Rh(iii)-catalysed C–H/C–H cross-coupling of S-aryl sulfoximines with thiophenes: facile access to [1]benzothieno[3,2-b][1]benzothiophene (BTBT) and benzothiazines

Chengyong Yang, Zheng Liu, Rui Cheng, Jiping Du, Chunhao Ran, Di Wu and Jingbo Lan

Chem. Commun., 2022, 58, 7952
DOI: 10.1039/D2CC02232J

Mechanistic investigation of the NH-sulfoximination of sulfide. Evidence for λ6-sulfanenitrile intermediates

Jean-François Lohier, Thomas Glachet, Hamid Marzag, Annie-Claude Gaumont and Vincent Reboul

Chem. Commun., 2017, 53, 2064
DOI: 10.1039/C6CC09940H

A divergent and metal free synthesis of sulfoximine tethered imidazoles, imidazopyridines, imidazothiazoles, imidazobenzothiazines, thiazoles and selenazoles

S. R. K. Battula, V. P. Rama Kishore Putta, G. V. Subbareddy, I. E. Chakravarthy and V. Saravanan

Org. Biomol. Chem., 2017, 15, 3742
DOI: 10.1039/C7OB00601B

Merging hypervalent iodine and sulfoximine chemistry: a new electrophilic trifluoromethylation reagent

Jorna Kalim, Thibaut Duhail, Thanh-Nghi Le, Nicolas Vanthuyne, Elsa Anselmi, Antonio Togni and Emmanuel Magnier

Chem. Sci., 2019, 10, 10516
DOI: 10.1039/C9SC04289J

TMTHSI, a superior 7-membered ring alkyne containing reagent for strain-promoted azide–alkyne cycloaddition reactions

Jimmy Weterings, Cristianne J. F. Rijcken, Harald Veldhuis, Tommi Meulemans, Darya Hadavi, Matt Timmers, Maarten Honing, Hans Ippel and Rob M. J. Liskamp

Chem. Sci., 2020, 11, 9011
DOI: 10.1039/D0SC03477K

N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines: synthesis, X-ray crystallography, and halogen bonding

Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen and Carsten Bolm

Org. Chem. Front., 2020, 7, 3896
DOI: 10.1039/D0QO01139H

Copper-catalyzed oxidative decarboxylative coupling of α-keto acids and sulfoximines

Chaleena Pimpasri, Ladawan Sumunnee and Sirilata Yotphan

Org. Biomol. Chem., 2017, 15, 4320
DOI: 10.1039/C7OB00776K

Access to N-cyanosulfoximines by transition metal-free iminations of sulfoxides

C. A. Dannenberg, L. Fritze, F. Krauskopf and C. Bolm

Org. Biomol. Chem., 2017, 15, 1086
DOI: 10.1039/C6OB02691E

Synthesis of 3-amino-substituted benzothiadiazine oxides by a palladium-catalysed cascade reaction

Renè Hommelsheim, Sandra Bausch, Robin van Nahl, Jas S. Ward, Kari Rissanen and Carsten Bolm

Green Chem., 2023, 25, 3021
DOI: 10.1039/D3GC00442B

Advances in cross-coupling and oxidative coupling reactions of NH-sulfoximines – a review

Hala Adam Elzubier Adam, Sihan Zhou and Qingle Zeng

Chem. Commun., 2025, 61, 1934
DOI: 10.1039/D4CC05308G

Synthesis of glycosyl sulfoximines by a highly chemo- and stereoselective NH- and O-transfer to thioglycosides

Arianna Tota, Claudia Carlucci, Luisa Pisano, Giuliano Cutolo, Guy J. Clarkson, Giuseppe Romanazzi, Leonardo Degennaro, James A. Bull, Patrick Rollin and Renzo Luisi

Org. Biomol. Chem., 2020, 18, 3893
DOI: 10.1039/D0OB00647E

Alkyldisulfanium salt-mediated difunctionalization of alkenes with NH-sulfoximines

Lu-Can Cheng, Si-Si Tian, Hao-Pan Tan, Sha Peng, Li-Hua Yang and Long-Yong Xie

Org. Biomol. Chem., 2026, 24, 1510
DOI: 10.1039/D6OB00047A

Regioselective oxidative cleavage of conjugated dienes to access α,β-unsaturated nitriles

Yuqing Fu, Yijia Leng, Haotong Bai, Jiaxi Xu and Ning Chen

Org. Chem. Front., 2024, 11, 3263
DOI: 10.1039/D3QO02101G

Enantiopure nanohoops through racemic resolution of diketo[n]CPPs by chiral derivatization as precursors to DBP[n]CPPs

Daniel Wassy, Mathias Hermann, Jan S. Wössner, Lucas Frédéric, Grégory Pieters and Birgit Esser

Chem. Sci., 2021, 12, 10150
DOI: 10.1039/D1SC02718B

The stereochemistry of substitution at S(vi)

Oliver L. Symes and James A. Bull

Org. Chem. Front., 2025, 12, 6681
DOI: 10.1039/D5QO01043H

Persulfate-promoted oxidative C–N bond coupling of quinoxalinones andNH-sulfoximines

Ladawan Sumunnee, Chaleena Pimpasri, Medena Noikham and Sirilata Yotphan

Org. Biomol. Chem., 2018, 16, 2697
DOI: 10.1039/C8OB00375K

Direct N-acylation of sulfoximines with carboxylic acids catalyzed by the B3NO2 heterocycle

Hidetoshi Noda, Yasuko Asada, Masakatsu Shibasaki and Naoya Kumagai

Chem. Commun., 2017, 53, 7447
DOI: 10.1039/C7CC03386A

Stereospecific reaction of sulfonimidoyl fluorides with Grignard reagents for the synthesis of enantioenriched sulfoximines

Stephanie Greed, Oliver Symes and James A. Bull

Chem. Commun., 2022, 58, 5387
DOI: 10.1039/D2CC01219G

An efficient imidation of thioethers with nitrene in water

Tao Feng, Zhihui Tang, Xiaoli Luo and Junming Mo

Org. Biomol. Chem., 2020, 18, 6497
DOI: 10.1039/D0OB01539C

Brønsted acid-catalyzed solvent-controlled regioselective thiolation of 2-furylcarbinols

Chunyu Zhang, Tianyu Lin, Qing Liu, Rui Hu and Weidong Rao

Org. Chem. Front., 2025, 12, 678
DOI: 10.1039/D4QO01904K

Rhodium-catalyzed benzoisothiazole synthesis by tandem annulation reactions of sulfoximines and activated olefins

Yang Li and Lin Dong

Org. Biomol. Chem., 2017, 15, 9983
DOI: 10.1039/C7OB02586F

O-Substituted hydroxyl amine reagents: an overview of recent synthetic advances

Shekh Sabir, Ganesh Kumar and Jawahar L. Jat

Org. Biomol. Chem., 2018, 16, 3314
DOI: 10.1039/C8OB00146D

Direct formation and site-selective elaboration of methionine sulfoximine in polypeptides

