Kevin Lindenau, Nora Jannsen, Mirko Rippke, Hanan Al Hamwi, Carmen Selle, Hans-Joachim Drexler, Anke Spannenberg, Mathias Sawall, Klaus Neymeyr, Detlef Heller, Fabian Reiß and Torsten Beweries

Catal. Sci. Technol., 2021, 11, 4034
DOI: 10.1039/D1CY00531F

N-Silylamines in catalysis: synthesis and reactivity

Vani Verma, Ana Koperniku, Peter M. Edwards and Laurel L. Schafer

Chem. Commun., 2022, 58, 9174
DOI: 10.1039/D2CC02915D

Silicon–nitrogen bond formation via dealkynative coupling of amines with bis(trimethylsilyl)acetylene mediated by KHMDS

Krzysztof Kuciński and Grzegorz Hreczycho

Chem. Commun., 2022, 58, 11386
DOI: 10.1039/D2CC04413G

Mechanism, catalysis and predictions of 1,3,2-diazaphospholenes: theoretical insight into highly polarized P–X bonds

Liu Leo Liu, Yile Wu, Peng Chen, Chinglin Chan, Ji Xu, Jun Zhu and Yufen Zhao

Org. Chem. Front., 2016, 3, 423
DOI: 10.1039/C6QO00002A

Base-catalyzed addition of silylacetylenes to ketones: a route to protected tertiary propargyl alcohols

Krzysztof Kuciński, Alicja Łuczak, Aliaksei Mankouski and Grzegorz Hreczycho

Org. Chem. Front., 2023, 10, 2752
DOI: 10.1039/D3QO00579H

Investigation of the rhodium-catalyzed hydroboration of NHC-boranes: the role of alkene coordination and the origin of enantioselectivity

Paola Nava, Momar Toure, Amel Abdou Mohamed, Jean-Luc Parrain and Olivier Chuzel

Dalton Trans., 2019, 48, 17605
DOI: 10.1039/C9DT03660A

Main group metal–ligand cooperation of N-heterocyclic germylene: an efficient catalyst for hydroboration of carbonyl compounds

Yile Wu, Changkai Shan, Ying Sun, Peng Chen, Jianxi Ying, Jun Zhu, Liu Leo Liu and Yufen Zhao

Chem. Commun., 2016, 52, 13799
DOI: 10.1039/C6CC08147A

Dialumenes – arylvs.silyl stabilisation for small molecule activation and catalysis

Catherine Weetman, Amelie Porzelt, Prasenjit Bag, Franziska Hanusch and Shigeyoshi Inoue

Chem. Sci., 2020, 11, 4817
DOI: 10.1039/D0SC01561J

Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle

Anna Bücker, Christoph Wölper, Gebhard Haberhauer and Stephan Schulz

Chem. Commun., 2022, 58, 9758
DOI: 10.1039/D2CC03561H

Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation

Ekaterina S. Gulyaeva, Elena S. Osipova, Sergey A. Kovalenko, Oleg A. Filippov, Natalia V. Belkova, Laure Vendier, Yves Canac, Elena S. Shubina and Dmitry A. Valyaev

Chem. Sci., 2024, 15, 1409
DOI: 10.1039/D3SC05356C

Sustainable preparation of aminosilane monomers, oligomers, and polymers through Si–N dehydrocoupling catalysis

Brock E. Leland, Joydeb Mondal and Ryan J. Trovitch

Chem. Commun., 2023, 59, 3665
DOI: 10.1039/D2CC07092H

Synthesis, characterisation and reactivity of group 2 complexes with a thiopyridyl scorpionate ligand

Matthew P. Stevens, Emily Spray, Iñigo J. Vitorica-Yrezabal, Kuldip Singh, Vanessa M. Timmermann, Lia Sotorrios, Stuart A. Macgregor and Fabrizio Ortu

