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Green hydroboration of carboxylic acids and mechanism investigation

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Lithium and magnesium complexes by using pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and application as catalysts for the hydroboration of carbonyl compounds

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Lithium compounds as single site catalysts for hydroboration of alkenes and alkynes

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Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides

Milan Kumar Bisai, Kritika Gour, Tamal Das, Kumar Vanka and Sakya S. Sen

Dalton Trans., 2021, 50, 2354
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Low-valent germanium and tin hydrides as catalysts for hydroboration, hydrodeoxygenation (HDO), and hydrodesulfurization (HDS) of heterocumulenes

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CeO2–nanocubes as efficient and selective catalysts for the hydroboration of carbonyl groups

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Lithium amide catalyzed hydroboration of nitriles

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Recent advances in the catalytic hydroboration of carbonyl compounds

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Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis

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A bis-dianionic β-ketoiminato octalithium complex as a universal catalyst for hydroboration with broad scope

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Syntheses of asymmetrical magnesium(i) complexes and their catalytic application in epoxide hydroboration

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Org. Chem. Front., 2020, 7, 3625
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Pyridylpyrrolido ligand in Ge(ii) and Sn(ii) chemistry: synthesis, reactivity and catalytic application

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Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

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Dalton Trans., 2020, 49, 2417
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Controlled reduction of isocyanates to formamides using monomeric magnesium

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Donor free stibenium cation as an efficient cyanosilylation catalyst

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Electrochemical hydroboration of carbonyl compounds

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Expanding the limits of catalysts with low-valent main-group elements for the hydroboration of aldehydes and ketones using [L†Sn(ii)][OTf] (L† = aminotroponate; OTf = triflate)

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n-Butyllithium as a highly efficient precatalyst for cyanosilylation of aldehydes and ketones

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Org. Biomol. Chem., 2021, 19, 7432
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Silylene induced cooperative B–H bond activation and unprecedented aldehyde C–H bond splitting with amidinate ring expansion

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Computational study on catalyst-free BCl3-promoted chloroboration of carbonyl compounds

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Bulky bis-guanidine ligand-based neutral and cationic zinc alkyl, halide, and hydride complexes: synthesis, characterization, and catalytic application

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Catalytic hydroboration of carbonyl derivatives by using phosphinimino amide ligated magnesium complexes

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[(Me6TREN)MgOCHPh2][B(C6F5)4]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

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Eur J Inorg Chem, 2021, 2021, 4632
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Distannadithiophenes and Their Application towards Hydroboration of Carbonyl Compounds

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s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds

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Mononuclear Aluminum Complexes as Precursors for Cyanosilylation of Carbonyl Compounds

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ChemistrySelect, 2024, 9
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Alkylaluminum Complexes Featuring Bridged Bis-Formylfluorenimide Ligands for Hydroboration of Aldehyde, Ketone, and Imines

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Super hydride catalyzed ester and isocyanate hydroboration

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Alkaline Earth Metal Compounds of Methylpyridinato β-Diketiminate Ligands and Their Catalytic Application in Hydroboration of Aldehydes and Ketones

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Potassium Fluoride‐Catalyzed Hydroboration of Aldehydes and Ketones: Facile Reduction to Primary and Secondary Alcohols

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Eur J Org Chem, 2020, 2020, 552
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Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes

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Conjugated Bis‐Guanidines (CBGs) as β‐Diketimine Analogues: Synthesis, Characterization of CBGs/Their Lithium Salts and CBG Li Catalyzed Addition of B−H and TMSCN to Carbonyls

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Eur J Inorg Chem, 2021, 2021, 2034
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Bis‐Dianionic β‐Ketoiminato Octalithium Complex Catalyzed Hydrosilylation and Cyanosilylation of Carbonyl Compounds

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Germyliumylidene: A Versatile Low Valent Group 14 Catalyst

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Heavier Tetrylenes as Single Site Catalysts

