Formate dehydrogenase activity by a Cu(ii)-based molecular catalyst and deciphering the mechanism using DFT studies

Aman Mishra, Diship Srivastava, Dev Raj, Niladri Patra and Sumanta Kumar Padhi

Dalton Trans., 2024, 53, 1209
DOI: 10.1039/D3DT03023G

Reactant or reagent? Oxidation of H2 at electronically distinct nickel-thiolate sites [Ni2(μ-SR)2]+ and [Ni–SR]+

Felix Koch and Andreas Berkefeld

Dalton Trans., 2018, 47, 10561
DOI: 10.1039/C8DT00275D

Manganese(i) κ2-NN complex-catalyzed formic acid dehydrogenation

Alexander Léval, Henrik Junge and Matthias Beller

Catal. Sci. Technol., 2020, 10, 3931
DOI: 10.1039/D0CY00769B

Insertion of CS2into the Mg–H bond: synthesis and structural characterization of the magnesium dithioformate complex, [TismPriBenz]Mg(κ2-S2CH)

Michael Rauch and Gerard Parkin

Dalton Trans., 2018, 47, 12596
DOI: 10.1039/C8DT01947A

Versatile (η6-arene)Ni(PCy3) nickel monophosphine precursors

Sha Zhu, Manar M. Shoshani and Samuel A. Johnson

Chem. Commun., 2017, 53, 13176
DOI: 10.1039/C7CC08416A

Recent advances in liquid-phase chemical hydrogen storage

Chengguang Lang, Yi Jia and Xiangdong Yao

Energy Storage Materials, 2020, 26, 290
DOI: 10.1016/j.ensm.2020.01.010

Efficient [Fe-Imidazole@SiO2] Nanohybrids for Catalytic H2 Production from Formic Acid

Christos Gkatziouras, Maria Solakidou and Maria Louloudi

Nanomaterials, 2023, 13, 1670
DOI: 10.3390/nano13101670

Additive‐Free Formic Acid Dehydrogenation Using a Pincer‐Supported Iron Catalyst

Julia B. Curley, Wesley H. Bernskoetter and Nilay Hazari

ChemCatChem, 2020, 12, 1934
DOI: 10.1002/cctc.202000066

Using CS2 to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes

Qiang-Qiang Ma, Ting Liu, Anubendu Adhikary, Jie Zhang, Jeanette A. Krause and Hairong Guan

Organometallics, 2016, 35, 4077
DOI: 10.1021/acs.organomet.6b00759

A Recent Review of Primary Hydrogen Carriers, Hydrogen Production Methods, and Applications

Risheng Li and Hajime Kawanami

Catalysts, 2023, 13, 562
DOI: 10.3390/catal13030562

A computational approach to understand stepwise PCET during hydrogen evolution reaction by iron dithiolene catalyst

Koushik Makhal and Bhabani S. Mallik

Computational and Theoretical Chemistry, 2026, 1256, 115564
DOI: 10.1016/j.comptc.2025.115564

Reactivity of Cyclopentadienyl Molybdenum Compounds towards Formic Acid: Structural Characterization of CpMo(PMe3)(CO)2H, CpMo(PMe3)2(CO)H, [CpMo(μ-O)(μ-O2CH)]2, and [Cp*Mo(μ-O)(μ-O2CH)]2

Michelle C. Neary and Gerard Parkin

Inorg. Chem., 2017, 56, 1511
DOI: 10.1021/acs.inorgchem.6b02606

Reviews on Homogeneous and Heterogeneous Catalysts for Dehydrogenation and Recycling of Formic Acid: Progress and Perspectives

Aofei Wang, Ping He, Jiang Wu, Naichao Chen, Changyu Pan, Enqi Shi, Haodong Jia, Tianyang Hu, Kangsai He, Qian Cai and Rui Shen

Energy Fuels, 2023, 37, 17075
DOI: 10.1021/acs.energyfuels.3c02595

Formic acid as renewable reagent and product in biomass upgrading

Mahdi Achour, Débora Álvarez-Hernández, Estela Ruiz-López, Cristina Megías-Sayago, Fatima Ammari, Svetlana Ivanova and Miguel Ángel Centeno

Tetrahedron Green Chem, 2023, 2, 100020
DOI: 10.1016/j.tgchem.2023.100020

Advances in Nonprecious Metal Homogeneously Catalyzed Formic Acid Dehydrogenation

Manuel Iglesias and Francisco J. Fernández-Alvarez

Catalysts, 2021, 11, 1288
DOI: 10.3390/catal11111288

Cost Efficiency Analysis of H2 Production from Formic Acid by Molecular Catalysts

