Doubly zwitterionic, di-reduced, highly electron-rich, air-stable naphthalenediimides: redox-switchable islands of aromatic–antiaromatic states

Sharvan Kumar, Jyoti Shukla, Kalyanashis Mandal, Yogendra Kumar, Ravi Prakash, Panch Ram and Pritam Mukhopadhyay

Chem. Sci., 2019, 10, 6482
DOI: 10.1039/C9SC00962K

Two-dimensional carbon/boron nitrides: modification, machine learning and beyond

Qi Wu, YangRui Lin, Yangwenting Ou, Changhua Wang, He Ma, Rui Wang, Yuanyuan Li and Xintong Zhang

J. Mater. Chem. A, 2024, 12, 14302
DOI: 10.1039/D4TA02059F

Intersystem crossing of perylene bisimide neutral, radical anion, and dianion derivatives compared via ultrafast spectroelectrochemistry

Julia Heitmüller, Rebecca Fröhlich, Rebecca Renner, Frank Würthner and Tobias Brixner

Phys. Chem. Chem. Phys., 2023, 25, 17214
DOI: 10.1039/D2CP05602J

A cofacial metal–organic framework based photocathode for carbon dioxide reduction

Bowen Ding, Bun Chan, Nicholas Proschogo, Marcello B. Solomon, Cameron J. Kepert and Deanna M. D'Alessandro

Chem. Sci., 2021, 12, 3608
DOI: 10.1039/D0SC04691D

Green and far-red-light induced electron injection from perylene bisimide to wide bandgap semiconductor nanocrystals with stepwise two-photon absorption process

Daisuke Yoshioka, Daiki Fukuda and Yoichi Kobayashi

Nanoscale, 2021, 13, 1823
DOI: 10.1039/D0NR08493J

Concepts and principles of self-n-doping in perylene diimide chromophores for applications in biochemistry, energy harvesting, energy storage, and catalysis

Daniel Powell and Luisa Whittaker-Brooks

Mater. Horiz., 2022, 9, 2026
DOI: 10.1039/D2MH00279E

Electron-poor arylenediimides

Sharvan Kumar, Jyoti Shukla, Yogendra Kumar and Pritam Mukhopadhyay

Org. Chem. Front., 2018, 5, 2254
DOI: 10.1039/C8QO00256H

Covalently linking CuInS2 quantum dots with a Re catalyst by click reaction for photocatalytic CO2 reduction

Jing Huang, Mélina Gilbert Gatty, Bo Xu, Palas Baran Pati, Ahmed S. Etman, Lei Tian, Junliang Sun, Leif Hammarström and Haining Tian

Dalton Trans., 2018, 47, 10775
DOI: 10.1039/C8DT01631C

Photo-driven electron transfer from the highly reducing excited state of naphthalene diimide radical anion to a CO2 reduction catalyst within a molecular triad

Jose F. Martinez, Nathan T. La Porte, Catherine M. Mauck and Michael R. Wasielewski

Faraday Discuss., 2017, 198, 235
DOI: 10.1039/C6FD00219F

Naphthalene diimides: perspectives and promise

Sheshanath V. Bhosale, Mohammad Al Kobaisi, Ratan W. Jadhav, Pranay P. Morajkar, Lathe A. Jones and Subi George

Chem. Soc. Rev., 2021, 50, 9845
DOI: 10.1039/D0CS00239A

Deciphering the single electron transfer ability of fluorene under photoredox conditions

Dhananjay Dey, Abhishek Kundu, Baishanal Mandal, Monojit Roy and Debashis Adhikari

Catal. Sci. Technol., 2022, 12, 7322
DOI: 10.1039/D2CY01460B

Long-lived triplet charge-separated state in naphthalenediimide based donor–acceptor systems

Alexander Aster, Christopher Rumble, Anna-Bea Bornhof, Hsin-Hua Huang, Naomi Sakai, Tomáš Šolomek, Stefan Matile and Eric Vauthey