Dalton Trans., 2022, 51, 11922
DOI: 10.1039/D2DT02012B

1,3-Dipolar cyclisation reactions of nitriles with sterically encumbered cyclic triphosphanes: synthesis and electronic structure of phosphorus-rich heterocycles with tunable colour

Mitchell A. Nascimento, Etienne A. LaPierre, Brian O. Patrick, Jade E. T. Watson, Lara Watanabe, Jeremy Rawson, Christian Hering-Junghans and Ian Manners

Chem. Sci., 2024, 15, 12006
DOI: 10.1039/D4SC02497D

Grignard reagents as simple precatalysts for the dehydrocoupling of amines and silanes

Claire E. Bushey, Diego R. Javier-Jiménez, Matthew B. Reuter and Rory Waterman

Dalton Trans., 2024, 53, 16843
DOI: 10.1039/D4DT02403F

Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Roberto Nolla-Saltiel, Ana M. Geer, William Lewis, Alexander J. Blake and Deborah L. Kays

Chem. Commun., 2018, 54, 1825
DOI: 10.1039/C7CC08385H

Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols

Rebeca González-Fernández, Pascale Crochet and Victorio Cadierno

Dalton Trans., 2020, 49, 210
DOI: 10.1039/C9DT04421C

Metallfreie B−B Dehydrokupplung eines Einfachen Boran‐Addukts: Bequemer Zugang zu einem Nukleophilen Diboran(4)

Lucas Kistner, Lukas Maximilian Sigmund, Fabian Frank Grieser, Julian Krauß, Simone Leingang, Elisabeth Kaifer, Lutz Greb and Hans‐Jörg Himmel

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202317462

Iron Catalyzed Dehydrocoupling of Amine‐ and Phosphine‐Boranes

Nathan T. Coles and Ruth L. Webster

Israel Journal of Chemistry, 2017, 57, 1070
DOI: 10.1002/ijch.201700018

Aluminum Amidinates: Insights into Alkyne Hydroboration

Katie Hobson, Claire J. Carmalt and Clare Bakewell

Inorg. Chem., 2021, 60, 10958
DOI: 10.1021/acs.inorgchem.1c00619

Reactivity of [TismPriBenz]MgMe towards secondary amines and terminal alkynes: Catalytic dehydrocoupling with hydrosilanes to afford Si–N and Si–C bonds

Michael Rauch, Renee C. Roberts and Gerard Parkin

Inorganica Chimica Acta, 2019, 494, 271
DOI: 10.1016/j.ica.2019.03.015

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

Ross McLellan, Alan R. Kennedy, Robert E. Mulvey, Samantha A. Orr and Stuart D. Robertson

Chemistry A European J, 2017, 23, 16853
DOI: 10.1002/chem.201703609

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

Lara E. Lemmerz, Ross McLellan, Neil R. Judge, Alan R. Kennedy, Samantha A. Orr, Marina Uzelac, Eva Hevia, Stuart D. Robertson, Jun Okuda and Robert E. Mulvey

Chemistry A European J, 2018, 24, 9940
DOI: 10.1002/chem.201801541

Inorganometallics (Transition Metal–Metalloid Complexes) and Catalysis

Bogdan Marciniec, Cezary Pietraszuk, Piotr Pawluć and Hieronim Maciejewski

Chem. Rev., 2022, 122, 3996
DOI: 10.1021/acs.chemrev.1c00417

Recent advances in transition metal catalysed dehydropolymerisation of amine boranes and phosphine boranes

Delong Han, Felix Anke, Michael Trose and Torsten Beweries

Coordination Chemistry Reviews, 2019, 380, 260
DOI: 10.1016/j.ccr.2018.09.016

Dehydrogenation of (Di)amine–Boranes by Highly Active Scandocene Alkyl Catalysts

Pengfei Xu and Xin Xu

Organometallics, 2019, 38, 3212
DOI: 10.1021/acs.organomet.9b00461

Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols

Xianya Wang, Chungu Xia and Lipeng Wu

Org. Lett., 2020, 22, 7373
DOI: 10.1021/acs.orglett.0c02746

Atypical and Asymmetric 1,3‐P,N Ligands: Synthesis, Coordination and Catalytic Performance of Cycloiminophosphanes