Yuxuan Ding, Simon S. Pedersen, Alex Lin, Ruoyu Qian and Zachary T. Ball

Chem. Sci., 2022, 13, 14101
DOI: 10.1039/D2SC04220G

Synthesis of dibenzothiazines from sulfides by one-potN,O-transfer and intramolecular C–H amination

Yan-Na Ma, Chen-Yang Guo, Qianyi Zhao, Jie Zhang and Xuenian Chen

Green Chem., 2018, 20, 2953
DOI: 10.1039/C8GC01057A

Copper-promoted dehydrogenative cross-coupling reaction of dialkyl phosphites with sulfoximines

Surabhi Gupta, Siddharth Baranwal, Priyanka Chaudhary and Jeyakumar Kandasamy

Org. Chem. Front., 2019, 6, 2260
DOI: 10.1039/C9QO00469F

Facile synthesis of N-1,2,4-oxadiazole substituted sulfoximines from N-cyano sulfoximines

Chenna Reddy M. L., Fazlur Rahman Nawaz Khan and Vadivelu Saravanan

Org. Biomol. Chem., 2019, 17, 9187
DOI: 10.1039/C9OB01931F

Metal-free synthesis of α-keto-N-acyl sulfoximines from sulfoximines and α-bromomethyl aryl ketones under photoredox catalysis

V. Navaneetha Krishnan, K. Natarajan, V. R. Padma Priya, A. Antony Haritha Mercy and Ganesh Chandra Nandi

Org. Biomol. Chem., 2026, 24, 816
DOI: 10.1039/D5OB01642H

Iodine-Promoted Sulfoximidation of Cinnamic Acids via Oxidative C═C Bond Cleavage

Parbin Rahman, Nikita Chakraborty, Bhisma K. Patel and Kamal K. Rajbongshi

J. Org. Chem., 2024, 89, 10472
DOI: 10.1021/acs.joc.4c00585

Modular Synthesis of ortho‐Thiolated Aryl Esters Enabled with Thiocarbonate through Catellani Strategy

Guopeng Du, Pingliang Zhu, Jing Wang, Xinjin Li, Dao‐Peng Zhang, Chuan‐Zeng Wang and Feng‐Gang Sun

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202201382

Batch and Continuous‐Flow Iron(II)‐Catalyzed Synthesis of Sulfilimines and Sulfoximines using N‐Mesyloxycarbamates

Calvine Lai, Gary Mathieu, Lucia Paola Gabrielli Tabarez and Hélène Lebel

Chemistry A European J, 2019, 25, 9423
DOI: 10.1002/chem.201900953

A Decade of NH-Transfer via Iodonitrene: A Journey of NH-Transfer from Sulfur and Nitrogen to Alkenes

Philipp Natho, Marco Colella and Renzo Luisi

Synlett, 2026
DOI: 10.1055/a-2845-8119

Electrochemical oxidations through hypervalent iodine redox catalysis

Ronit S. Bernard, Ajit Kumar Jha and Marcin Kalek

Tetrahedron Chem, 2024, 11, 100081
DOI: 10.1016/j.tchem.2024.100081

Synthesis of Cyclic Sulfilimines and Sulfoximines via Copper‐Mediated C(sp2)–H Sulfanylation of Benzylamines with a Catalytic Transient Directing Group

Tsz‐Kan Ma, Peerawat Saejong, King‐Long Or, Callum S. Begg and James A. Bull

ChemistryEurope, 2025, 3
DOI: 10.1002/ceur.202500209

Syntheses and Transformations of Sulfoximines

Wenting Zheng, Xianlie Chen, Feng Chen, Ze He and Qingle Zeng

The Chemical Record, 2021, 21, 396
DOI: 10.1002/tcr.202000134

Calcium(II)‐Catalyzed Synthesis of Sulfoximinocyclopentenones

Xiangmeng Chen, Christophe Bour, Emilie Kolodziej, Régis Guillot, Nicolas S. George, Aurélien Alix and Vincent Gandon

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401085

One-Pot Synthesis of Iodo-Dibenzothiazines from 2-Biaryl Sulfides

Yan-Na Ma, Yajing Bian, Xin Liu, Jie Zhang and Xuenian Chen

J. Org. Chem., 2019, 84, 450
DOI: 10.1021/acs.joc.8b02729

Efficient Kinetic Resolution of Sulfur‐Stereogenic Sulfoximines by Exploiting CpXRhIII‐Catalyzed C−H Functionalization

Marcus Brauns and Nicolai Cramer

Angew Chem Int Ed, 2019, 58, 8902
DOI: 10.1002/anie.201904543

Nickel‐Catalyzed Thiolation of Aryl Nitriles

Tristan Delcaillau and Bill Morandi

Chemistry A European J, 2021, 27, 11823
DOI: 10.1002/chem.202101273

A Copper‐Catalyzed Interrupted Domino Reaction for the Synthesis of Fused Triazolyl Benzothiadiazine‐1‐oxides

Renè Hommelsheim, Sandra Bausch, Arjuna Selvakumar, Mostafa M. Amer, Khai‐Nghi Truong , Kari Rissanen and Carsten Bolm

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203729

Cu‐catalyzed Bilateral Linkage of Sulfenamides for the Construction of Benzothiophene‐based Cyclic Sulfilimines

Xinyu Zhang, Rutian Sun, Daming Zeng, Ming Wang and Xuefeng Jiang

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401467

Visible-Light-Triggered Synthesis of N-α-Ketoacylated Sulfoximines by Denitrogenative and Oxidative Functionalization of Vinyl Azides

Subhankar Sarkar, Satyajit Pal, Sougata Santra, Grigory V. Zyryanov and Adinath Majee

J. Org. Chem., 2024, 89, 8137
DOI: 10.1021/acs.joc.4c00796

C2‐Symmetric Bissulfoximine‐Based Metal Complexes: Synthesis, Characterization and Their Electrocatalytic Activity in Oxygen Reduction Reaction

Qazi Mohammad Junaid, Devesh Kumar Singh, Vellaichamy Ganesan and Shahulhameed Sabiah

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200160

Shifting Lithium Amide Reactivity to the Radical Domain: Regioselective Radical C−H Functionalization of 3‐Iodooxetane for the Synthesis of 1,5‐Dioxaspiro[2.3]hexanes

Philipp Natho, Marco Colella, Annarita Vicenti, Giuseppe Romanazzi, Faizan Ullah, Nadeem S. Sheikh, Andrew J. P. White, Francesco Pasca and Renzo Luisi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424346

Synthesis of Sulfilimines Enabled by Copper-Catalyzed S-Arylation of Sulfenamides

Qingjin Liang, Lucille A. Wells, Kaiming Han, Shufeng Chen, Marisa C. Kozlowski and Tiezheng Jia