Chem. Sci., 2021, 12, 4908
DOI: 10.1039/D1SC00285F

Sensitization-initiated electron transfer via upconversion: mechanism and photocatalytic applications

Felix Glaser, Christoph Kerzig and Oliver S. Wenger

Chem. Sci., 2021, 12, 9922
DOI: 10.1039/D1SC02085D

Mechanistic insights into two-photon-driven photocatalysis in organic synthesis

Marianna Marchini, Andrea Gualandi, Luca Mengozzi, Paola Franchi, Marco Lucarini, Pier Giorgio Cozzi, Vincenzo Balzani and Paola Ceroni

Phys. Chem. Chem. Phys., 2018, 20, 8071
DOI: 10.1039/C7CP08011E

Promoting photocatalytic CO2 reduction through facile electronic modification of N-annulated perylene diimide rhenium bipyridine dyads

Josh D. B. Koenig, Warren E. Piers and Gregory C. Welch

Chem. Sci., 2022, 13, 1049
DOI: 10.1039/D1SC05465A

Photoinduced electron transfer from the naphthalene diimide anion radical doublet excited state

Soojin Kim, Charles J. Zeman, Habtom B. Gobeze, Naresh Duvva and Kirk S. Schanze

Chem. Commun., 2025, 61, 5511
DOI: 10.1039/D5CC00190K

Comparative Analysis of the Hydrazine Interaction with Arylene Diimide Derivatives: Complementary Approach Using First Principles Calculation and Experimental Confirmation

Aditya Tiwari, Rikitha S. Fernandes, Nilanjan Dey and Sayan Kanungo

Langmuir, 2024, 40, 10966
DOI: 10.1021/acs.langmuir.4c00331

Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis

Han Li and Oliver S. Wenger

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202110491

Direct Observation of the Photoreduction Products of Mn(NDI-bpy)(CO)3X CO2 Reduction Catalysts Using Femtosecond Transient IR Spectroscopy

Jose F. Martinez, Nathan T. La Porte, Ryan M. Young, Alessandro Sinopoli, Muhammad Sohail and Michael R. Wasielewski

J. Phys. Chem. C, 2019, 123, 6416
DOI: 10.1021/acs.jpcc.9b00138

α‐Benzyl‐β‐Alanine Containing Naphthalenediimide Promotes Photoresponsive Radical Anion

Arpita Paikar, Totan Mondal, Mintu Debnath and Debasish Haldar

ChemistrySelect, 2018, 3, 9576
DOI: 10.1002/slct.201801133

Spin–Orbit Charge‐Transfer Intersystem Crossing in Anthracene–Perylenebisimide Compact Electron Donor–Acceptor Dyads and Triads and Photochemical Dianion Formation

Noreen Rehmat, Ivan V. Kurganskii, Zafar Mahmood, Qing Lin Guan, Jianzhang Zhao, Yong Heng Xing, Gagik G. Gurzadyan and Matvey V. Fedin

Chemistry A European J, 2021, 27, 5521
DOI: 10.1002/chem.202005285

Ligand–Metal Charge Transfer Induced via Adjustment of Textural Properties Controls the Performance of Single-Atom Catalysts during Photocatalytic Degradation

Jiaxu Liu, Yajun Zou, Daniel Cruz, Aleksandr Savateev, Markus Antonietti and Gianvito Vilé

ACS Appl. Mater. Interfaces, 2021, 13, 25858
DOI: 10.1021/acsami.1c02243

De Novo Design of Proteins That Bind Naphthalenediimides, Powerful Photooxidants with Tunable Photophysical Properties

Samuel I. Mann, Zhi Lin, Sophia K. Tan, Jiaqi Zhu, Zachary X. W. Widel, Ian Bakanas, Jarrett P. Mansergh, Rui Liu, Mark J. S. Kelly, Yibing Wu, James A. Wells, Michael J. Therien and William F. DeGrado

