Upgrading the chemistry of π-conjugated polymers toward more sustainable materials

Lauriane Giraud, Stéphane Grelier, Etienne Grau, Georges Hadziioannou, Cyril Brochon, Henri Cramail and Eric Cloutet

J. Mater. Chem. C, 2020, 8, 9792
DOI: 10.1039/D0TC01645D

Ladderization of polystyrene derivatives by palladium-catalyzed polymer direct arylation

Koji Takagi, Hidetoshi Tanaka and Koichiro Mikami

Polym. Chem., 2019, 10, 2647
DOI: 10.1039/C9PY00359B

Precise synthesis of conjugated polymers via reducing homocoupling defects

Bowei Ma, Qinqin Shi and Hui Huang

Chem. Soc. Rev., 2026, 55, 1755
DOI: 10.1039/D4CS00644E

EDOT-based conjugated polymers accessed via C–H direct arylation for efficient photocatalytic hydrogen production

Zhi-Rong Tan, Yu-Qin Xing, Jing-Zhao Cheng, Guang Zhang, Zhao-Qi Shen, Yu-Jie Zhang, Guangfu Liao, Long Chen and Shi-Yong Liu

Chem. Sci., 2022, 13, 1725
DOI: 10.1039/D1SC05784G

Cost-effective poly(3-alkylthiophene)-based organic photovoltaics: advancing solar energy conversion and photodetection technologies

Kai Zhang, Mengyuan Gao, Junjiang Wu, Chunlong Sun, Wenchao Zhao, Diyora Urazkulova, Vakhobjon Kuvondikov, Sherzod Nematov and Long Ye

Mater. Horiz., 2025, 12, 8832
DOI: 10.1039/D5MH01115A

Diketopyrrolopyrrole-based conjugated polymers synthesized by direct arylation polycondensation for anisole-processed high mobility organic thin-film transistors

Ying Sui, Zhongli Wang, Junhua Bai, Yibo Shi, Xuwen Zhang, Yunfeng Deng, Yang Han and Yanhou Geng

J. Mater. Chem. C, 2022, 10, 2616
DOI: 10.1039/D1TC04207F

High-mobility organic mixed conductors with a low synthetic complexity index via direct arylation polymerization

Joost Kimpel, Youngseok Kim, Jesika Asatryan, Jaime Martín, Renee Kroon and Christian Müller

Chem. Sci., 2024, 15, 7679
DOI: 10.1039/D4SC01430H

n-Type conjugated polymers comprising bithiophene imide and multifluorinated thiophene moieties synthesized by direct arylation polycondensation

Houji Cai, Xuwen Zhang, Yibo Shi, Chenhui Xu, Tianzuo Wang, Cheng Wang, Tian Du, Yunfeng Deng and Yanhou Geng

J. Mater. Chem. C, 2022, 10, 13905
DOI: 10.1039/D2TC00732K

Synthesis of conjugated polymers via cyclopentannulation reaction: promising materials for iodine adsorption

Noorullah Baig, Suchetha Shetty, Saleh Al-Mousawi and Bassam Alameddine

Polym. Chem., 2020, 11, 3066
DOI: 10.1039/D0PY00286K

Dithienophosphole-based molecular electron acceptors constructed using direct (hetero)arylation cross-coupling methods

Thomas A. Welsh, Audrey Laventure, Thomas Baumgartner and Gregory C. Welch

J. Mater. Chem. C, 2018, 6, 2148
DOI: 10.1039/C7TC05631A

Keep glowing and going: recent progress in diketopyrrolopyrrole synthesis towards organic optoelectronic materials

Nan Luo, Guanxin Zhang and Zitong Liu

Org. Chem. Front., 2021, 8, 4560
DOI: 10.1039/D1QO00613D

Influence of an ester directing-group on defect formation in the synthesis of conjugated polymers via direct arylation polymerization (DArP) using sustainable solvents

Robert M. Pankow, Liwei Ye and Barry C. Thompson

Polym. Chem., 2019, 10, 4561
DOI: 10.1039/C9PY00815B

Nucleophilic substitution reactions of cyclic thiosulfinates are accelerated by hyperconjugative interactions