J. Am. Chem. Soc., 2023, 145, 6310
DOI: 10.1021/jacs.2c12947

Stereoselectivity Enhancement During the Generation of Three Contiguous Stereocenters in Tetrahydrothiophenes

Żaneta A. Mała, Mikołaj J. Janicki, Natalia H. Niedźwiecka, Robert W. Góra, Krzysztof A. Konieczny and Rafał Kowalczyk

ChemCatChem, 2021, 13, 574
DOI: 10.1002/cctc.202001583

Synthesis and Functionalization of Sulfoximine‐Bicyclo[1.1.0]butanes: Functionalizable, Tuneable and Cysteine‐Selective Chiral Warheads

Zhenhao Zhong, Brad J. W. Hocking, Charles P. Brown, Tsz‐Kan Ma, Andrew J. P. White, David J. Mann, Alan Armstrong and James A. Bull

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420028

N‐(sulfonio)sulfilimin‐Reagenzien: Nicht‐oxidierende Quellen von elektrophilen Stickstoffatomen für Skeletal Editing

Tobias Heilmann, Juan M. Lopez‐Soria, Johannes Ulbrich, Johannes Kircher, Zhen Li, Brigitte Worbs, Christopher Golz, Ricardo A. Mata and Manuel Alcarazo

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202403826

A Convenient, Mild, and Green Synthesis of NH‐Sulfoximines in Flow Reactors

Leonardo Degennaro, Arianna Tota, Sonia De Angelis, Michael Andresini, Cosimo Cardellicchio, Maria Annunziata Capozzi, Giuseppe Romanazzi and Renzo Luisi

Eur J Org Chem, 2017, 2017, 6486
DOI: 10.1002/ejoc.201700850

Discovery of 2-Amino-7-sulfonyl-7H-pyrrolo[2,3-d]pyrimidine Derivatives as Potent Reversible FGFR Inhibitors with Gatekeeper Mutation Tolerance: Design, Synthesis, and Biological Evaluation

Wuchen Xie, Siyu Yang, Li Liang, Meng Wang, Wen Zuo, Yan Lei, Yanmin Zhang, Weifang Tang, Tao Lu, Yadong Chen and Yulei Jiang

J. Med. Chem., 2022, 65, 16570
DOI: 10.1021/acs.jmedchem.2c01420

How do we address neglected sulfur pharmacophores in drug discovery?

Michael J. Tilby and Michael C. Willis

Expert Opinion on Drug Discovery, 2021, 16, 1227
DOI: 10.1080/17460441.2021.1948008

Computer-Aided Retrosynthesis for Greener and Optimal Total Synthesis of a Helicase-Primase Inhibitor Active Pharmaceutical Ingredient

Rodolfo I. Teixeira, Michael Andresini, Renzo Luisi and Brahim Benyahia

JACS Au, 2024, 4, 4263
DOI: 10.1021/jacsau.4c00624

Synthesis and Functionalization of Sulfoximine‐Bicyclo[1.1.0]butanes: Functionalizable, Tuneable and Cysteine‐Selective Chiral Warheads

Zhenhao Zhong, Brad J. W. Hocking, Charles P. Brown, Tsz‐Kan Ma, Andrew J. P. White, David J. Mann, Alan Armstrong and James A. Bull

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420028

Harnessing Sulfinyl Nitrenes: A Unified One-Pot Synthesis of Sulfoximines and Sulfonimidamides

Thomas Q. Davies, Michael J. Tilby, Jack Ren, Nicholas A. Parker, David Skolc, Adrian Hall, Fernanda Duarte and Michael C. Willis

J. Am. Chem. Soc., 2020, 142, 15445
DOI: 10.1021/jacs.0c06986

Synthesis of Furanone-Fused 1,2-Benzothiazine by Rh(III)-Catalyzed C–H Activation: Regioselective Oxidative Annulation Leading to in Situ Lactonization in One Pot

Vinayak Hanchate, Anil Kumar and Kandikere Ramaiah Prabhu

J. Org. Chem., 2019, 84, 11335
DOI: 10.1021/acs.joc.9b01899

General Method for the Asymmetric Synthesis of N–H Sulfoximines via C–S Bond Formation

Priscilla Mendonça Matos, William Lewis, Stephen P. Argent, Jonathan C. Moore and Robert A. Stockman

Org. Lett., 2020, 22, 2776
DOI: 10.1021/acs.orglett.0c00761

An Organocatalytic and Stereoselective Vinylogous Domino Process towards Thiochromans

Pierre Milbeo, Arthur Lebrêne, Mariia Savchuk, Giang Vo‐Thanh, Sylvain Oudeyer, Hélène Beucher and Jean‐François Brière

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301311

Forging C−S Bonds on the Azetidine Ring by Continuous Flow Photochemical Addition of Thiols and Disulfides to Azetines

Marco Colella, Yuri Gelato, Michael Andresini, Elena Graziano, Gianvito Vilé, Leonardo Degennaro and Renzo Luisi

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300413

Stereospecific α-(hetero)arylation of sulfoximines and sulfonimidamides

Zachary P. Shultz, Thomas Scattolin, Lukasz Wojtas and Justin M. Lopchuk

Nat Synth, 2022, 1, 170
DOI: 10.1038/s44160-021-00011-2

Sulfoximines as Rising Stars in Modern Drug Discovery? Current Status and Perspective on an Emerging Functional Group in Medicinal Chemistry

Patrick Mäder and Lars Kattner

J. Med. Chem., 2020, 63, 14243
DOI: 10.1021/acs.jmedchem.0c00960

Synthesis and Configurational Assignment of Vinyl Sulfoximines and Sulfonimidamides

Gregory B. Craven, Edward L. Briggs, Charlotte M. Zammit, Alexander McDermott, Stephanie Greed, Dominic P. Affron, Charlotte Leinfellner, Hannah R. Cudmore, Ruth R. Tweedy, Renzo Luisi, James A. Bull and Alan Armstrong

J. Org. Chem., 2021, 86, 7403
DOI: 10.1021/acs.joc.1c00373

Dibenzothiophenium Salts: Practical Alternatives to Hypervalent I(III)-Based Reagents

Manuel Alcarazo

Acc. Chem. Res., 2025, 58, 635
DOI: 10.1021/acs.accounts.4c00804

N−H and C−H Functionalization of Sulfoximine: Recent Advancement and Prospects

Prasanjit Ghosh, Bhaskar Ganguly and Sajal Das

Asian J Org Chem, 2020, 9, 2035
DOI: 10.1002/ajoc.202000320

N‐(Sulfonio)Sulfilimine Reagents: Non‐Oxidizing Sources of Electrophilic Nitrogen Atom for Skeletal Editing

Tobias Heilmann, Juan M. Lopez‐Soria, Johannes Ulbrich, Johannes Kircher, Zhen Li, Brigitte Worbs, Christopher Golz, Ricardo A. Mata and Manuel Alcarazo

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202403826

Synthesis and oxidative transformations of 2-functionalized 2-trifluoromethyltetrahydrothiophenes