Mark K. Rong, Flip Holtrop, Eduard O. Bobylev, Martin Nieger, Andreas W. Ehlers, J. Chris Slootweg and Koop Lammertsma

Chemistry A European J, 2021, 27, 14007
DOI: 10.1002/chem.202101921

Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts

Lipeng Wu, Vincent T. Annibale, Haijun Jiao, Adam Brookfield, David Collison and Ian Manners

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-09832-4

Alkaline-Earth Derivatives of Diphenylphosphine–Borane

Louis J. Morris, Michael S. Hill, Mary F. Mahon, Ian Manners and Brian O. Patrick

Organometallics, 2020, 39, 4195
DOI: 10.1021/acs.organomet.0c00008

Practical and Scalable Synthesis of Borylated Heterocycles Using Bench-Stable Precursors of Metal-Free Lewis Pair Catalysts

Arumugam Jayaraman, Luis C. Misal Castro and Frédéric-Georges Fontaine

Org. Process Res. Dev., 2018, 22, 1489
DOI: 10.1021/acs.oprd.8b00248

Dehydrocyclization of diamine borane and amine-borane alcohol catalyzed by 1-lithio-2-alkyl-1,2-dihydropyridine and its Na & K analogues: A DFT analysis of the reaction mechanism

Avik Ghosh, Tanay Debnath, Tamalika Ash and Abhijit K. Das

International Journal of Hydrogen Energy, 2019, 44, 28731
DOI: 10.1016/j.ijhydene.2019.09.099

NHI- and NHC-Supported Al(III) Hydrides for Amine–Borane Dehydrocoupling Catalysis

Catherine Weetman, Nozomi Ito, Masafumi Unno, Franziska Hanusch and Shigeyoshi Inoue

Inorganics, 2019, 7, 92
DOI: 10.3390/inorganics7080092

Transition Metal‐Free Catalytic C−H Silylation of Terminal Alkynes with bis(Trimethylsilyl)acetylene Initiated by KHMDS

Krzysztof Kuciński and Grzegorz Hreczycho

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200794

Rhodium-Catalyzed Asymmetric Dehydrocoupling: Enantioselective Synthesis of a P-Stereogenic Diphospholane with Mistake-Correcting Diastereoselectivity

Sarah T. Chachula, Perry M. Scheetz, Andrew H. Zureick, Russell P. Hughes, David S. Glueck, Ritchie E. Hernandez, Joshua S. Figueroa and Arnold L. Rheingold

Organometallics, 2023, 42, 1448
DOI: 10.1021/acs.organomet.3c00188

High‐temperature platinum‐catalyzed hydrosilylation and dehydrocoupling cross‐linking of silicones

Sofia S. Filippova, Konstantin V. Deriabin, Ekaterina A. Golovenko, Sergey V. Baykov, Nikita S. Antonov, Vadim P. Boyarskiy and Regina M. Islamova

Applied Organom Chemis, 2023, 37
DOI: 10.1002/aoc.7249

A [HN(BH═NH)2]2– Dianion, Isoelectronic with a β-Diketiminate

Robert J. Less, Schirin Hanf, Raúl García-Rodríguez, Andrew D. Bond and Dominic S. Wright

Organometallics, 2018, 37, 628
DOI: 10.1021/acs.organomet.7b00436

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

Victoria A. Pollard, Allan Young, Ross McLellan, Alan R. Kennedy, Tell Tuttle and Robert E. Mulvey