Daniel P. Donnelly, Jeffrey N. Agar and Steven A. Lopez

Chem. Sci., 2019, 10, 5568
DOI: 10.1039/C9SC01098J

Innovative approaches to the molecular design, synthesis, and functionalization of conjugated organic polymer (D–A, D–π–A, A–A–D, and A–D–A) photocatalysts for sustainable hydrogen production

Pachaiyappan Murugan and Shi-Yong Liu

J. Mater. Chem. A, 2025, 13, 30870
DOI: 10.1039/D5TA04101E

To branch or not to branch: C–H selectivity of thiophene-based donor–acceptor–donor monomers in direct arylation polycondensation exemplified by PCDTBT

Florian Lombeck, Franziska Marx, Karen Strassel, Susanna Kunz, Caroline Lienert, Hartmut Komber, Richard Friend and Michael Sommer

Polym. Chem., 2017, 8, 4738
DOI: 10.1039/C7PY00879A

Thermally stable direct arylation derived terthiophene-isoindigo copolymer for organic solar cell application

Nika Bekri, Wendimagegn Mammo and Newayemedhin A. Tegegne

New J. Chem., 2025, 49, 1356
DOI: 10.1039/D4NJ03644A

Direct heteroarylation polymerization of a π-conjugated polymer with degradable 1,2,4-oxadiazole linkers

Bryton R. Varju and Dwight S. Seferos

Polym. Chem., 2022, 13, 6386
DOI: 10.1039/D2PY00984F

Elucidating the impact of molecular weight on morphology, charge transport, photophysics and performance of all-polymer solar cells

Duyen K. Tran, Amélie Robitaille, I. Jo Hai, Xiaomei Ding, Daiki Kuzuhara, Tomoyuki Koganezawa, Yu-Cheng Chiu, Mario Leclerc and Samson A. Jenekhe

J. Mater. Chem. A, 2020, 8, 21070
DOI: 10.1039/D0TA08195G

Deviate from the norm: ambipolar-acceptor frameworks as a new design paradigm for low bandgap conjugated polymers

Wyatt D. Wilcox, Evan W. Culver, Nicolas C. Nicolaidis, Spencer J. Gilman, Tomas J. Marsh, Paul C. Dastoor and Seth C. Rasmussen

J. Mater. Chem. C, 2025, 13, 7290
DOI: 10.1039/D5TC00519A

Synthesis of fluorinated phenylene-alkoxybenzothiadiazole polymer (PDTBTBz-2Fanti) by DHAP

William Dupont, Tristan Marcoux St-Pierre, Louis-Philippe Boivin, Mathieu Mainville, Mario Leclerc, Paul A. Johnson and David Gendron

Polym. Chem., 2025, 16, 4996
DOI: 10.1039/D5PY00957J

Influence of the aryl spacer in 2,5-dialkoxyphenylene and diaryl substituted thieno[3,4-c]pyrrole-4,6-dione copolymers

Robert M. Pankow, John D. Munteanu and Barry C. Thompson

J. Mater. Chem. C, 2018, 6, 5992
DOI: 10.1039/C8TC00823J

Poly(5-alkyl-thieno[3,4-c]pyrrole-4,6-dione): a study of π-conjugated redox polymers as anode materials in lithium-ion batteries

Amélie Robitaille, Alexis Perea, Daniel Bélanger and Mario Leclerc

J. Mater. Chem. A, 2017, 5, 18088
DOI: 10.1039/C7TA03786D

Theoretical Calculations for Highly Selective Direct Heteroarylation Polymerization: New Nitrile-Substituted Dithienyl-Diketopyrrolopyrrole-Based Polymers

Thomas Bura, Serge Beaupré, Marc-André Légaré, Olzhas A. Ibraikulov, Nicolas Leclerc and Mario Leclerc

Molecules, 2018, 23, 2324
DOI: 10.3390/molecules23092324

Optimization of the Bulk Heterojunction of All-Small-Molecule Organic Photovoltaics Using Design of Experiment and Machine Learning Approaches

Aaron Kirkey, Erik J. Luber, Bing Cao, Brian C. Olsen and Jillian M. Buriak

ACS Appl. Mater. Interfaces, 2020, 12, 54596
DOI: 10.1021/acsami.0c14922

Toward Defect Suppression in Polythiophenes Synthesized by Direct (Hetero)Arylation Polymerization

