An easy-to-perform evaluation of steric properties of Lewis acids

Ludwig Zapf, Melanie Riethmann, Steffen A. Föhrenbacher, Maik Finze and Udo Radius

Chem. Sci., 2023, 14, 2275
DOI: 10.1039/D3SC00037K

Nickel boryl complexes and nickel-catalyzed alkyne borylation

Lukas Tendera, Felipe Fantuzzi, Todd B. Marder and Udo Radius

Chem. Sci., 2023, 14, 2215
DOI: 10.1039/D2SC04690C

Visible-light-driven TTST enables divergent synthesis of trifluoromethylated and trifluoromethylthiolated products through chemo- and regioselectivity

Shuo Li, Hao Zheng, Yuyan Xu, Chuchu Xie, Jie Sun and Zhiwei Chen

Green Chem., 2025, 27, 11466
DOI: 10.1039/D5GC02793D

Bis(neopentylglycolato)diboron (B2nep2) as a bidentate ligand and a reducing agent for early transition metal chlorides giving MCl4(B2nep2) complexes

Hiromu Hosoya, Takuya Akiyama, Kazushi Mashima and Hayato Tsurugi

Dalton Trans., 2023, 52, 13154
DOI: 10.1039/D3DT01828H

Metal-free radical borylations: mechanisms, catalytic strategies, and synthetic applications

Ziyi Quan, Yaxu Liu, Qidi Zhong and Bo Wang

Chem. Sci., 2026, 17, 1534
DOI: 10.1039/D5SC08322B

Modular assembly of amines and diborons with photocatalysis enabled halogen atom transfer of organohalides for C(sp3)–C(sp3) bond formation

Rong-Bin Liang, Ting-Ting Miao, Xiang-Rui Li, Jia-Bo Huang, Shao-Fei Ni, Sanliang Li, Qing-Xiao Tong and Jian-Ji Zhong

Chem. Sci., 2025, 16, 3580
DOI: 10.1039/D5SC00190K

Boron–boron bonds: boldly breaking boundaries towards amine- and peroxide-free 2K radical polymerization

Florian Pieringer, Konstantin Knaipp, Robert Liska, Norbert Moszner, Yohann Catel, Georg Gescheidt and Patrick Knaack

Polym. Chem., 2024, 15, 3127
DOI: 10.1039/D4PY00445K

Visible light induced boryl radical and its application in reduction of unsaturated XO (X = C, N, S) bonds

Lingfeng Yin, Guanglong Huang, Xiuhua Lin, Xinluo Song, Yanqi Chen, Tianhong Yan, Mingde Li and Li Dang

Org. Chem. Front., 2023, 10, 4623
DOI: 10.1039/D3QO00808H

On the Reactivity of a NHC Nickel Bis‐Boryl Complex: Reductive Elimination and Formation of Mono‐Boryl Complexes

Lukas Tendera, Laura Kuehn, Todd B. Marder and Udo Radius

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302310

Photoinduced Radical Borylation of Robust Carbon–Heteroatom Bonds

Ya‐Ming Tian, Xiang Pu, Alejandro Heredero Sánchez, Wagner Silva, Ruth M. Gschwind and Burkhard König

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202400547

Zur Dekarbonisierung N‐Heterocyclischer Carbene (NHCs): Die einfachen Alan‐Addukte (NHC) ⋅ AlR3 (R=H, Me, Et)

Luis Werner and Udo Radius

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202403639

N-Heterocyclic Carbene Switchable Radical- or Benzyne-Meditated Arylation of Thiols Using DMF/KOt-Bu

Johannes Puschnig and Ben W. Greatrex

Synlett, 2025, 36, 884
DOI: 10.1055/a-2460-8302

Efficient system for facile access to ortho-substituted aryl boronates through palladium-catalysed borylation

Jairus L. Lamola, Paseka T. Moshapo, Cedric W. Holzapfel, Banothile C.E. Makhubela and Munaka Christopher Maumela

Tetrahedron Letters, 2023, 120, 154432
DOI: 10.1016/j.tetlet.2023.154432

2,3‐Diboratabutadiene Complexes of Group 4 Metals and their Donor‐Induced Oxidative Cleavage to Methyleneboranes