Maria Solakidou, Aikaterini Gemenetzi, Georgia Koutsikou, Marinos Theodorakopoulos, Yiannis Deligiannakis and Maria Louloudi

Energies, 2023, 16, 1723
DOI: 10.3390/en16041723

Base‐Free Dehydrogenation of Aqueous and Neat Formic Acid with Iridium(III) Cp*(dipyridylamine) Catalysts

Shengdong Wang, Haiyun Huang, Thierry Roisnel, Christian Bruneau and Cédric Fischmeister

ChemSusChem, 2019, 12, 179
DOI: 10.1002/cssc.201802275

Synergistic Effect of Pendant N Moieties for Proton Shuttling in the Dehydrogenation of Formic Acid Catalyzed by Biomimetic IrIII Complexes

Wan‐Hui Wang, Hong Wang, Yajing Yang, Xiaoling Lai, Yang Li, Jiasheng Wang, Yuichiro Himeda and Ming Bao

ChemSusChem, 2020, 13, 5015
DOI: 10.1002/cssc.202001190

Photocatalytic hydrogen generation from formic acid: Understanding the mechanistic insights and recent trends

Mathivathani J R, Himanshu Sharma, Kohsuke Mori, Hiromi Yamashita and Priyanka Verma

Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2025, 65, 100725
DOI: 10.1016/j.jphotochemrev.2025.100725

N-Heterocyclic Carbene Complexes of Nickel, Palladium, and Iridium Derived from Nitron: Synthesis, Structures, and Catalytic Properties

Patrick J. Quinlivan, Aaron Loo, Daniel G. Shlian, Joan Martinez and Gerard Parkin

Organometallics, 2021, 40, 166
DOI: 10.1021/acs.organomet.0c00679

On the Demise of PPP-Ligated Iron Catalysts in the Formic Acid Dehydrogenation Reaction

Bedraj Pandey, Jeanette A. Krause and Hairong Guan

Inorg. Chem., 2023, 62, 18714
DOI: 10.1021/acs.inorgchem.3c03125

Dehydrogenation of formic acid mediated by a Phosphorus–Nitrogen PN3P-manganese pincer complex: Catalytic performance and mechanistic insights

Indranil Dutta, Nasser A. Alobaid, Fabio Lorenzo Menicucci, Priyanka Chakraborty, Chao Guan, Delong Han and Kuo-Wei Huang

International Journal of Hydrogen Energy, 2023, 48, 26559
DOI: 10.1016/j.ijhydene.2022.04.220

Recent Progress in Homogeneous Catalytic Dehydrogenation of Formic Acid

Naoya Onishi, Ryoichi Kanega, Hajime Kawanami and Yuichiro Himeda

Molecules, 2022, 27, 455
DOI: 10.3390/molecules27020455

Hydrogen production from formic acid catalyzed by NHC–Cu complexes

Orlando Santoro and Catherine S J Cazin

Beilstein J. Org. Chem., 2026, 22, 620
DOI: 10.3762/bjoc.22.48

Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation Catalyzed by Iridium Complexes Bearing Pyridyl‐pyrazole Ligands: Effect of an Electron‐donating Substituent on the Pyrazole Ring on the Catalytic Activity and Durability

Naoya Onishi, Ryoichi Kanega, Etsuko Fujita and Yuichiro Himeda

Adv Synth Catal, 2019, 361, 289
DOI: 10.1002/adsc.201801323

Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

Nicolas Lentz, Alicia Aloisi, Pierre Thuéry, Emmanuel Nicolas and Thibault Cantat

Organometallics, 2021, 40, 565
DOI: 10.1021/acs.organomet.0c00777

Noninnocent Ligands for Efficient Dehydrogenation of Aqueous and Neat Formic Acid under Base-Free Conditions

Liwei Guo, Zilong Li, Marie Cordier, Rémi Marchal, Boris Le Guennic and Cédric Fischmeister

ACS Catal., 2023, 13, 13626
DOI: 10.1021/acscatal.3c02060

Efficient Iridium Catalysts for Formic Acid Dehydrogenation: Investigating the Electronic Effect on the Elementary β-Hydride Elimination and Hydrogen Formation Steps

Hong Liu, Wan-Hui Wang, Huatian Xiong, A. Nijamudheen, Mehmed Z. Ertem, Mei Wang and Lele Duan

Inorg. Chem., 2021, 60, 3410
DOI: 10.1021/acs.inorgchem.0c03815

Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols

Katerina Sordakis, Conghui Tang, Lydia K. Vogt, Henrik Junge, Paul J. Dyson, Matthias Beller and Gábor Laurenczy