Angewandte Chemie, 2019, 131, 12419
DOI: 10.1002/ange.201906807

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes

Carsten Lenczyk, Dipak Kumar Roy, Jörn Nitsch, Krzysztof Radacki, Florian Rauch, Rian D. Dewhurst, F. Matthias Bickelhaupt, Todd B. Marder and Holger Braunschweig

Chemistry A European J, 2019, 25, 13566
DOI: 10.1002/chem.201902890

Synthesis of Mono- and Acyclic Bis-aminoboranes via Controlled Hydroboration of Imines

Siyuan Zhai, Craig Forsyth, Zhizhou Liu and Dragoslav Vidović

Organometallics, 2022, 41, 2562
DOI: 10.1021/acs.organomet.2c00283

Ruthenium‐Photocatalyzed Synthesis of Borasiloxanes in a One‐Pot Manner from Readily Available Silanes and Pinacolborane

Wei Wu, Jingchao Chen, Lulin Qiao, Haiping Lv, Fuqin Zhang, Yuanbin Zhu, Shiyuan Wu and Baomin Fan

Asian J Org Chem, 2021, 10, 3249
DOI: 10.1002/ajoc.202100544

The Road Travelled: After Main‐Group Elements as Transition Metals

Catherine Weetman and Shigeyoshi Inoue

ChemCatChem, 2018, 10, 4213
DOI: 10.1002/cctc.201800963

Activation of heteroallenes by metal-substituted electron-rich tetrylenes

Anna Bücker, Christoph Wölper and Stephan Schulz

Polyhedron, 2024, 247, 116702
DOI: 10.1016/j.poly.2023.116702

Metal‐Free B−B Dehydrocoupling Reaction of a Simple Borane Adduct: Convenient Access to a Nucleophilic Diborane(4)

Lucas Kistner, Lukas Maximilian Sigmund, Fabian Frank Grieser, Julian Krauß, Simone Leingang, Elisabeth Kaifer, Lutz Greb and Hans‐Jörg Himmel

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202317462

Stable Organic Neutral Diradical via Reversible Coordination

Zhenpin Lu, Henrik Quanz, Olaf Burghaus, Jonas Hofmann, Christian Logemann, Sebastian Beeck, Peter R. Schreiner and Hermann A. Wegner

J. Am. Chem. Soc., 2017, 139, 18488
DOI: 10.1021/jacs.7b11823

Zinc-Catalyzed Chemoselective Reduction of Nitriles to N-Silylimines through Hydrosilylation: Insights into the Reaction Mechanism

Rajata Kumar Sahoo and Sharanappa Nembenna

Inorg. Chem., 2023, 62, 12213
DOI: 10.1021/acs.inorgchem.3c00309

Iron-Mediated Si–H Bond Activation: Synthesis, Characterization and Spectral Properties of a Series of FeII(H)(SiR3)(dmpe)2 Complexes

Till Neumann, Vincent Wowk, Faycel Djebbar, Lise-Marie Chamoreau and Guillaume Lefèvre

Inorg. Chem., 2025, 64, 22251
DOI: 10.1021/acs.inorgchem.5c03278

Non-Metal-Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes: Mechanistic Studies of B(C6F5)3-Mediated Formation of P–Si Bonds

Lipeng Wu, Saurabh S. Chitnis, Haijun Jiao, Vincent T. Annibale and Ian Manners

J. Am. Chem. Soc., 2017, 139, 16780
DOI: 10.1021/jacs.7b09175

Doping the Backbone of π‐Conjugated Polymers with Tricoordinate Boron: Synthetic Strategies and Emerging Applications

Holger Helten

Chemistry An Asian Journal, 2019, 14, 919
DOI: 10.1002/asia.201900016

Cobalt-catalyzed synthesis of silyl ethers via cross-dehydrogenative coupling between alcohols and hydrosilanes

Ewelina Szafoni, Krzysztof Kuciński and Grzegorz Hreczycho

Green Chemistry Letters and Reviews, 2022, 15, 757
DOI: 10.1080/17518253.2022.2133554