Sergiy A. Siry, Vadim M. Timoshenko, Eduard B. Rusanov and Yuriy G. Schermolovich

Journal of Fluorine Chemistry, 2022, 261-262, 109999
DOI: 10.1016/j.jfluchem.2022.109999

Pd/PTABS: Low-Temperature Thioetherification of Chloro(hetero)arenes

Siva Sankar Murthy Bandaru, Shatrughn Bhilare, Jesvita Cardozo, Nicolas Chrysochos, Carola Schulzke, Yogesh S. Sanghvi, Krishna Chaitanya Gunturu and Anant R. Kapdi

J. Org. Chem., 2019, 84, 8921
DOI: 10.1021/acs.joc.9b00840

Design, Synthesis, Biological Evaluation and SARs of Novel N‐Substituted Sulfoximines as Potential Ryanodine Receptor Modulators

Yongtao Xie, Sha Zhou, Yuxin Li, Shaa Zhou, Minggui Chen, Baolei Wang, Lixia Xiong, Na Yang and Zhengming Li

Chin. J. Chem., 2018, 36, 129
DOI: 10.1002/cjoc.201700555

Visible‐Light‐Mediated Photoredox‐Catalyzed N‐Arylation of NH‐Sulfoximines with Electron‐Rich Arenes

Alexander Wimmer and Burkhard König

Adv Synth Catal, 2018, 360, 3277
DOI: 10.1002/adsc.201800607

Cu(II)-Catalyzed, Site Selective Sulfoximination to Indole and Indolines via Dual C–H/N–H Activation

Mohit Kumar, Anushka Rastogi, Raziullah, Ashfaq Ahmad, Manoj Kumar Gangwar and Dipankar Koley

Org. Lett., 2022, 24, 8729
DOI: 10.1021/acs.orglett.2c02817

Shifting Lithium Amide Reactivity to the Radical Domain: Regioselective Radical C−H Functionalization of 3‐Iodooxetane for the Synthesis of 1,5‐Dioxaspiro[2.3]hexanes

Philipp Natho, Marco Colella, Annarita Vicenti, Giuseppe Romanazzi, Faizan Ullah, Nadeem S. Sheikh, Andrew J. P. White, Francesco Pasca and Renzo Luisi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424346

Hydroxylamine‐Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron‐Catalyzed Preparation of Unprotected Sulfinamides from Thiols

Sayanti Chatterjee, Szabolcs Makai and Bill Morandi

Angew Chem Int Ed, 2021, 60, 758
DOI: 10.1002/anie.202011138

Synthesis of Benzo[c]isothiazole 2-Oxides via Copper-Catalyzed Cycloamidation Reaction

Limin Yu, Jie Weng, Yimeng He, Jiefang Meng and Yimiao He

Synlett, 2025, 36, 1387
DOI: 10.1055/a-2544-3496

Diastereoselective Synthesis of γ‐Lactones through Reaction of Sulfoxonium Ylides, Aldehydes, and Ketenes: Substrate Scope and Mechanistic Studies

Nicholas J. Peraino, Mukulesh Mondal, Han‐Jen Ho, Antoine Beuque, Evan Viola, Melanie Gary, Kraig A. Wheeler and Nessan J. Kerrigan

Eur J Org Chem, 2021, 2021, 151
DOI: 10.1002/ejoc.202001233

N−N Bond Formation Using an Iodonitrene as an Umpolung of Ammonia: Straightforward and Chemoselective Synthesis of Hydrazinium Salts

Arianna Tota, Marco Colella, Claudia Carlucci, Andrea Aramini, Guy Clarkson, Leonardo Degennaro, James A. Bull and Renzo Luisi

Adv Synth Catal, 2021, 363, 194
DOI: 10.1002/adsc.202001047

Dehydrogenative Imination of Low-Valent Sulfur Compounds─Fast and Scalable Synthesis of Sulfilimines, Sulfinamidines, and Sulfinimidate Esters

Martin Klein, David L. Troglauer and Siegfried R. Waldvogel

JACS Au, 2023, 3, 575
DOI: 10.1021/jacsau.2c00663

Synthesis of Six‐Membered N‐Heterocycle Frameworks Based on Intramolecular Metal‐Free N‐Centered Radical Chemistry

Yan Gao, Qianyi Zhao, Lixin Li and Yan‐Na Ma

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202100218

Iodonitrene-Mediated Nitrogen Transfer to Alkenes for the Direct Synthesis of NH-Aziridines

Yuri Gelato, Laura Marraffa, Francesco Pasca, Philipp Natho, Giuseppe Romanazzi, Arianna Tota, Marco Colella and Renzo Luisi

J. Am. Chem. Soc., 2025, 147, 35567
DOI: 10.1021/jacs.5c10372

Synthesis of NH‐Sulfoximines by Using Recyclable Hypervalent Iodine(III) Reagents under Aqueous Micellar Conditions

Guocai Zhang, Hongsheng Tan, Weichun Chen, Hong C. Shen, Yue Lu, Changwu Zheng and Hongxi Xu

ChemSusChem, 2020, 13, 922
DOI: 10.1002/cssc.201903430

Sulfoximine N-Functionalization with N-Fluorobenzenesulfonamide

Žan Testen, Črtomir Podlipnik and Marjan Jereb

J. Org. Chem., 2025, 90, 15790
DOI: 10.1021/acs.joc.5c02077

A One‐Pot Cascade Reaction by Combining NH‐Sulfoximines with Thiophenols Under Mild Conditions

Yao Peng, Yan Lin, Ruifang Nie, Yang Zheng, Yanzhao Liu, Li Guo and Yong Wu

Eur J Org Chem, 2018, 2018, 844
DOI: 10.1002/ejoc.201701643

Iron(II)‐Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides

Hao Yu, Zhen Li and Carsten Bolm

Angewandte Chemie, 2018, 130, 330
DOI: 10.1002/ange.201710498

Chromatographic Enantioseparation of Chiral Sulfoximines on Polysaccharide-Based Chiral Stationary Phases

Qinqin Tang, Ping Zhao and Qingle Zeng

Journal of Chromatographic Science, 2023, 61, 838
DOI: 10.1093/chromsci/bmad046

Highly Chemoselective NH- and O-Transfer to Thiols Using Hypervalent Iodine Reagents: Synthesis of Sulfonimidates and Sulfonamides

Arianna Tota, Sahra St John-Campbell, Edward L. Briggs, Gala Ogalla Estévez, Michelle Afonso, Leonardo Degennaro, Renzo Luisi and James A. Bull

Org. Lett., 2018, 20, 2599
DOI: 10.1021/acs.orglett.8b00788

Transition-Metal-Free Sulfoximidation of Sulfonylhydrazones for the Synthesis of N-Sulfanylidenehydrazonamides

Tianming Huang, Muhammad Suleman, Zhengyu Xu, Li Wei, Yi Yang, Ming Zhang and Zhiyuan Chen