Philipp Grewelinger, Carsten Präsang, Bernd Morgenstern and David Scheschkewitz

ChemistryEurope, 2025, 3
DOI: 10.1002/ceur.202500153

Base-Free Borylation of Aryl Halides Enabled by Zn-Promoted Halide Abstraction

Brittany L. Gay, Lauren A. Prendeville, Ya-Nong Wang and Kami L. Hull

Org. Lett., 2024, 26, 10481
DOI: 10.1021/acs.orglett.4c03821

Neutral Boryl Radicals in Mixed‐Valent B(III)Br‐B(II) Adducts

Tong‐Tong Liu, Jiaxin Chen, Xin‐Lei Chen, Li Ma, Bing‐Tao Guan, Zhenyang Lin and Zhang‐Jie Shi

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202634

Pyridine‐Boryl Radical Mediated Decarboxylative Homolytic Substitution of N‐hydroxyphthalimide Ester with Ar2X2 (X=S, Se)

Jia Cao, Liuzhou Gao, Guoqiang Wang and Shuhua Li

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202201290

Preparation of Mono and Bis‐Hydrazino‐Substituted N‐Heterocyclic Carbene Boranes

Romane Bellec, Romain Godelier, Lionel Joucla, Anne Renault and Emmanuel Lacôte

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300806

A Crystalline Monomeric Diboryl Diazene

Fengbo Huang, Xin-Feng Wang, Baixu Ma, Lizhi Tao, Lingbing Kong, Liu Leo Liu and Qiuming Liang

J. Am. Chem. Soc., 2025, 147, 37919
DOI: 10.1021/jacs.5c14754

Triflylpyridinium Enables Rapid and Scalable Controlled Reduction of Carboxylic Acids to Aldehydes using Pinacolborane

Du Chen, Liangxuan Xu, Yi Yu, Qinliang Mo, Xiaotian Qi and Chao Liu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202215168

Direct B–H Functionalization of Icosahedral Carboranes via Hydrogen Atom Transfer

Hongyuan Ren, Ping Zhang, Jingkai Xu, Wenli Ma, Deshuang Tu, Chang-sheng Lu and Hong Yan

J. Am. Chem. Soc., 2023, 145, 7638
DOI: 10.1021/jacs.3c01314

Photoinduced Dehydrogenative Borylation via Dihydrogen Bond Bridged Electron Donor and Acceptor Complexes**

Zhiyong Wang, Jiaxin Chen, Zhenyang Lin and Yangjian Quan

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203053

Metal-Free One-Pot Multi-Functionalization of Unsaturated Compounds with Interelement Compounds by Radical Process

Yuki Yamamoto and Akiya Ogawa

Molecules, 2023, 28, 787
DOI: 10.3390/molecules28020787

Triflylpyridinium Enables Rapid and Scalable Controlled Reduction of Carboxylic Acids to Aldehydes using Pinacolborane

Du Chen, Liangxuan Xu, Yi Yu, Qinliang Mo, Xiaotian Qi and Chao Liu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202215168

Zinc Complexes Supported by Hydroxyl‐Containing Schiff‐Base Ligands as Efficient Catalysts for the Borylation of Aryl Iodides

Mengxiang Wu, Chaohong Jia, Ling Chen, Xue Gao, Biqin Wang and Yahong Li

Asian J Org Chem, 2024, 13
DOI: 10.1002/ajoc.202400247

How to Decarbonize N‐Heterocyclic Carbenes (NHCs): The simple Alane Adducts (NHC) ⋅ AlR3 (R=H, Me, Et)

Luis Werner and Udo Radius

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202403639

Reaction of 4‐Bpin‐o‐Carborane with Ketones: Sequential Carbon Vertex Alkylation and B−B Bond Activation

Zhen Nie, Ruofei Cheng, Zaozao Qiu and Zuowei Xie

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300598

NHC‐Stabilized Dialanes(4) of Al2Mes4

Luis Werner, Julika Hagn and Udo Radius

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202303111