Samuel Brassard, Mona Hamidzad Sangachin and Mario Leclerc

Macromolecules, 2023, 56, 1362
DOI: 10.1021/acs.macromol.2c02248

Homocoupling Defects in EDOT-Based Polymers: Their Impact on Solution Aggregation, Redox Behavior, and Electrical Conductivity

Spencer J. Gilman, Shamil Saiev, Jean-Luc Brédas and John R. Reynolds

Macromolecules, 2025, 58, 4807
DOI: 10.1021/acs.macromol.5c00661

Acceptor Unit Effects for Ambipolar Organic Field-Effect Transistors Based on TIPS-Benzodithiophene Copolymers

Henry Opoku, Chinna Bathula, Melaku Dereje Mamo, Nabeen K. Shrestha, Taegweon Lee and Yong-Young Noh

Macromol. Res., 2019, 27, 90
DOI: 10.1007/s13233-019-7008-5

Mechanistic Origin of β-Defect Formation in Thiophene-Based Polymers Prepared by Direct (Hetero)arylation

J. Terence Blaskovits, Paul A. Johnson and Mario Leclerc

Macromolecules, 2018, 51, 8100
DOI: 10.1021/acs.macromol.8b01142

The Influence of the Side Chain Structure on the Photostability of Low Band Gap Polymers

Sven Bölke, Tina Keller, Florian Trilling, Michael Forster, Ullrich Scherf, Thomas Chassé and Heiko Peisert

Molecules, 2023, 28, 3858
DOI: 10.3390/molecules28093858

Eco-friendly synthesis of regioregular poly(3-hexylthiophene) by direct arylation polymerization: Analysis of the properties that determine its performance in BHJ solar cells

Miriam Rangel, Marisol Güizado-Rodríguez, José Luis Maldonado, Roberto Olayo-Valles, Victor Barba and J. Ulises Reveles

Polymer, 2020, 193, 122348
DOI: 10.1016/j.polymer.2020.122348

Supramolecular Luminescent Sensors

Teresa L. Mako, Joan M. Racicot and Mindy Levine

Chem. Rev., 2019, 119, 322
DOI: 10.1021/acs.chemrev.8b00260

Structural Engineering in Polymer Semiconductors with Aromatic N-Heterocycles

Jianyao Huang and Gui Yu

Chem. Mater., 2021, 33, 1513
DOI: 10.1021/acs.chemmater.0c03975

General room-temperature Suzuki–Miyaura polymerization for organic electronics

Haigen Xiong, Qijie Lin, Yu Lu, Ding Zheng, Yawen Li, Song Wang, Wenbin Xie, Congqi Li, Xin Zhang, Yuze Lin, Zhi-Xiang Wang, Qinqin Shi, Tobin J. Marks and Hui Huang

Nat. Mater., 2024, 23, 695
DOI: 10.1038/s41563-023-01794-9

Direct (Hetero)arylation: A Tool for Low-Cost and Eco-Friendly Organic Photovoltaics

Mathieu Mainville and Mario Leclerc

ACS Appl. Polym. Mater., 2021, 3, 2
DOI: 10.1021/acsapm.0c00883

Direct Arylation Polycondensations: Emerging Protocols for the Synthesis of High‐Performance Polymer Semiconductors

Xuwen Zhang and Yanhou Geng

Advanced Materials, 2026
DOI: 10.1002/adma.73025

Preparation of semi‐alternating conjugated polymers using direct arylation polymerization (DArP) and improvement of photovoltaic device performance through structural variation

Robert M. Pankow, Nemal S. Gobalasingham, John D. Munteanu and Barry C. Thompson

J. Polym. Sci. Part A: Polym. Chem., 2017, 55, 3370
DOI: 10.1002/pola.28712

Approaching the Integer‐Charge Transfer Regime in Molecularly Doped Oligothiophenes by Efficient Decarboxylative Cross‐Coupling

Jiang Tian Liu, Hannes Hase, Sarah Taylor, Ingo Salzmann and Pat Forgione

Angew Chem Int Ed, 2020, 59, 7146
DOI: 10.1002/anie.201914458

Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology

Amy L. Mayhugh, Preeti Yadav and Christine K. Luscombe

J. Am. Chem. Soc., 2022, 144, 6123
DOI: 10.1021/jacs.1c12455

New Fluorinated Dithienyldiketopyrrolopyrrole Monomers and Polymers for Organic Electronics