J. Am. Chem. Soc., 2025, 147, 7849
DOI: 10.1021/jacs.4c18151

Faster Excited-State Intramolecular Electron Transfer from Perylenediimide Dianion Compared to Its Radical Anion

Chao Lu, Kazuma Honda and Mamoru Fujitsuka

J. Phys. Chem. A, 2024, 128, 9869
DOI: 10.1021/acs.jpca.4c05189

Coherent two-dimensional electronic spectroelectrochemistry

Julia Heitmüller, Klaus Eckstein, Rebecca Renner, Matthias Stolte, Tobias Hertel, Frank Würthner and Tobias Brixner

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2021, 253, 119567
DOI: 10.1016/j.saa.2021.119567

Spin-Selective Photoinduced Electron Transfer within Naphthalenediimide Diradicals

Nathan T. La Porte, Joseph A. Christensen, Matthew D. Krzyaniak, Brandon K. Rugg and Michael R. Wasielewski

J. Phys. Chem. B, 2019, 123, 7731
DOI: 10.1021/acs.jpcb.9b06303

Lowering Electrocatalytic CO2 Reduction Overpotential Using N-Annulated Perylene Diimide Rhenium Bipyridine Dyads with Variable Tether Length

Josh D. B. Koenig, Zachary S. Dubrawski, Keerthan R. Rao, Janina Willkomm, Benjamin S. Gelfand, Chad Risko, Warren E. Piers and Gregory C. Welch

J. Am. Chem. Soc., 2021, 143, 16849
DOI: 10.1021/jacs.1c09481

Electron Transfer from Photoexcited Naphthalene Diimide Radical Anion to Electrocatalytically Active Re(bpy)(CO)3Cl in a Molecular Triad

Jose F. Martinez, Nathan T. La Porte and Michael R. Wasielewski

J. Phys. Chem. C, 2018, 122, 2608
DOI: 10.1021/acs.jpcc.7b11999

Perylene‐ and Perylene Diimide‐based Framework Materials Constructed through Metal Coordination

Junxiao Wang, Haoxuan Wei, Jun Guan, Klaus Müllen and Meizhen Yin

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403234

Dynamics of reduced perylene bisimide cyclophane redox species by ultrafast spectroelectrochemistry

Rebecca Fröhlich, Jessica Rühe, Michael Moos, Laura Kontschak, Patrik Ehrmann, Frank Würthner, Christoph Lambert and Tobias Brixner

The Journal of Chemical Physics, 2024, 160
DOI: 10.1063/5.0210490

Electron transfer from photoexcited naphthalene-1,4:5,8-bis(dicarboximide) radical anion to Mn(bpy)(CO)3X and Re(bpy)(CO)3X CO2 reduction catalysts linked via a saturated methylene bridge

Jose F. Martinez, Nathan T. La Porte and Michael R. Wasielewski

Journal of Photochemistry and Photobiology A: Chemistry, 2019, 372, 21
DOI: 10.1016/j.jphotochem.2018.11.047

Programmed Molecular Construction: Driving the Self-Assembly by Coordination and Hydrogen Bonds Using 6-(Pyridin-2-yl)-1,3,5-triazine-2,4-diamine with M(NO3)2 Salts

Sanil Rajak, Midhun Mohan, Alexandre A. Tremblay, Thierry Maris, Silvano Leal do Santos, Everaldo Carlos Venancio, Sydney Ferreira Santos and Adam Duong

ACS Omega, 2019, 4, 2708
DOI: 10.1021/acsomega.8b03517

Uniaxially Oriented and Polymerized Chromonic Nanocolumns for Redox-Responsive Smart Glass

Dong-Gue Kang, Minwoo Rim, Hyeyoon Ko, Jahyeon Koo, Seok-In Lim, Minwook Park, Won-Jin Yoon, Yu-Jin Choi and Kwang-Un Jeong

Chem. Mater., 2020, 32, 7630
DOI: 10.1021/acs.chemmater.0c00669

Thousandfold Enhancement of Photoreduction Lifetime in Re(bpy)(CO)3 via Spin-Dependent Electron Transfer from a Perylenediimide Radical Anion Donor