Org. Lett., 2024, 26, 6597
DOI: 10.1021/acs.orglett.4c02170

From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches

Bram Verbelen, Eric Siemes, Andreas Ehnbom, Christoph Räuber, Kari Rissanen, Dominik Wöll and Carsten Bolm

Org. Lett., 2019, 21, 4293
DOI: 10.1021/acs.orglett.9b01475

Photocatalytic N‐Alkylation of NH‐Sulfoximines via Anti‐Markovnikov Hydroamination of Alkenes

Cong Wang and Tiezheng Jia

Adv Synth Catal, 2023, 365, 3666
DOI: 10.1002/adsc.202300797

I2-Catalyzed Cascade Annulation/Cross-Dehydrogenative Coupling: Excellent Platform to Access 3-Sulfenyl Pyrazolo[1,5-a]pyrimidines with Potent Antibacterial Activity against Pseudomonas aeruginosa and Staphylococcus aureus

Suvam Paul, Samik Biswas, Tathagata Choudhuri, Shrabasti Bandyopadhyay, Supratim Mandal and Avik Kumar Bagdi

ACS Appl. Bio Mater., 2025, 8, 3254
DOI: 10.1021/acsabm.5c00059

Efficient Kinetic Resolution of Sulfur‐Stereogenic Sulfoximines by Exploiting CpXRhIII‐Catalyzed C−H Functionalization

Marcus Brauns and Nicolai Cramer

Angewandte Chemie, 2019, 131, 8994
DOI: 10.1002/ange.201904543

Rh(III)-Catalyzed Oxidative Annulation of Sulfoximines with Arylalkynyl Silanes via Desilylation

Vinayak Hanchate, Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

J. Org. Chem., 2019, 84, 8248
DOI: 10.1021/acs.joc.9b00743

Hydroxylamin‐abgeleitetes Reagenz als duales Oxidationsmittel und Aminogruppendonor für die eisenkatalysierte Herstellung von ungeschützten Sulfinamiden aus Thiolen

Sayanti Chatterjee, Szabolcs Makai and Bill Morandi

Angewandte Chemie, 2021, 133, 769
DOI: 10.1002/ange.202011138

Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis

Mathias Hermann, Daniel Wassy, Julia Kohn, Philipp Seitz, Martin U. Betschart, Stefan Grimme and Birgit Esser

Angewandte Chemie, 2021, 133, 10775
DOI: 10.1002/ange.202016968

Synthesis and Transformations of NH‐Sulfoximines

Michael Andresini, Arianna Tota, Leonardo Degennaro, James A. Bull and Renzo Luisi

Chemistry A European J, 2021, 27, 17293
DOI: 10.1002/chem.202102619

NH‐sulfoximine: A novel pharmacological inhibitor of the mitochondrial F1Fo‐ATPase, which suppresses viability of cancerous cells

Daniela Strobbe, Rosalba Pecorari, Oriana Conte, Antonella Minutolo, Christine M. M. Hendriks, Stefan Wiezorek, Danilo Faccenda, Rosella Abeti, Carla Montesano, Carsten Bolm and Michelangelo Campanella

British J Pharmacology, 2021, 178, 298
DOI: 10.1111/bph.15279

KI-mediated practical synthesis of N-acyl sulfoximines from benzyl alcohols

Himadri Boruah, Parbin Rahman and Kamal K. Rajbongshi

Tetrahedron, 2026, 197, 135295
DOI: 10.1016/j.tet.2026.135295

Design, synthesis, and antiplasmodial evaluation of a series of novel sulfoximine analogues of carbohydrate‐based thiochromans

Munashe Chizema, Tommy F. Mabasa, Heinrich C. Hoppe and Henok H. Kinfe

Chem Biol Drug Des, 2019, 93, 254
DOI: 10.1111/cbdd.13408

Structure and Reactivity of N‐Heterocyclic Alkynyl Hypervalent Iodine Reagents

Eliott Le Du, Thibaut Duhail, Matthew D. Wodrich, Rosario Scopelliti, Farzaneh Fadaei‐Tirani, Elsa Anselmi, Emmanuel Magnier and Jerome Waser

Chemistry A European J, 2021, 27, 10979
DOI: 10.1002/chem.202101475

Vinyl and Bromo‐Vinyl Sulfoximine Synthesis via Reactive Sulfonimidoyl Bromide Intermediates

Huaqin Wu, Yuanyuan Zhang, Xingxing Liu, Kehan Qian, Jianbin Deng, Yong Wang and Xiaobing Wan

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70178

Direct one step dehydrogenative C-H sulfonimidation of unfunctionalized arenes: A conveneient protocol to emerging medicinal chemistry motifs without prefunctionalized arenes

Satyanarayana Tummanapalli, Kali Charan Gulipalli, Srinu Bodige, Divya Vemula, Srinivas Endoori, Anil Kumar Pommidi and Shiva Kumar Punna

Tetrahedron Letters, 2021, 73, 153118
DOI: 10.1016/j.tetlet.2021.153118

Autocatalytic photoredox Chan-Lam coupling of free diaryl sulfoximines with arylboronic acids

Cong Wang, Hui Zhang, Lucille A. Wells, Tian Liu, Tingting Meng, Qingchao Liu, Patrick J. Walsh, Marisa C. Kozlowski and Tiezheng Jia

Nat Commun, 2021, 12
DOI: 10.1038/s41467-021-21156-w

Recent Advances in N-Arylation of NH-Sulfoximines and Their Applications

Xue Li, Cong Wang and Tiezheng Jia

Chinese Journal of Organic Chemistry, 2022, 42, 714
DOI: 10.6023/cjoc202110011

Synthesis of Sulfoximine Propargyl Carbamates under Improved Conditions for Rhodium Catalyzed Carbamate Transfer to Sulfoxides

Zhenhao Zhong, Julian Chesti, Alan Armstrong and James A. Bull

J. Org. Chem., 2022, 87, 16115
DOI: 10.1021/acs.joc.2c02083

Selective Deuteration and Tritiation of Pharmaceutically Relevant Sulfoximines

Blair I. P. Smith, Nathan M. L. Knight, Gary J. Knox, David M. Lindsay, Laura C. Paterson, Jonas Bergare, Charles S. Elmore, Ryan A. Bragg and William J. Kerr

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202417179

Dibenzothiophene Sulfoximine as an NH3 Surrogate in the Synthesis of Primary Amines by Copper‐Catalyzed C−X and C−H Bond Amination

Zhen Li, Hao Yu and Carsten Bolm

Angew Chem Int Ed, 2017, 56, 9532
DOI: 10.1002/anie.201705025

Sulfonimidates: Useful Synthetic Intermediates for Sulfoximine Synthesis via C–S Bond Formation

Priscilla Mendonça Matos, William Lewis, Jonathan C. Moore and Robert A. Stockman