Thomas Bura, Serge Beaupré, Olzhas A. Ibraikulov, Marc-André Légaré, Jesse Quinn, Patrick Lévêque, Thomas Heiser, Yuning Li, Nicolas Leclerc and Mario Leclerc

Macromolecules, 2017, 50, 7080
DOI: 10.1021/acs.macromol.7b01198

Direct (hetero)arylation polymerization for the synthesis of donor–acceptor conjugated polymers based on N‐benzoyldithieno [3,2‐b:2′,3′‐d]pyrrole and diketopyrrolopyrrole toward organic photovoltaic cell application

Tam H Nguyen, Loc T Nguyen, Huy T Nguyen, Ngoc‐Lan T Phan, Viet Q Nguyen, Le‐Thu T Nguyen, Mai Ha Hoang, Hai Le Tran, Phong T Mai, Hideyuki Murata, Mohd Zaidan bin Abdul Aziz, Masashi Akabori and Ha Tran Nguyen

Polymer International, 2019, 68, 1776
DOI: 10.1002/pi.5888

Direct Arylation Polycondensation of Chlorinated Thiophene Derivatives to High-Mobility Conjugated Polymers

Ying Sui, Yibo Shi, Yunfeng Deng, Riqing Li, Junhua Bai, Zhongli Wang, Yanfeng Dang, Yang Han, Nigel Kirby, Long Ye and Yanhou Geng

Macromolecules, 2020, 53, 10147
DOI: 10.1021/acs.macromol.0c02206

Fluorinated Thiophene-Based Synthons: Polymerization of 1,4-Dialkoxybenzene and Fluorinated Dithieno-2,1,3-benzothiadiazole by Direct Heteroarylation

Carl Roy, Thomas Bura, Serge Beaupré, Marc-André Légaré, Jon-Paul Sun, Ian G. Hill and Mario Leclerc

Macromolecules, 2017, 50, 4658
DOI: 10.1021/acs.macromol.7b00905

Ultrafast excited state dynamics of a bithiophene‐isoindigo copolymer obtained by direct arylation polycondensation and its application in indium tin oxide‐free solar cells

Newayemedhin A. Tegegne, Zelalem Abdissa, Wendimagegn Mammo, Mats R. Andersson, Derck Schlettwein and Heinrich Schwoerer

J Polym Sci B Polym Phys, 2018, 56, 1475
DOI: 10.1002/polb.24743

Addressing Synthetic Complexity in Conjugated Polymers: New Synthetic Methods for the Acceptor Units 2,1,3‐Benzothiadiazole, 2,3‐Dihexylquinoxaline, and 2H‐Benzotriazole

Wyatt D. Wilcox, Hunter V. Hanson, Maxwell Bultman and Seth C. Rasmussen

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500379

Suppressing Defect Formation Pathways in the Direct C–H Arylation Polymerization of Photovoltaic Copolymers

Thomas J. Aldrich, Alexander S. Dudnik, Nicholas D. Eastham, Eric F. Manley, Lin X. Chen, Robert P. H. Chang, Ferdinand S. Melkonyan, Antonio Facchetti and Tobin J. Marks

Macromolecules, 2018, 51, 9140
DOI: 10.1021/acs.macromol.8b02297

Highly Efficient Catalysts for Direct Arylation Polymerization (DArP)

Masayuki Wakioka and Fumiyuki Ozawa

Asian J Org Chem, 2018, 7, 1206
DOI: 10.1002/ajoc.201800227

Direct C–H Arylation Derived Ternary D–A Conjugated Polymers: Effects of Monomer Geometries, D/A Ratios, and Alkyl Side Chains on Photocatalytic Hydrogen Production and Pollutant Degradation

Zhao‐Qi Shen, Guang Zhang, Kai Yang, Yu‐Jie Zhang, Hao Gong, Guangfu Liao and Shi‐Yong Liu