Metal-Free Bond Activation by Carboranyl Diphosphines

Gayathri B. Gange, Amanda L. Humphries, Dmitry E. Royzman, Mark D. Smith and Dmitry V. Peryshkov

J. Am. Chem. Soc., 2021, 143, 10842
DOI: 10.1021/jacs.1c05387

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

Florian Schön, Lukas M. Sigmund, Friederike Schneider, Deborah Hartmann, Matthew A. Wiebe, Ian Manners and Lutz Greb

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202202176

Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis

Pradip Ghosh, Roland Schoch, Matthias Bauer and Axel Jacobi von Wangelin

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202110821

Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis

Pradip Ghosh, Roland Schoch, Matthias Bauer and Axel Jacobi von Wangelin

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202110821

Rare-earth metal bis(alkyl) amidopyridinate complexes in dehydrocoupling of anisole with hydrosilanes

G. K. Shumsky, A. A. Kissel, Yu. V. Nelyubina and A. A. Trifonov

Russ Chem Bull, 2024, 73, 2872
DOI: 10.1007/s11172-024-4404-6

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

Ross McLellan, Alan R. Kennedy, Samantha A. Orr, Stuart D. Robertson and Robert E. Mulvey

Angewandte Chemie, 2017, 129, 1056
DOI: 10.1002/ange.201610905

Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes

Evgenia D. Voronova, Igor E. Golub, Alexander Pavlov, Natalia V. Belkova, Oleg A. Filippov, Lina M. Epstein and Elena S. Shubina

Inorg. Chem., 2020, 59, 12240
DOI: 10.1021/acs.inorgchem.0c01293

Catalytic Dehydrogenation of Amine‐Boranes using Geminal Phosphino‐Boranes

Devin H. A. Boom, Ewoud J. J. de Boed, Emmanuel Nicolas, Martin Nieger, Andreas W. Ehlers, Andrew R. Jupp and J. Chris Slootweg

Zeitschrift anorg allge chemie, 2020, 646, 586
DOI: 10.1002/zaac.201900313

Dealkanative Main Group Couplings across the peri-Gap

Laurence J. Taylor, Michael Bühl, Brian A. Chalmers, Matthew J. Ray, Piotr Wawrzyniak, John C. Walton, David B. Cordes, Alexandra M. Z. Slawin, J. Derek Woollins and Petr Kilian

J. Am. Chem. Soc., 2017, 139, 18545
DOI: 10.1021/jacs.7b08682

Role of the Base in Dehydrocoupling Reaction of Phenylsilane with Methanol

Vasilisa A. Kulikova, Evgenii I. Gutsul, Oleg A. Filippov, Natalia V. Belkova and Elena S. Shubina

Russ J Gen Chem, 2026, 96
DOI: 10.1134/S107036322560804X

Unraveling a Biomass-Derived Multiphase Catalyst for the Dehydrogenative Coupling of Silanes with Alcohols under Aerobic Conditions

Iván Sorribes, David Ventura-Espinosa, Marcelo Assis, Santiago Martín, Patricia Concepción, Jefferson Bettini, Elson Longo, Jose A. Mata and Juan Andrés

ACS Sustainable Chem. Eng., 2021, 9, 2912
DOI: 10.1021/acssuschemeng.0c08953

Application of direct analysis in real time to the study of chemical vapor generation mechanisms: identification of intermediate hydrolysis products of amine-boranes

Lucia D’Ulivo, Enea Pagliano, Massimo Onor, Zoltan Mester and Alessandro D’Ulivo

Anal Bioanal Chem, 2019, 411, 1569
DOI: 10.1007/s00216-019-01598-4

Electrochemical Direct Thiolation of Lactams with Mercaptans: An Efficient Access to N‐Acylsulfenamides

Zhaoxin Wei, Renjie Wang, Yonghong Zhang, Bin Wang, Yu Xia, Ablimit Abdukader, Fei Xue, Weiwei Jin and Chenjiang Liu