Org. Lett., 2018, 20, 3674
DOI: 10.1021/acs.orglett.8b01473

Enantioselective Synthesis of Chiral‐at‐Sulfur 1,2‐Benzothiazines by CpxRhIII‐Catalyzed C−H Functionalization of Sulfoximines

Yang Sun and Nicolai Cramer

Angewandte Chemie, 2018, 130, 15765
DOI: 10.1002/ange.201810887

Development and Scale-up of a Route to ATR Inhibitor AZD6738

William R. F. Goundry, Kuangchu Dai, Miguel Gonzalez, Daniel Legg, Anne O’Kearney-McMullan, James Morrison, Andrew Stark, Paul Siedlecki, Paula Tomlin and Jianbo Yang

Org. Process Res. Dev., 2019, 23, 1333
DOI: 10.1021/acs.oprd.9b00075

Organophosphorus-Catalyzed Direct Dehydroxylative Thioetherification of Alcohols with Hypervalent Organosulfur Compounds

Gang Sun, Shi-Ping Zhan, Yi-Feng Zhao, Xingyi Du, Mao-Ying Shi, Jing Li, Haoliang Yuan, Xiaoan Wen, Hongbin Sun and Qing-Long Xu

J. Org. Chem., 2024, 89, 1083
DOI: 10.1021/acs.joc.3c02175

Planarizable Push‐Pull Probes with Sulfoximine‐Bridged Dithienothiophene Acceptors

José García‐Calvo, Javier López‐Andarias, Naomi Sakai and Stefan Matile

Helvetica Chimica Acta, 2022, 105
DOI: 10.1002/hlca.202100238

Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates

Juan Alberto Sirvent and Ulrich Lücking

ChemMedChem, 2017, 12, 487
DOI: 10.1002/cmdc.201700044

Photocatalytic Late-Stage Functionalization of Sulfonamides via Sulfonyl Radical Intermediates

Michael J. Tilby, Damien F. Dewez, Loïc R. E. Pantaine, Adrian Hall, Carolina Martínez-Lamenca and Michael C. Willis

ACS Catal., 2022, 12, 6060
DOI: 10.1021/acscatal.2c01442

The Role of Organosulfur Compounds as Nrf2 Activators and Their Antioxidant Effects

Melford Chuka Egbujor, Maria Petrosino, Karim Zuhra and Luciano Saso

Antioxidants, 2022, 11, 1255
DOI: 10.3390/antiox11071255

Stereoretentive Formation of Cyclobutanes from Pyrrolidines: Lessons Learned from DFT Studies of the Reaction Mechanism

Roger Monreal-Corona, Miquel Solà, Anna Pla-Quintana and Albert Poater

J. Org. Chem., 2023, 88, 4619
DOI: 10.1021/acs.joc.3c00080

Synthesis of Pyrazolesulfoximines Using α-Diazosulfoximines with Alkynes

Zhenhao Zhong, Tsz-Kan Ma, Andrew J. P. White and James A. Bull

Org. Lett., 2024, 26, 1178
DOI: 10.1021/acs.orglett.3c04274

Rhodium(III)‐Catalyzed C−H Alkynylation of N‐Methylsulfoximines

Tao Wang, Yi‐Ning Wang, Rui Wang and Xi‐Sheng Wang

Chemistry An Asian Journal, 2018, 13, 2449
DOI: 10.1002/asia.201800889

Iron(II)‐Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides

Hao Yu, Zhen Li and Carsten Bolm

Angew Chem Int Ed, 2018, 57, 324
DOI: 10.1002/anie.201710498

A New, Practical One‐Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides

Flavia Izzo, Martina Schäfer, Robert Stockman and Ulrich Lücking

Chemistry A European J, 2017, 23, 15189
DOI: 10.1002/chem.201703272

Electrochemical NH‐Sulfoximidation with α‐Keto Acids

Tipu Alam, Shalini Gupta and Bhisma K. Patel

ChemPhysChem, 2024, 25
DOI: 10.1002/cphc.202400599

Palladium-catalyzed heteroaryl thioethers synthesis overcoming palladium dithiolate resting states inertness: Practical road to sulfones and NH-sulfoximines

Johan Guilbaud, Marine Labonde, Awatef Selmi, Majed Kammoun, Hélène Cattey, Nadine Pirio, Julien Roger and Jean-Cyrille Hierso

Catalysis Communications, 2018, 111, 52
DOI: 10.1016/j.catcom.2018.03.025

Modular Sulfondiimine Synthesis Using a Stable Sulfinylamine Reagent

Ze-Xin Zhang, Thomas Q. Davies and Michael C. Willis

J. Am. Chem. Soc., 2019, 141, 13022
DOI: 10.1021/jacs.9b06831

Electrochemical Oxidative Syntheses of NH‐Sulfoximines, NH‐Sulfonimidamides and Dibenzothiazines via Anodically Generated Hypervalent Iodine Intermediates

Xianqiang Kong, Long Lin, Xiaohui Chen, Yiyi Chen, Wei Wang and Bo Xu

ChemSusChem, 2021, 14, 3277
DOI: 10.1002/cssc.202101002

Modern Stereoselective Synthesis of Chiral Sulfinyl Compounds

Elżbieta Wojaczyńska and Jacek Wojaczyński

Chem. Rev., 2020, 120, 4578
DOI: 10.1021/acs.chemrev.0c00002

Streamlining the Synthesis of Pyridones through Oxidative Amination of Cyclopentenones

Bence B. Botlik, Micha Weber, Florian Ruepp, Kazuki Kawanaka, Patrick Finkelstein and Bill Morandi

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202408230

Sulfoximine Derivatives — Their Pharmacochemical Properties, Synthesis, and Potential in Drug Discovery

Michalina Skóra, Michał Nowacki and Maciej Dawidowski

Prospect. Pharm. Sci., 2025
DOI: 10.56782/pps.626

One-Pot Synthesis of N-Iodo Sulfoximines from Sulfides

Anže Zupanc and Marjan Jereb

J. Org. Chem., 2021, 86, 5991
DOI: 10.1021/acs.joc.1c00292

Decarboxylative Radical Sulfilimination via Photoredox, Copper, and Brønsted Base Catalysis

Mingjun Zhang, Lixia Liu, Yuhao Tan, Yue Jing, Yuxiu Liu, Ziwen Wang and Qingmin Wang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202318344

Selenium Dioxide Promoted α‐Keto N‐Acylation of Sulfoximines Under Mild Reaction Conditions

Siddharth Baranwal, Surabhi Gupta and Jeyakumar Kandasamy

Asian J Org Chem, 2021, 10, 1835
DOI: 10.1002/ajoc.202100298

Streamlining the Synthesis of Pyridones through Oxidative Amination of Cyclopentenones

Bence B. Botlik, Micha Weber, Florian Ruepp, Kazuki Kawanaka, Patrick Finkelstein and Bill Morandi

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202408230

Sulfoximidation of Aryl Alkenes via Oxidative CC Bond Cleavage

Parbin Rahman, Nikita Chakraborty, Himadri Boruah, Bhisma K. Patel and Kamal K. Rajbongshi