Macromol. Rapid Commun., 2024, 45
DOI: 10.1002/marc.202300566

Direct Arylation Polycondensation of Thiophene‐Based C−H Monomers†

Xuwen Zhang, Yibo Shi, Yunfeng Deng and Yanhou Geng

Chin. J. Chem., 2023, 41, 2908
DOI: 10.1002/cjoc.202300194

Investigating the Degradability and Optoelectronic Properties of π-Conjugated Polymers with 1,2,4-Chalcogenadiazole Linkers

Bryton R. Varju, Alan J. Lough and Dwight S. Seferos

Macromolecules, 2025, 58, 1214
DOI: 10.1021/acs.macromol.4c02166

Poly(naphthalene diimide-alt-bithiophene) Prepared by Direct (Hetero)arylation Polymerization for Efficient All-Polymer Solar Cells

Amélie Robitaille, Samson A. Jenekhe and Mario Leclerc

Chem. Mater., 2018, 30, 5353
DOI: 10.1021/acs.chemmater.8b02160

Recent Structural Engineering of Polymer Semiconductors Incorporating Hydrogen Bonds

Qi Zhang, Jianyao Huang, Kai Wang and Wei Huang

Advanced Materials, 2022, 34
DOI: 10.1002/adma.202110639

Performance Comparisons of Polymer Semiconductors Synthesized by Direct (Hetero)Arylation Polymerization (DHAP) and Conventional Methods for Organic Thin Film Transistors and Organic Photovoltaics

Arthur D. Hendsbee and Yuning Li

Molecules, 2018, 23, 1255
DOI: 10.3390/molecules23061255

Synthesis of 1,6‐didecylnaphtho[1,2‐b:5,6‐b']difuran‐based copolymers by direct heteroarylation polymerization

Evan W. Muller, Alfred A. Burney‐Allen, Jessica Shaw, David L. Wheeler, Volodimyr Duzhko and Malika Jeffries‐EL

Journal of Polymer Science, 2020, 58, 1299
DOI: 10.1002/pol.20200069

Sustainable Access to π-Conjugated Molecular Materials via Direct (Hetero)Arylation Reactions in Water and under Air

Adiel Mauro Calascibetta, Sara Mattiello, Alessandro Sanzone, Irene Facchinetti, Mauro Sassi and Luca Beverina

Molecules, 2020, 25, 3717
DOI: 10.3390/molecules25163717

Computational chemistry advances on benzodithiophene-based organic photovoltaic materials

Felipe A. Angel, María B. Camarada and Ignacio A. Jessop

Critical Reviews in Solid State and Materials Sciences, 2023, 48, 333
DOI: 10.1080/10408436.2022.2052798

Poly(thieno[3,4-b]pyrazine-alt-2,1,3-benzothiadiazole)s: A New Design Paradigm in Low Band Gap Polymers

Evan W. Culver, Trent E. Anderson, Juan T. López Navarrete, M. Carmen Ruiz Delgado and Seth C. Rasmussen

ACS Macro Lett., 2018, 7, 1215
DOI: 10.1021/acsmacrolett.8b00682

In vitro and In silico Studies on the Base Effect in Palladium‐Catalyzed Direct Arylation

Yu‐Ying Lai, Hau‐Ren Yang, Hao‐Ting Lee, Tien‐Liang Tsai and Han‐Sheng Sun

Asian J Org Chem, 2020, 9, 296
DOI: 10.1002/ajoc.201900705

Direct Arylation Polycondensation of β-Fluorinated Bithiophenes to Polythiophenes: Effect of Side Chains in C–Br Monomers

Xuwen Zhang, Yibo Shi, Yanfeng Dang, Ziqi Liang, Zhongli Wang, Yunfeng Deng, Yang Han, Wenping Hu and Yanhou Geng

Macromolecules, 2022, 55, 8095
DOI: 10.1021/acs.macromol.2c01266

CH Activation as a Shortcut to Conjugated Polymer Synthesis

J. Terence Blaskovits and Mario Leclerc

Macromol. Rapid Commun., 2019, 40
DOI: 10.1002/marc.201800512

Rational Monomer Design for the Synthesis of Conjugated Polymers by Direct Heteroarylation Polymerization

Navnath R. Kakde, Himanshu Sharma, Nitin V. Dalvi, Kumar Vanka and Asha S.K

ACS Polym. Au, 2024, 4, 449
DOI: 10.1021/acspolymersau.4c00050

Survey of Recent Advances in Molecular Fluorophores, Unconjugated Polymers, and Emerging Functional Materials Designed for Electrofluorochromic Use

