jin, Jiajie Wen and Zhaoyin Wen

Small Methods, 2026, 10
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Helical Branched Gel Polymer Electrolytes for 4.6V‐Class Lithium Metal Batteries

Wang Xu, Anjun Hu, Ruixin Zheng, Yuanjian Li, Kai Chen, Jingze Chen, Zhen Wang, Ruize Xu, Jian Wang, Fei Li, Jianping Long and Feixiang Wu

Adv Funct Materials, 2026, 36
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Unlocking Stable Operation of All‐Climate 4.6 V High‐Rate LiCoO2 Batteries by Potential‐Dependent Interphase Engineering

Jun Gan, Shuai Chen, Yuanqin Li, Chengfeng Li, Changyong Mo, Kuan Zhou, Youhao Liao, Zhexi Xiao and Weishan Li

Adv Funct Materials, 2026, 36
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Polyphosphates‐Based Cathode‐Electrolyte Interphase for 4.65 V LiCoO2

Hengyu Ren, Xiaohu Wang, Wenwei Cai, Wenguang Zhao, Kunchen Xie, Dongwen Zou, Tao Zeng, Funing Yu, Zhikang Deng, Haocong Yi, Chunyu Xu, Wenhua Zhang, Shunning Li, Qinghe Zhao and Feng Pan

Advanced Materials, 2026
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Electrolyte Chemistry Towards Ultra‐High Voltage (4.7 V) And Ultra‐Wide Temperature (−30 to 70 °C) LiCoO2 Batteries

Wenming Yang, Wen Chen, Hanqing Zou, Jiawei Lai, Xueyi Zeng, Yuping Zhang, Xing Zeng, Kui Ding, Shiwei Zhang, Liang Ma, Zhongliang Li and Qifeng Zheng

Angewandte Chemie, 2025, 137
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Nonflammable localized high-concentration phosphazene electrolytes for enhanced safety and interfacial stability in high-voltage lithium metal batteries

Dianfa Zhao, Guanghui Cui, Wei Liu and Zhanpeng Wu

Electrochimica Acta, 2025, 537, 146884
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Stabilizing Surface Lattice On− (0 < n < 2) for Long‐Term Durability of LiCoO2

Wenguang Zhao, Mingyang Li, Zijian Li, Hengyu Ren, Xiaohu Wang, Xingxing Yin, Wangyang Ding, Guojie Chen, Shiming Chen, Haocong Yi, Shunning Li, Jun Wang, Dong Zhou, Lin Zhou, Hai Lin, Bin Fei, Feng Pan and Qinghe Zhao

Angewandte Chemie, 2025, 137
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Cyanide-driven double-layer regulation enables long-lifespan cycling of high-voltage quasi-solid-state lithium metal batteries

Zixuan Wang, Jialong Fu, Zhiyong Li, Lu Wei and Xin Guo

Energy Storage Materials, 2026, 84, 104782
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Reevaluating the Effect of a LiF-Containing Solid Electrolyte Interphase on Lithium Metal Anodes

Chengkun Liu, Kaixiang Ren, Shilin Wu, Yuhang Zhang, Hai-Wen Li, Meng Yao, Zhipeng Jiang and Yongtao Li

Nano Lett., 2025, 25, 7762
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Engineering Surface Oxygen Vacancies Buffer Achieving Ultrahigh-Voltage LiCoO2

Muhammad Imran, Zhongsheng Dai, Fiaz Hussain, Renjie Chen, Feng Wu and Li Li

ACS Nano, 2025, 19, 29372
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Tuning the additive participation in cathode-electrolyte-interphase construction via competitive adsorption for high-voltage LiCoO2

Ziwei Liu, Lingfeng Shi, Yuangui Liu, Chi Ma, Guangxiang Zhang, Shuai Li, Wei Zhao, Chunyu Du, Hua Huo, Geping Yin, Rui Guo and Yulin Ma

Journal of Energy Chemistry, 2026, 117, 386
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Utilizing the Elimination Reaction of Linear Fluorinated Carbonate to Stabilize LiCoO2 Cathode up to 4.6 V

Siyu Zhou, Jixiang Yang, Cheng Zhen, M. Danny Gu and Minhua Shao

Advanced Materials, 2025, 37
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Trace high-valence ions induced surface coherent phase stabilized high voltage LiCoO2