Eur J Org Chem, 2021, 2021, 4728
DOI: 10.1002/ejoc.202100924

Catalytic Formation of Silicon–Heteroatom (N, P, O, S) Bonds

Krzysztof Kuciński and Grzegorz Hreczycho

ChemCatChem, 2017, 9, 1868
DOI: 10.1002/cctc.201700054

Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species

Hanna Stachowiak-Dłużyńska, Krzysztof Kuciński, Konstancja Broniarz, Ewelina Szafoni, Marcin Gruszczyński, Dariusz Lewandowski, Giuseppe Consiglio and Grzegorz Hreczycho

Sci Rep, 2023, 13
DOI: 10.1038/s41598-023-32172-9

A Highly Active Bidentate Magnesium Catalyst for Amine‐Borane Dehydrocoupling: Kinetic and Mechanistic Studies

Alexander C. A. Ried, Laurence J. Taylor, Ana M. Geer, Huw E. L. Williams, William Lewis, Alexander J. Blake and Deborah L. Kays

Chemistry A European J, 2019, 25, 6840
DOI: 10.1002/chem.201901197

A Dehydrocoupling Approach Towards Titanocene Iminophosphane Complexes

Andrey Petrov and Christian Hering‐Junghans

Eur J Inorg Chem, 2025, 28
DOI: 10.1002/ejic.202400578

Heavier Alkaline‐Earth Catalyzed Dehydrocoupling of Silanes and Alcohols for the Synthesis of Metallo‐Polysilylethers

Louis J. Morris, Michael S. Hill, Mary F. Mahon, Ian Manners, Fred S. McMenamy and George R. Whittell

Chemistry A European J, 2020, 26, 2954
DOI: 10.1002/chem.201905313

Catalytic silylation of O–nucleophiles via Si–H or Si–C bond cleavage: A route to silyl ethers, silanols and siloxanes

Krzysztof Kuciński, Hanna Stachowiak-Dłużyńska and Grzegorz Hreczycho

Coordination Chemistry Reviews, 2022, 459, 214456
DOI: 10.1016/j.ccr.2022.214456

Phosphine- and Amine-Borane Dehydrocoupling Using a Three-Coordinate Iron(II) β-Diketiminate Precatalyst

Nathan T. Coles, Mary F. Mahon and Ruth L. Webster

Organometallics, 2017, 36, 2262
DOI: 10.1021/acs.organomet.7b00326

Constrained Geometry ansa‐Half‐Sandwich Complexes of Magnesium – Versatile s‐Block Catalysts

Lisa Wirtz, Kinza Yasmin Ghulam, Bernd Morgenstern and André Schäfer

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202201007

Magnesocenophane‐Catalyzed Amine Borane Dehydrocoupling

Lisa Wirtz, Wasim Haider, Volker Huch, Michael Zimmer and André Schäfer

Chemistry A European J, 2020, 26, 6176
DOI: 10.1002/chem.202000106

Dehydrogenative Coupling Reactions with Oxidized Guanidino‐Functionalized Aromatic Compounds: Novel Options for σ‐Bond Activation

Ute Wild, Stefanie Federle, Arne Wagner, Elisabeth Kaifer and Hans‐Jörg Himmel

Chemistry A European J, 2016, 22, 11971
DOI: 10.1002/chem.201602236

Syntheses of Dianionic α-Iminopyridine Rare-Earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes

Xiuli Zhang, Shuangliu Zhou, Xiaofei Fang, Lijun Zhang, Guide Tao, Yun Wei, Xiancui Zhu, Peng Cui and Shaowu Wang

Inorg. Chem., 2020, 59, 9683
DOI: 10.1021/acs.inorgchem.0c00907

Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors

Nicola L. Oldroyd, Saurabh S. Chitnis, Vincent T. Annibale, Marius I. Arz, Hazel A. Sparkes and Ian Manners