Ilies Seddiki, Brelotte Idriss N’Diaye and W. G. Skene

Molecules, 2023, 28, 3225
DOI: 10.3390/molecules28073225

Development of highly efficient and selective catalysts for direct arylation polymerization (DArP)

Masayuki Wakioka

Polym J, 2026, 58, 103
DOI: 10.1038/s41428-025-01107-8

Improving the efficiency and sustainability of catalysts for direct arylation polymerization (DArP)

Liwei Ye and Barry C. Thompson

Journal of Polymer Science, 2022, 60, 393
DOI: 10.1002/pol.20210524

Synthesis and Characterization of a 2,3-Dialkoxynaphthalene-Based Conjugated Copolymer via Direct Arylation Polymerization (DAP) for Organic Electronics

Ignacio A. Jessop, Aylin Chong, Linda Graffo, María B. Camarada, Catalina Espinoza, Felipe A. Angel, Cesar Saldías, Alain Tundidor-Camba and Claudio A. Terraza

Polymers, 2020, 12, 1377
DOI: 10.3390/polym12061377

Sequencing conjugated polymers by eye

Daniel A. Warr, Luís M. A. Perdigão, Harry Pinfold, Jonathan Blohm, David Stringer, Anastasia Leventis, Hugo Bronstein, Alessandro Troisi and Giovanni Costantini

Sci. Adv., 2018, 4
DOI: 10.1126/sciadv.aas9543

Conjugated Polymers from Direct Arylation Polycondensation of 3,4‐Difluorothiophene‐Substituted Aryls: Synthesis and Properties

Ying Sui, Xuwen Zhang, Chenhui Xu, Yibo Shi, Yunfeng Deng, Yang Han and Yanhou Geng

Macromol. Rapid Commun., 2023, 44
DOI: 10.1002/marc.202300393

Regulating Charge Distribution to Achieve High‐Performance n‐Type Single‐Component Organic Neuromorphic Phototransistors

Yifan Li, Yanyan Cao, Chengyu Wang, Mingliang Zhu, Haojie Huang, Mingcong Qin, Zhihao Shao, Zhao Yang, Yunlong Guo and Yunqi Liu

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202503696

Thienoisoindigo‐Based Conjugated Polymers Synthesized by Direct Arylation Polycondensation

Pai Wang, Chenhui Xu, Xuwen Zhang, Yibo Shi, Cheng Wang, Yang Han, Yunfeng Deng and Yanhou Geng

Macromol. Rapid Commun., 2024, 45
DOI: 10.1002/marc.202300245

Designing organic mixed ionic-electronic conductors with low environmental footprint for bioelectronics and energy storage

Bowen Ding, Il-Young Jo, Myung-Han Yoon and Martin Heeney

Materials Science and Engineering: R: Reports, 2025, 164, 100974
DOI: 10.1016/j.mser.2025.100974

Exploration of the Direct Arylation Polymerization Method for the Practical Application of Conjugated Materials: Synthetic Scale‐Up, Solar Cell Performance, and Cost Analyses

Ted M. Pappenfus, Furqan Almyahi, Nathan A. Cooling, Evan W. Culver, Seth C. Rasmussen and Paul C. Dastoor

Macro Chemistry & Physics, 2018, 219
DOI: 10.1002/macp.201800272

Diketopyrrolopyrrole-based Conjugated Polymers as Representative Semiconductors for High-Performance Organic Thin-Film Transistors and Circuits

Kai-Qing Liu, Yuan-He Gu, Zheng-Ran Yi and Yun-Qi Liu

Chin J Polym Sci, 2023, 41, 671
DOI: 10.1007/s10118-023-2943-1

Conjugated Imine Polymer Synthesized via Step‐Growth Metathesis for Highly Stable Silicon Nanoparticle Anodes in Lithium‐Ion Batteries

Trevor R. Martin, Leah Rynearson, Mackenzie Kuller, Joseph Quinn, Chongmin Wang, Brett Lucht and Nathan R. Neale