Svante Hedström, Subhajyoti Chaudhuri, Nathan T. La Porte, Benjamin Rudshteyn, Jose F. Martinez, Michael R. Wasielewski and Victor S. Batista

J. Am. Chem. Soc., 2017, 139, 16466
DOI: 10.1021/jacs.7b09438

Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

David C. Grills, Mehmed Z. Ertem, Meaghan McKinnon, Ken T. Ngo and Jonathan Rochford

Coordination Chemistry Reviews, 2018, 374, 173
DOI: 10.1016/j.ccr.2018.05.022

Theoretical Investigation of Ru(II) Complexes with Long Lifetime and a Large Two-Photon Absorption Cross-Section in Photodynamic Therapy

Xue Wei, Wei-bo Cui, Gui-ya Qin, Xiu-e Zhang, Feng-yi Sun, Hui Li, Jing-fu Guo and Ai-min Ren

J. Med. Chem., 2023, 66, 4167
DOI: 10.1021/acs.jmedchem.3c00047

Manganese carbonyl complexes for CO2 reduction

Alessandro Sinopoli, Nathan T. La Porte, Jose F. Martinez, Michael R. Wasielewski and Muhammad Sohail

Coordination Chemistry Reviews, 2018, 365, 60
DOI: 10.1016/j.ccr.2018.03.011

Electron Spin Dynamics of the Intersystem Crossing of Triplet Photosensitizers That Show Strong Absorption of Visible Light and Long-Lived Triplet States

Zhijia Wang, Xue Zhang and Jianzhang Zhao

J. Phys. Chem. C, 2021, 125, 19097
DOI: 10.1021/acs.jpcc.1c06184

Photocatalytic Reduction of Nicotinamide Co‐factor by Perylene Sensitized RhIII Complexes**

Jannik Brückmann, Carolin Müller, Ilse Friedländer, Alexander K. Mengele, Kalina Peneva, Benjamin Dietzek‐Ivanšić and Sven Rau

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201931

Ultrafast Electron Dynamics in Solar Energy Conversion

Carlito S. Ponseca, Pavel Chábera, Jens Uhlig, Petter Persson and Villy Sundström

Chem. Rev., 2017, 117, 10940
DOI: 10.1021/acs.chemrev.6b00807

Near-Infrared-Light Triggered Electron Transfer from Ag2S Nanocrystals to Perylene Bisimide

Yuki Nagai, Tadashi Watanabe, Daisuke Yoshioka, Yoshinori Okayasu, Naoto Tamai and Yoichi Kobayashi

ECS J. Solid State Sci. Technol., 2022, 11, 101001
DOI: 10.1149/2162-8777/ac93b2

Exploring Optically Fueled Dissipative Self-Assembly of a Redox-Active Perylene Diimide Scaffold

Oendrila Chatterjee, Anup Pramanik and Apurba Lal Koner

Organic Materials, 2022, 4, 228
DOI: 10.1055/a-1967-8617

Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell

Degao Wang, Lei Wang, Matthew D. Brady, Christopher J. Dares, Gerald J. Meyer, Thomas J. Meyer and Javier J. Concepcion

J. Phys. Chem. C, 2019, 123, 30039
DOI: 10.1021/acs.jpcc.9b07125

Photoexcited radical anion super-reductants for solar fuels catalysis

Nathan T. La Porte, Jose F. Martinez, Subhajyoti Chaudhuri, Svante Hedström, Victor S. Batista and Michael R. Wasielewski

Coordination Chemistry Reviews, 2018, 361, 98
DOI: 10.1016/j.ccr.2018.01.018

Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis

Han Li and Oliver S. Wenger

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202110491

Stable Bifunctional Perylene Imide Radicals for High‐Performance Organic–Lithium Redox‐Flow Batteries