Eur J Org Chem, 2026
DOI: 10.1002/ejoc.70437

Functionalization of four-membered cyclic sulfoximines by a convenient lithiation/trapping sequence

Arianna Tota, Flavio Fanelli, Aurelia Falcicchio, Renzo Luisi and Leonardo Degennaro

Chem Heterocycl Comp, 2017, 53, 322
DOI: 10.1007/s10593-017-2060-6

Bicyclo[1.1.1]pentyl Sulfoximines: Synthesis and Functionalizations

Robin M. Bär, Lukas Langer, Martin Nieger and Stefan Bräse

Adv Synth Catal, 2020, 362, 1356
DOI: 10.1002/adsc.201901453

One‐Pot Synthesis of Aryl‐ and Alkyl S‐Perfluoroalkylated NH‐Sulfoximines from Sulfides

Slim Chaabouni, Jean‐François Lohier, Anne‐Laure Barthelemy, Thomas Glachet, Elsa Anselmi, Guillaume Dagousset, Patrick Diter, Bruce Pégot, Emmanuel Magnier and Vincent Reboul

Chemistry A European J, 2018, 24, 17006
DOI: 10.1002/chem.201805055

I2/PhI(OAc)2 Copromoted Amination Reaction: Synthesis of α-Dicarbonylsulfoximine Derivatives by Incorporating an Intact Dimethyl Sulfoxide

Peng Zhao, Xia Wu, Xiao Geng, Can Wang, You Zhou, Yan-Dong Wu and An-Xin Wu

J. Org. Chem., 2019, 84, 8322
DOI: 10.1021/acs.joc.9b01160

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis

Philip R. D. Murray, James H. Cox, Nicholas D. Chiappini, Casey B. Roos, Elizabeth A. McLoughlin, Benjamin G. Hejna, Suong T. Nguyen, Hunter H. Ripberger, Jacob M. Ganley, Elaine Tsui, Nick Y. Shin, Brian Koronkiewicz, Guanqi Qiu and Robert R. Knowles

Chem. Rev., 2022, 122, 2017
DOI: 10.1021/acs.chemrev.1c00374

Increasing Complexity: A Practical Synthetic Approach to Three‐Dimensional, Cyclic Sulfoximines and First Insights into Their in Vitro Properties

Emilie Boulard, Vivien Zibulski, Luisa Oertel, Philip Lienau, Martina Schäfer, Ursula Ganzer and Ulrich Lücking

Chemistry A European J, 2020, 26, 4378
DOI: 10.1002/chem.201905461

Palladium(II)‐Catalyzed N‐Carbonylative Cross‐Coupling Reaction of Sulfoximines with Aryl, Heteroaryl, and Alkenyl Halides Using Tungsten Hexacarbonyl as Carbon Monoxide Source

Sang Hoon Han, Kyungsup Lee, Hee Chan Noh and Phil Ho Lee

Asian J Org Chem, 2021, 10, 2397
DOI: 10.1002/ajoc.202100388

Selective Deuteration and Tritiation of Pharmaceutically Relevant Sulfoximines

Blair I. P. Smith, Nathan M. L. Knight, Gary J. Knox, David M. Lindsay, Laura C. Paterson, Jonas Bergare, Charles S. Elmore, Ryan A. Bragg and William J. Kerr

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202417179

Straightforward Synthesis of Functionalized 4,5,6,7‐Tetrahydro‐pyrazolo[1,5‐a]pyrazines – Important Building Blocks for Medicinal Chemistry

Vladimir I. Bozhanov, Dmytro P. Bohdan, Oleksandr V. Borysov, Aleksey V. Silin, Oleg V. Zaremba, Mykola M. Avramenko, Dmitriy M. Volochnyuk, Sergey V. Ryabukhin and Konstantin S. Gavrilenko

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202104287

Multistep Continuous Flow Synthesis of Isolable NH2‐Sulfinamidines via Nucleophilic Addition to Transient Sulfurdiimide

Michael Andresini, Sébastien Carret, Leonardo Degennaro, Fulvio Ciriaco, Jean‐François Poisson and Renzo Luisi

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202202066

Exploration of Novel Chemical Space: Synthesis and in vitro Evaluation of N‐Functionalized Tertiary Sulfonimidamides

Flavia Izzo, Martina Schäfer, Philip Lienau, Ursula Ganzer, Robert Stockman and Ulrich Lücking

Chemistry A European J, 2018, 24, 9295
DOI: 10.1002/chem.201801557

Importance of Binding Site Hydration and Flexibility Revealed When Optimizing a Macrocyclic Inhibitor of the Keap1–Nrf2 Protein–Protein Interaction

Fabio Begnini, Stefan Geschwindner, Patrik Johansson, Lisa Wissler, Richard J. Lewis, Emma Danelius, Andreas Luttens, Pierre Matricon, Jens Carlsson, Stijn Lenders, Beate König, Anna Friedel, Peter Sjö, Stefan Schiesser and Jan Kihlberg

J. Med. Chem., 2022, 65, 3473
DOI: 10.1021/acs.jmedchem.1c01975

Sulfoximines-Assisted Rh(III)-Catalyzed C–H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature

Bao Wang, Xu Han, Jian Li, Chunpu Li and Hong Liu

Molecules, 2020, 25, 2515
DOI: 10.3390/molecules25112515

Decarboxylative Radical Sulfilimination via Photoredox, Copper, and Brønsted Base Catalysis

Mingjun Zhang, Lixia Liu, Yuhao Tan, Yue Jing, Yuxiu Liu, Ziwen Wang and Qingmin Wang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202318344

Electrochemical N‐Aroylation of Sulfoximines by Using Benzoyl Hydrazines with H2 Generation

Tipu Alam and Bhisma K. Patel

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303444

Oxidative Coupling with S–N Bond Formation

Olga M. Mulina, Alexey I. Ilovaisky and Alexander O. Terent'ev

Eur J Org Chem, 2018, 2018, 4648
DOI: 10.1002/ejoc.201800838

3-Functional substituted 4-trifluoromethyl tetrahydrothiophenes via [3 + 2]-cycloaddition reactions

Yuriy M. Markitanov, Vadim M. Timoshenko, Tymofii V. Rudenko, Eduard B. Rusanov and Yuriy G. Shermolovich

Journal of Sulfur Chemistry, 2019, 40, 629
DOI: 10.1080/17415993.2019.1633326

Synthesis of Sulfoximines and Sulfonimidamides Using Hypervalent Iodine Mediated NH Transfer

Renzo Luisi and James A. Bull

Molecules, 2023, 28, 1120
DOI: 10.3390/molecules28031120

Rapid and chemoselective imidation of sulfides in aqueous buffer enabled by a novel guanidine-derived N-O reagent