Advanced Energy Materials, 2023, 13
DOI: 10.1002/aenm.202203921

On the “True” Structure of Push–Pull‐Type Low‐Bandgap Polymers for Organic Electronics

Geert Pirotte, Pieter Verstappen, Dirk Vanderzande and Wouter Maes

Adv Elect Materials, 2018, 4
DOI: 10.1002/aelm.201700481

Direct arylation polymerization: A guide to optimal conditions for effective conjugated polymers

Nemal S. Gobalasingham and Barry C. Thompson

Progress in Polymer Science, 2018, 83, 135
DOI: 10.1016/j.progpolymsci.2018.06.002

Direct Arylation Polycondensation (DAP) Synthesis of Alternating Quaterthiophene−Benzothiadiazole Copolymers for Organic Solar Cell Applications

Tina Keller, Tobias Gahlmann, Thomas Riedl and Ullrich Scherf

ChemPlusChem, 2019, 84, 1249
DOI: 10.1002/cplu.201900260

An improved greener process for the direct C H:C H arylation polymerization of 3,4-Propylenedioxythiophene derivatives

Nagaraj Nayak, Kajal Arora, Shruti Shirke, Snehal Shriwardhankar and Anil Kumar

European Polymer Journal, 2022, 178, 111436
DOI: 10.1016/j.eurpolymj.2022.111436

Direct (hetero)arylation polymerization: toward defect-free conjugated polymers

Mario Leclerc, Samuel Brassard and Serge Beaupré

Polym J, 2020, 52, 13
DOI: 10.1038/s41428-019-0245-9

Tunable Regioselectivity in C−H‐Activated Direct Arylation Reactions of Dithieno[3,2‐b:2’,3’‐d]pyrroles

Astrid Vogt, Florian Stümpges, Jessi Bajrami, Daniel Baumgarten, Judith Millan, Elena Mena‐Osteritz and Peter Bäuerle

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301867

Precision Synthesis of Conjugated Polymers Enabled by Direct Arylation Polymerization

Masayuki WAKIOKA

Kobunshi, 2025, 74, 606
DOI: 10.1295/kobunshi.74.11_606

Direct (Hetero)Arylation Polymerization of a Spirobifluorene and a Dithienyl-Diketopyrrolopyrrole Derivative: New Donor Polymers for Organic Solar Cells

Pierre Josse, Sergey Dayneko, Yangqian Zhang, Sylvie Dabos-Seignon, Shiming Zhang, Philippe Blanchard, Gregory C. Welch and Clément Cabanetos

Molecules, 2018, 23, 962
DOI: 10.3390/molecules23040962

Facile Direct C‐H Arylation Polymerization of Conjugated Polymer, PDCBT, for Organic Solar Cells

Soo‐Young Jang, In‐bok Kim, Yunseul Kim, Dae‐Hee Lim, Hongkyu Kang, Martin Heeney and Dong‐Yu Kim

Macromol. Rapid Commun., 2022, 43
DOI: 10.1002/marc.202200405

Advances of batch-variation control for photovoltaic polymers

Yongrui He, Lijun Huo and Bing Zheng

Nano Energy, 2024, 123, 109397
DOI: 10.1016/j.nanoen.2024.109397

Approaching the Integer‐Charge Transfer Regime in Molecularly Doped Oligothiophenes by Efficient Decarboxylative Cross‐Coupling

Jiang Tian Liu, Hannes Hase, Sarah Taylor, Ingo Salzmann and Pat Forgione

Angewandte Chemie, 2020, 132, 7212
DOI: 10.1002/ange.201914458

Curious Case of BiEDOT: MALDI-TOF Mass Spectrometry Reveals Unbalanced Monomer Incorporation with Direct (Hetero)arylation Polymerization

Austin L. Jones, Michel De Keersmaecker, Ian Pelse and John R. Reynolds

Macromolecules, 2020, 53, 7253
DOI: 10.1021/acs.macromol.0c01093

Microwave-assisted and conventional synthesis, characterisation, and DFT-based property prediction of BT-based (D–A) n and (A–D–A) n π-conjugated oligomers

Beatriz Lagunas-Simón, María Aurora Veloz-Rodríguez, Arián Espinosa-Roa and Oscar Javier Hernández Ortiz

Molecular Physics, 2026
DOI: 10.1080/00268976.2025.2612324