Lei Li, Hai‐Xian Gong, Dong‐Yang Chen and Mei‐Jin Lin

Chemistry A European J, 2018, 24, 13188
DOI: 10.1002/chem.201801443

Singlet Fission in Covalent Terrylenediimide Dimers: Probing the Nature of the Multiexciton State Using Femtosecond Mid-Infrared Spectroscopy

Michelle Chen, Youn Jue Bae, Catherine M. Mauck, Aritra Mandal, Ryan M. Young and Michael R. Wasielewski

J. Am. Chem. Soc., 2018, 140, 9184
DOI: 10.1021/jacs.8b04830

Synthesis of model heterojunction interfaces reveals molecular-configuration-dependent photoinduced charge transfer

Jeroen Royakkers, Hanbo Yang, Alexander J. Gillett, Flurin Eisner, Pratyush Ghosh, Daniel G. Congrave, Mohammed Azzouzi, Zahra Andaji-Garmaroudi, Anastasia Leventis, Akshay Rao, Jarvist Moore Frost, Jenny Nelson and Hugo Bronstein

Nat. Chem., 2024, 16, 1453
DOI: 10.1038/s41557-024-01578-x

Distance Dependence for Intramolecular Electron Transfer from Excited Naphthalenediimide Dianion

Chao Lu, Hiroki Nakayama, Yasuko Osakada and Mamoru Fujitsuka

J. Phys. Chem. A, 2026, 130, 57
DOI: 10.1021/acs.jpca.5c06164

Rapid and Efficient Electrochemical Actuation in a Flexible Perylene Bisimide Dimer

Samaresh Samanta, Narottam Mukhopadhyay and Debangshu Chaudhuri

Chem. Mater., 2019, 31, 899
DOI: 10.1021/acs.chemmater.8b04077

Excited-State Properties of Radical Anions of C70 and Its Derivatives: Significant Differences from the Case of C60

Chao Lu, Mamoru Fujitsuka, Akira Sugimoto and Tetsuro Majima

J. Phys. Chem. C, 2018, 122, 13385
DOI: 10.1021/acs.jpcc.7b10926

Visible Light Generation of a Microsecond Long-Lived Potent Reducing Agent

Zijian Zhao, Fushuang Niu, Pengju Li, Hanqi Wang, Zhenghao Zhang, Gerald J. Meyer and Ke Hu

J. Am. Chem. Soc., 2022, 144, 7043
DOI: 10.1021/jacs.2c00422

Near-IR Light-Induced Electron Transfer via Dynamic Quenching

Takafumi Enomoto, Mio Kondo, Mizue Asada, Toshikazu Nakamura and Shigeyuki Masaoka

J. Phys. Chem. C, 2018, 122, 11282
DOI: 10.1021/acs.jpcc.8b02591

Supramolecular Luminescent Sensors

Teresa L. Mako, Joan M. Racicot and Mindy Levine

Chem. Rev., 2019, 119, 322
DOI: 10.1021/acs.chemrev.8b00260

Photophysical properties of perylenebisimide derivatives studied by time-resolved transient optical and electron paramagnetic resonance spectroscopy

Wenhui Li, Jiayu Li, Ivan Kurganskii, Kaiyue Ye, Xue Zhang, Jianzhang Zhao, Ming-De Li, Bernhard Dick and Matvey Fedin

The Journal of Chemical Physics, 2025, 163
DOI: 10.1063/5.0277710

Recent development of the transition metal complexes showing strong absorption of visible light and long-lived triplet excited state: From molecular structure design to photophysical properties and applications

Xue Zhang, Yuqi Hou, Xiao Xiao, Xi Chen, Mengyu Hu, Xinyu Geng, Zhijia Wang and Jianzhang Zhao

Coordination Chemistry Reviews, 2020, 417, 213371
DOI: 10.1016/j.ccr.2020.213371

Naphthalenediimide (NDI)‐Conjugated Foldable Polyurethanes: Impact of Chromophoric Location on Hierarchical Supramolecular Assembly and Conductivity