Hanzheng Li, Long Xu and Jiajia Dong

Sci. China Chem., 2024, 67, 1929
DOI: 10.1007/s11426-023-1947-8

Stereoselective Synthesis of Cyclobutanes by Contraction of Pyrrolidines

Chunngai Hui, Lukas Brieger, Carsten Strohmann and Andrey P. Antonchick

J. Am. Chem. Soc., 2021, 143, 18864
DOI: 10.1021/jacs.1c10175

Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides

Michael Andresini, Mauro Spennacchio, Giuseppe Romanazzi, Fulvio Ciriaco, Guy Clarkson, Leonardo Degennaro and Renzo Luisi

Org. Lett., 2020, 22, 7129
DOI: 10.1021/acs.orglett.0c02471

Synthesis of Sulfonimidamides from Sulfenamides via an Alkoxy‐amino‐λ6‐sulfanenitrile Intermediate

Edward L. Briggs, Arianna Tota, Marco Colella, Leonardo Degennaro, Renzo Luisi and James A. Bull

Angewandte Chemie, 2019, 131, 14441
DOI: 10.1002/ange.201906001

Rapid Assembly of Tetrasubstituted Furans via Pummerer-Type Rearrangement

Franz-Lucas Haut, Christoph Habiger, Lukas A. Wein, Klaus Wurst, Maren Podewitz and Thomas Magauer

J. Am. Chem. Soc., 2021, 143, 1216
DOI: 10.1021/jacs.0c12194

The design, synthesis and antiplasmodial evaluation of novel sulfoximine-isoxazole hybrids as potential antimalarial agents

Jackie L. Mabasa, Tommy F. Mabasa, Musawenkosi L. Nyathi and Paseka T. Moshapo

European Journal of Medicinal Chemistry Reports, 2024, 10, 100128
DOI: 10.1016/j.ejmcr.2023.100128

Dibenzothiophene Sulfoximine as an NH3 Surrogate in the Synthesis of Primary Amines by Copper‐Catalyzed C−X and C−H Bond Amination

Zhen Li, Hao Yu and Carsten Bolm

Angewandte Chemie, 2017, 129, 9660
DOI: 10.1002/ange.201705025

A rapid and selective methionine oxidative modification strategy

Meng‐Qian Zhang, Pei‐Yang He, Jin‐Jian Hu and Yan‐Mei Li

Journal of Peptide Science, 2023, 29
DOI: 10.1002/psc.3454

I2‐Catalyzed N‐Sulfonylation of Sulfoximines with Sulfinates in Water at Room Temperature

Wenting Zheng, Mingchao Tan, Lu Yang, Lihong Zhou and Qingle Zeng

Eur J Org Chem, 2020, 2020, 1764
DOI: 10.1002/ejoc.202000120

Palladium-Catalyzed Oxidative Annulation of Sulfoximines and Arynes by C–H Functionalization as an Approach to Dibenzothiazines

Shan Li, Liansheng Liu, Rong Wang, Yihui Yang, Jing Li and Junfa Wei

Org. Lett., 2020, 22, 7470
DOI: 10.1021/acs.orglett.0c02615

Photochemistry of N‐Phenyl Dibenzothiophene Sulfoximine†

Ankita Isor, Renè Hommelsheim, Grant W. Cone, Marcus Frings, John T. Petroff, Carsten Bolm and Ryan D. McCulla

Photochem & Photobiology, 2021, 97, 1322
DOI: 10.1111/php.13456

Oxidative Nitrogen Insertion into Silyl Enol Ether C═C Bonds

Alex Lin, Arghya Ghosh, Simon Yellen, Zachary T. Ball and László Kürti

J. Am. Chem. Soc., 2024, 146, 21129
DOI: 10.1021/jacs.4c07111

Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents

Akira Yoshimura and Viktor V. Zhdankin

Chem. Rev., 2024, 124, 11108
DOI: 10.1021/acs.chemrev.4c00303

Sulfonimidamides: Synthesis and Applications in Preparative Organic Chemistry

Ganesh Chandra Nandi and Per I. Arvidsson

Adv Synth Catal, 2018, 360, 2976
DOI: 10.1002/adsc.201800273

Enantioselective Synthesis of Chiral‐at‐Sulfur 1,2‐Benzothiazines by CpxRhIII‐Catalyzed C−H Functionalization of Sulfoximines

Yang Sun and Nicolai Cramer

Angew Chem Int Ed, 2018, 57, 15539
DOI: 10.1002/anie.201810887

Synthesis of novel five-membered endocyclic sulfoximines — 1-aryl-3-(arylimino)-3,5-dihydro-1,4,2-dithiazole 1-oxides

Yong Hua, Wenjie Zhang, Xin Wang, Zemei Ge and Runtao Li

Tetrahedron, 2017, 73, 4387
DOI: 10.1016/j.tet.2017.05.098

Molybdenumhexacarbonyl‐Mediated Imino‐Carbonylative Acylation of NH‐Sulfoximines with Aryl Iodides

Siddharth Baranwal, Surabhi Gupta, Shahulhameed Sabiah and Jeyakumar Kandasamy

Asian J Org Chem, 2019, 8, 2218
DOI: 10.1002/ajoc.201900526

Sulfinimidate Esters as an Electrophilic Sulfinimidoyl Motif Source: Synthesis of N-Protected Sulfilimines from Grignard Reagents

Michael Andresini, Mauro Spennacchio, Marco Colella, Gianluca Losito, Andrea Aramini, Leonardo Degennaro and Renzo Luisi

Org. Lett., 2021, 23, 6850
DOI: 10.1021/acs.orglett.1c02413

Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis

Mathias Hermann, Daniel Wassy, Julia Kohn, Philipp Seitz, Martin U. Betschart, Stefan Grimme and Birgit Esser

Angew Chem Int Ed, 2021, 60, 10680
DOI: 10.1002/anie.202016968

BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units

Felix Brosge, Thomas Lorenz, Holger Helten and Carsten Bolm

Chemistry A European J, 2019, 25, 12708
DOI: 10.1002/chem.201903289

Synthesis of New Sulfoximine‐Tethered Alkynones and Further Extension towards Metal‐Free Synthesis of Pyrimidines, Amino Pyrimidines, Pyrazoles and Isoxazoles

M. L. Chenna Reddy, Fazlur Rahman Nawaz Khan and Vadivelu Saravanan

ChemistrySelect, 2019, 4, 9573
DOI: 10.1002/slct.201902774

Synthesis of Sulfonimidamides from Sulfenamides via an Alkoxy‐amino‐λ6‐sulfanenitrile Intermediate

Edward L. Briggs, Arianna Tota, Marco Colella, Leonardo Degennaro, Renzo Luisi and James A. Bull

Angew Chem Int Ed, 2019, 58, 14303
DOI: 10.1002/anie.201906001

Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Functionalization of Sulfoximines

Long-Tao Huang, Yuki Hirata, Yoshimi Kato, Luqing Lin, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

Synthesis, 2022, 54, 4703
DOI: 10.1055/a-1588-0072