Muhammad Imran, Zhongsheng Dai, Fiaz Hussain, Wei Xia, Renjie Chen, Feng Wu and Li Li

Energy Storage Materials, 2025, 74, 103950
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Engineering durable interphases for high-voltage Li-ion batteries under thermal stress

Shiming Chen, Wenguang Zhao, Guorui Zheng, Chenyu Yang, Taowen Chen, Hengyu Ren, Yue Zuo, Xiangming Yao, Ke Li, Haoyu Xue, Jianjun Fang, Yuxiang Huang, Kai Yang, Zu-Wei Yin, Luyi Yang and Feng Pan

National Science Review, 2025, 12
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Stabilizing Surface Lattice On− (0 < n < 2) for Long‐Term Durability of LiCoO2

Wenguang Zhao, Mingyang Li, Zijian Li, Hengyu Ren, Xiaohu Wang, Xingxing Yin, Wangyang Ding, Guojie Chen, Shiming Chen, Haocong Yi, Shunning Li, Jun Wang, Dong Zhou, Lin Zhou, Hai Lin, Bin Fei, Feng Pan and Qinghe Zhao

Angew Chem Int Ed, 2025, 64
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A Weakly‐Solvating Propylene Carbonate Electrolyte for High‐Voltage and Low‐Temperature Lithium‐Ion Batteries

Chaonan Wang, Shaoyun Zhou, Zetai Xu, Jiaxuan She, Qiang Xiao, Rong Huang, Yi Cui, Yuhao Lu, Hongchang Jin and Hengxing Ji

Angew Chem Int Ed, 2025, 64
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Phytate lithium cross-linked polyacrylamide aqueous binder mediated LiF-rich cathode electrolyte interphase stabilizes 4.6 V LiCoO2

Xiaofeng Wu, Xinye Mai, Fangchang Zhang, Yulin Cao, Wen Luo, Yongcong Huang, Hongzhi Wang, Kuan Jing, Cheng Wang, Fangzheng Liu, Chunyu Liu, Zhenyao Wei, Huanzhu Lv, Yanfang Wang, Kaili Zhang, Yingzhi Li and Zhouguang Lu

Chemical Engineering Journal, 2026, 532, 173771
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Unlocking fast and reversible sodium intercalation in Na 3MnTi(PO 4) 3 cathode toward high performance sodium-ion batteries

Miaorui Yang, Shengping Deng, Shuoshuo Cheng, Jingwen Zhao, Shiyu Li and Ying Bai

Nano Research, 2025, 18, 94907561
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The Resurrection of Fe in layered cathode materials for sodium-ion batteries

Zongyu Guan, Guoyao Pang, Meng Li, Haoxiang Zhuo, Kuan Wang, Jiangtao Hu, Biwei Xiao and Weidong Zhuang

Materials Today, 2025, 87, 176
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One Stone for Multiple Birds: Copolymer with Multifunctional Groups Boosts the Cycling Stability of Lithium Cobalt Oxide Cathodes at 4.5 V

Yuan Peng, Mengtong Xie, Dishu Zeng, Huimin Chen, Xuli Chen, Jiangtao Xu, Zhanglin Shi, Xiaoming Yang, Yaobang Li, Yucong Jiao, Zhaohui Wang and Kunkun Guo

ACS Appl. Mater. Interfaces, 2025, 17, 2224
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Optimizing the electrochemical performance of LiCoO2 at 4.5 V via synergistic modification of Mg2+ ion doping and Li1.3La0.3Ti1.7(PO4)3 coating

Gaoqiang Mao, Jingfan Lu, Haiyan Cai, Wanjing Yu, Hui Tong, Xueyi Guo, Leiying Zeng and Long Jiang

Adv Compos Hybrid Mater, 2025, 8
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Modulating surface reconstruction of LiNi 0.8Co 0.1Mn 0.1O 2 via simply blending the nano-sized LiCoO 2 particles in electrode

Jiaxuan Hu, Hengyu Ren, Xiaohu Wang, Zijian Li, Wenguang Zhao, Haocong Yi, Feng Pan and Qinghe Zhao

Nano Research, 2025, 18, 94907576
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