Anurag Mukherjee, Tsuneaki Sakurai, Shu Seki and Suhrit Ghosh

ChemNanoMat, 2018, 4, 860
DOI: 10.1002/cnma.201800220

Colored Ionic Liquid Based on Stable Polycyclic Anion Salt Showing Halochromism with HCl Vapor

Hideo Enozawa, Shusaku Ukai, Hiroshi Ito, Tsuyoshi Murata and Yasushi Morita

Org. Lett., 2019, 21, 2161
DOI: 10.1021/acs.orglett.9b00468

Effect of Electronic Coupling on Electron Transfer Rates from Photoexcited Naphthalenediimide Radical Anion to Re(bpy)(CO)3X

Jose F. Martinez, Nathan T. La Porte, Subhajyoti Chaudhuri, Alessandro Sinopoli, Youn Jue Bae, Muhammad Sohail, Victor S. Batista and Michael R. Wasielewski

J. Phys. Chem. C, 2019, 123, 10178
DOI: 10.1021/acs.jpcc.8b12264

Efficient Photoredox Cycles to Control Perylenediimide Self‐Assembly**

Chunfeng Chen, Jorge S. Valera, Takuji B. M. Adachi and Thomas M. Hermans

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202849

Polymer connectivity governs electrophotocatalytic activity in the solid state

Jianheng Ling, Amy L. Vonder Haar, Kiser Z. Colley, Juno Kim, Andrew J. Musser and Phillip J. Milner

Nat. Chem., 2025, 17, 1853
DOI: 10.1038/s41557-025-01897-7

Deciphering Charge Transfer Processes in Transition Metal Complexes from the Perspective of Ultrafast Electronic and Nuclear Motions

Michael W. Mara, Nicholas P. Weingartz, Denis Leshchev, Darren Hsu, Andrew Valentine, Alexis Mills, Subhangi Roy, Arnab Chakraborty, Pyosang Kim, Elisa Biasin, Kristoffer Haldrup, Matthew S. Kirschner, Dolev Rimmerman, Matthieu Chollet, James M. Glownia, Timothy B. van Driel, Felix N. Castellano, Xiaosong Li and Lin X. Chen

J. Phys. Chem. Lett., 2024, 15, 5250
DOI: 10.1021/acs.jpclett.4c00735

Asymmetric anionic [O⋯H⋯N]−1 -type strong H-bond constructed new near-infrared organic photothermal materials with high molar absorptivity and high amount of temperature rise

Yuanyuan Li, Longgang Wang, Mengming Sun, Jianping Zhang, Wenlong Hou, Lu Liu, Bo Liang, Hongliang Liu and Haiquan Zhang

Dyes and Pigments, 2022, 206, 110649
DOI: 10.1016/j.dyepig.2022.110649

Phenothiazine Radical Cation Excited States as Super-oxidants for Energy-Demanding Reactions

Joseph A. Christensen, Brian T. Phelan, Subhajyoti Chaudhuri, Atanu Acharya, Victor S. Batista and Michael R. Wasielewski

J. Am. Chem. Soc., 2018, 140, 5290
DOI: 10.1021/jacs.8b01778

Efficient Spin–Orbit Charge‐Transfer Intersystem Crossing and Slow Intramolecular Triplet–Triplet Energy Transfer in Bodipy–Perylenebisimide Compact Dyads and Triads

Xi Chen, Noreen Rehmat, Ivan V. Kurganskii, Partha Maity, Ayhan Elmali, Jianzhang Zhao, Ahmet Karatay, Omar F. Mohammed and Matvey V. Fedin

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302137

Photoexcited Naphthalene Diimide Radical Anion Linking the Nodes of a Metal–Organic Framework: A Heterogeneous Super-reductant

Subhadip Goswami, Jordan N. Nelson, Timur Islamoglu, Yi-Lin Wu, Omar K. Farha and Michael R. Wasielewski

Chem. Mater., 2018, 30, 2488
DOI: 10.1021/acs.chemmater.8b00720