Chem. Rev., 2018, 118, 372
DOI: 10.1021/acs.chemrev.7b00182

Green hydrogen storage and delivery: Utilizing highly active homogeneous and heterogeneous catalysts for formic acid dehydrogenation

Mohammad Younas, Mashallah Rezakazemi, Muhammad Saddique Arbab, Jehangir Shah and Waheed Ur Rehman

International Journal of Hydrogen Energy, 2022, 47, 11694
DOI: 10.1016/j.ijhydene.2022.01.184

Iron Dihydride Complex Stabilized by an All-Phosphorus-Based Pincer Ligand and Carbon Monoxide

Bedraj Pandey, Jeanette A. Krause and Hairong Guan

Inorg. Chem., 2022, 61, 11143
DOI: 10.1021/acs.inorgchem.2c01027

Catalytic Dehydrogenation of Formic Acid Promoted by Triphos-Co Complexes: Two Competing Pathways for H2 Production

Chou-Pen Tsai, Chih-Yao Chen, Yi-Lin Lin, Jen-Chen Lan and Ming-Li Tsai

Inorg. Chem., 2024, 63, 1759
DOI: 10.1021/acs.inorgchem.3c02959

Structural characterization of the nickel(II) formate complex, Ni(py)4(O2CH)2·2py, and re-evaluation of the nitrate counterpart, Ni(py)4(ONO2)2·2py: Evidence for non-linear nitrate coordination

Michelle C. Neary and Gerard Parkin

Polyhedron, 2016, 116, 189
DOI: 10.1016/j.poly.2016.04.033

Recent progress for reversible homogeneous catalytic hydrogen storage in formic acid and in methanol

Naoya Onishi, Gábor Laurenczy, Matthias Beller and Yuichiro Himeda

Coordination Chemistry Reviews, 2018, 373, 317
DOI: 10.1016/j.ccr.2017.11.021

An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis

Chao Guan, Yupeng Pan, Tonghuan Zhang, Manjaly J. Ajitha and Kuo‐Wei Huang

Chemistry An Asian Journal, 2020, 15, 937
DOI: 10.1002/asia.201901676

Base-Free Reversible Hydrogen Storage Using a Tethered π-Coordinated-Phenoxy Ruthenium-Dimer Precatalyst

Raphael Verron, Emmanuel Puig, Pierre Sutra, Alain Igau and Cédric Fischmeister

ACS Catal., 2023, 13, 5787
DOI: 10.1021/acscatal.3c00476

Synthesis and structural characterization of 2,2′:6′,2″-terpyridine zinc formate: Hydroboration and hydrosilylation of CO2 and carbonyl compounds

Aaron Loo, Gonzalo Fernandez de la Mora and Gerard Parkin

Polyhedron, 2025, 270, 117235
DOI: 10.1016/j.poly.2024.117235

Advances in the Homogeneously Catalyzed Hydrogen Production from Biomass Derived Feedstocks: A Review

Andrea Fasolini, Giulia Martelli, Andrea Piazzi, Massimiliano Curcio, Jacopo De Maron, Francesco Basile and Rita Mazzoni

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400393

Formic Acid Dehydrogenation by a Cyclometalated κ3‐CNN Ruthenium Complex

Alexander Léval, Henrik Junge and Matthias Beller

Eur J Inorg Chem, 2020, 2020, 1293
DOI: 10.1002/ejic.202000068

CO2-based hydrogen storage – formic acid dehydrogenation

Thomas Zell and Robert Langer

Physical Sciences Reviews, 2018, 3
DOI: 10.1515/psr-2017-0012

Cobalt-Catalyzed Additive-Free Dehydrogenation of Neat Formic Acid

Bedraj Pandey, Jeanette A. Krause and Hairong Guan

ACS Catal., 2024, 14, 13781
DOI: 10.1021/acscatal.4c04109

Zerovalent Nickel Compounds Supported by 1,2-Bis(diphenylphosphino)benzene: Synthesis, Structures, and Catalytic Properties

Michelle C. Neary, Patrick J. Quinlivan and Gerard Parkin

Inorg. Chem., 2018, 57, 374
DOI: 10.1021/acs.inorgchem.7b02636

Deciphering the Mechanistic Details of Manganese-Catalyzed Formic Acid Dehydrogenation: Insights from DFT Calculations

Neethinathan Johnee Britto and Madhavan Jaccob

Inorg. Chem., 2021, 60, 11038
DOI: 10.1021/acs.inorgchem.1c00757