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Catalyst-Free Approach for Hydroboration of Carboxylic Acids under Mild Conditions

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ACS Omega, 2019, 4, 6775
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Synthesis and Characterization of Zinc, Lithium and Magnesium Complexes Containing Pyrrolyl Ligands, and Utilization as Catalysts in Borylation of Aryl Iodides and Hydroboration of Aldehydes and Ketones

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Efficient cyanosilylation of carbonyls using a well-defined dimeric sodium complex

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Magnesium-mediated hydroboration under ambient condition: A reduction of esters, aldehydes, and ketones

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Efficient and selective aldehyde cyanosilylation catalyzed by Mg-Li bimetallic complex

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Readily available lithium compounds as catalysts for the hydroboration of carbodiimides and esters

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Expected and Unexpected Reactivities of Homoleptic LiNacNac and Heteroleptic NacNacMg(TMP) β-Diketiminates toward Various Small Unsaturated Organic Molecules

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Inorg. Chem., 2021, 60, 6057
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Manganese‐Catalyzed Hydroborations with Broad Scope

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Three Coordinated Organoaluminum Cation for Rapid and Selective Cyanosilylation of Carbonyls under Solvent‐Free Conditions

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Magnesium-catalyzed stereoselective transformations – A survey through recent achievements

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The phosphinoboration of 2-diphenylphosphino benzaldehyde and related aldimines

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Highly Efficient Solvent‐Free Cyanosilylation of Aldehydes Catalyzed by Bilayered Two‐Dimensional Metal–Organic Frameworks

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Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones

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The Hidden Role of Boranes and Borohydrides in Hydroboration Catalysis

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Stable heterocyclic stannylene: The metal, ligand‐centered reactivity, and effective catalytic hydroboration of aldehydes

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Molecular Main Group Metal Hydrides

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Cyanosilylation by Compounds with Main-Group Elements: An Odyssey

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ACS Omega, 2020, 5, 25477
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Bis(o-Aminophenolato)germanium(II) and Tin(II) Complexes in Hydroboration Reactions of Aromatic Aldehydes

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Functionalised Alkaline Earth Iodides from Grignard Synthons “PhAeI(thf)n” (Ae = Mg‐Ba)

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Nucleophilic Addition and α-C–H Substitution Reactions of an Imine Mediated by Dibutylmagnesium and Organolithium Reagents

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A Uranium(IV) Alkyl Complex: Synthesis and Catalytic Property in Carbonyl Hydroboration

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Crystallographic Characterisation of Organolithium and Organomagnesium Intermediates in Reactions of Aldehydes and Ketones

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NaHBEt3-Catalyzed 1,2-Hydroboration of α,β-Unsaturated Carbonyls: Mechanistic Insights into Hydride Transfer Pathways

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Waste-Minimized Cyanosilylation of Carbonyls Using Fluoride on Polymeric Ionic Tags in Batch and under Continuous Flow Conditions

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Catalytic cyanosilylation of ketones utilizing air-stable zinc complexes supported by amidophosphine chalcogenide ligands

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n-Butyllithium Catalyzed Selective Hydroboration of Aldehydes and Ketones

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Stannylenes Bearing an Amino‐Linked NHC Ligand as Efficient Catalysts for Hydroboration of Carbonyls and Imines

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Reactivities of Silaimines with Boranes: From Cooperative B–H Bond Activation to Donor Stabilized Silyl Cation

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Diverse Reactivity of Hypersilylsilylene with Boranes and Three-Component Reactions with Aldehyde and HBpin

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Synthesis and structural characterization of 2,2′:6′,2″-terpyridine zinc formate: Hydroboration and hydrosilylation of CO2 and carbonyl compounds

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Theoretical Insights into Aluminum-Catalyzed Cyanosilylation of Aldehydes and Ketones

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Recent Advances in Metal‐Catalyzed Asymmetric Hydroboration of Ketones

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Manganese‐Catalyzed Hydroborations with Broad Scope

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