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-08967-8

Rhodium‐Mediated Dehydrogenation of Hydroboranes and Group 14 Compounds: Base‐Stabilized Silylene and Germylene Complexes vs. Transmetalation

Shou‐Jen Hsiang and Paul G. Hayes

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202302925

Rising Opportunities in Catalytic Dehydrogenative Polymerization

Alejandra Sophia Lozano-Pérez, Pavel Kulyabin and Amit Kumar

ACS Catal., 2025, 15, 3619
DOI: 10.1021/acscatal.4c08091

B‐P Coupling: Metal Stabilized Phosphinoborate Complexes

Sourav Gayen, Sampad Shyamal, Stutee Mohapatra, P. K. Sudhadevi Antharjanam and Sundargopal Ghosh

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202302362

Reactivity of a Phosphinoamidinate-Stabilized Disilylene toward H–X Bonds

Aliona G. Baradzenka, Melanie Pilkington, Anton Dmitrienko, Razvan Simionescu and Georgii I. Nikonov

Inorg. Chem., 2021, 60, 13110
DOI: 10.1021/acs.inorgchem.1c01518

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

Ross McLellan, Alan R. Kennedy, Samantha A. Orr, Stuart D. Robertson and Robert E. Mulvey

Angew Chem Int Ed, 2017, 56, 1036
DOI: 10.1002/anie.201610905

Isolable Tin(II) Hydrides Featuring Sterically Undemanding Pincer-Type Ligands and Their Dehydrogenative Sn–Sn Bond Forming Reactions to Distannynes Promoted by Lewis Acidic Tri-sec-butylborane

Yu-Hua Lai, Wei-Chieh Chang, Kuan-Ting Chen, Ding-Hong Wu, Han-Jung Li, Li-Ching Shen, Ting-Shen Kuo and Hsueh-Ju Liu

Inorg. Chem., 2022, 61, 6026
DOI: 10.1021/acs.inorgchem.1c04019

Cross-Dehydrogenative Coupling of Secondary Amines with Silanes Catalyzed by Agostic Iridium-NSi Species

Marina Padilla, María Batuecas, Pilar García-Orduña, Israel Fernández and Francisco J. Fernández-Álvarez

Inorg. Chem., 2025, 64, 255
DOI: 10.1021/acs.inorgchem.4c04512

Magnesium(I)‐Mediated Dearomatizing Coupling of Pyridines and Subsequent Hydrogen Transfer Reactions

Zhenzhou Sun, Luomo Li, Li Yang, Shi‐Lu Chen, Xiao‐Hui Yang, Biao Wu and Xiao‐Juan Yang

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.202503394

Catalytic Dehydrogenation of Dimethylamine Borane by Highly Active Thorium and Uranium Metallocene Complexes

Karla A. Erickson and Jaqueline L. Kiplinger

ACS Catal., 2017, 7, 4276
DOI: 10.1021/acscatal.7b00967

Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

Yann Sarazin and Jean‐François Carpentier

The Chemical Record, 2016, 16, 2482
DOI: 10.1002/tcr.201600067

Rhodium-Catalyzed Isomerization of a Bis(secondary phosphine) to an Unsymmetrical Diphosphine via P–C Cleavage and P–P and C–H Bond Formation

Perry M. Scheetz, David S. Glueck and Arnold L. Rheingold

Organometallics, 2017, 36, 3387
DOI: 10.1021/acs.organomet.7b00515

Synthesis and Reactivity of Bis-tris(pyrazolyl)borate Lanthanide/Aluminum Heterobimetallic Trihydride Complexes

Tajrian Chowdhury, Fáinché Murphy, Alan R. Kennedy, Claire Wilson, Joy H. Farnaby and Catherine E. Weetman

Inorg. Chem., 2024, 63, 9390
DOI: 10.1021/acs.inorgchem.4c00824

Cleavage of the Inert C(sp2)–Ar σ-Bond of Alkenes by a Spatial Constrained Interaction with Phosphinidene

Junjian Wang, Donghui Wei, Zheng Duan and François Mathey

J. Am. Chem. Soc., 2020, 142, 20973
DOI: 10.1021/jacs.0c11195

Carbenoid‐Mediated Formation and Activation of Element‐Element and Element–Hydrogen Bonds

Katharina Dilchert, Thorsten Scherpf and Viktoria H. Gessner

Eur J Inorg Chem, 2020, 2020, 4111
DOI: 10.1002/ejic.202000860

Isolation of an N‐Heterocyclic Carbene Complex of a Borasilene

Daniel Franz, Tibor Szilvási, Alexander Pöthig and Shigeyoshi Inoue

Chemistry A European J, 2019, 25, 11036
DOI: 10.1002/chem.201902877

ChemInform Abstract: Dehydrocoupling Routes to Element—Element Bonds Catalyzed by Main Group Compounds

Rebecca L. Melen

ChemInform, 2016, 47
DOI: 10.1002/chin.201615247

Facile Access to Unprecedented Electron‐Precise Monohydrodiboranes(4), cis‐1,2‐Dihydrodiboranes(4), and a 1,1‐Dihydrodiborane(5)

Merle Arrowsmith, Holger Braunschweig, Krzysztof Radacki, Torsten Thiess and Arthur Turkin

Chemistry A European J, 2017, 23, 2179
DOI: 10.1002/chem.201605270

Comprehensive Insight into the Hydrogen Bonding of Silanes

Evgenia D. Voronova, Igor E. Golub, Alexander A. Pavlov, Natalia V. Belkova, Oleg A. Filippov, Lina M. Epstein and Elena S. Shubina

Chemistry An Asian Journal, 2018, 13, 3084
DOI: 10.1002/asia.201801156

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

Florian Schön, Lukas M. Sigmund, Friederike Schneider, Deborah Hartmann, Matthew A. Wiebe, Ian Manners and Lutz Greb

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202202176

Dehydrogenation of Amine–Boranes Using p‐Block Compounds

Devin H. A. Boom, Andrew R. Jupp and J. Chris Slootweg

Chemistry A European J, 2019, 25, 9133
DOI: 10.1002/chem.201900679

Catalytic Bond‐Forming Reactions Using Aluminium(III)

Dipanjana Choudhury and Dominic S. Wright

Eur J Inorg Chem, 2025, 28
DOI: 10.1002/ejic.202400638

Chemoselective and Catalyst‐Free O‐Borylation of Silanols: A Facile Access to Borasiloxanes

K. Kuciński and G. Hreczycho

ChemSusChem, 2017, 10, 4695
DOI: 10.1002/cssc.201701648

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

Victoria A. Pollard, Allan Young, Ross McLellan, Alan R. Kennedy, Tell Tuttle and Robert E. Mulvey

Angew Chem Int Ed, 2019, 58, 12291
DOI: 10.1002/anie.201906807

Synthesis and reactivity of a P–H functionalized benzazaphosphole

Miranda P. Howard, Preston M. Miura-Akagi, Timothy W. Chapp, Yuri J.H. Ah-Tye, Tomoko Kitano, Daniel Y. Zhou, Landon G. Balkwill, Wesley Y. Yoshida, Amy L. Fuller, Glenn P.A. Yap, Arnold L. Rheingold, Gabriela L. Borosky, Kenneth K. Laali and Matthew F. Cain

Polyhedron, 2024, 253, 116905
DOI: 10.1016/j.poly.2024.116905

Synthesis, Characterization, and Reactivity of a Pincer-Type Aluminum(III) Complex

Penglong Wang, Mingxing Zhang and Congqing Zhu

Organometallics, 2020, 39, 2732
DOI: 10.1021/acs.organomet.0c00325