Increasing the stability of calixarene-capped porous cages through coordination sphere tuning

Avishek Dey, Michael R. Dworzak, Kaushalya D. P. Korathotage, Munmun Ghosh, Jahidul Hoq, Christine M. Montone, Glenn P. A. Yap and Eric D. Bloch

Dalton Trans., 2024, 53, 4005
DOI: 10.1039/D3DT03365A

Constructing calixarene-supported high nuclearity Co27, Co28 and Ni18Na6 clusters with triazoles as co-bridges

Shentang Wang, Yanfeng Bi and Wuping Liao

CrystEngComm, 2015, 17, 2896
DOI: 10.1039/C5CE00314H

Designing structurally tunable and functionally versatile synthetic supercontainers

Feng-Rong Dai, Yupu Qiao and Zhenqiang Wang

Inorg. Chem. Front., 2016, 3, 243
DOI: 10.1039/C5QI00212E

Selective gas adsorption by calixarene-based porous octahedral M32coordination cages

Ivan V. Khariushin, Alexander S. Ovsyannikov, Stéphane A. Baudron, Jas S. Ward, Anniina Kiesilä, Kari Rissanen, Elina Kalenius, Konstantin A. Kovalenko, Vladimir P. Fedin, Svetlana E. Solovieva, Igor S. Antipin, Véronique Bulach and Sylvie Ferlay

Chem. Commun., 2022, 58, 13628
DOI: 10.1039/D2CC04510A

A monomeric bowl-like pyrogallol[4]arene Ti12 coordination complex

Kongzhao Su, Mingyan Wu, Yanxi Tan, Wenjing Wang, Daqiang Yuan and Maochun Hong

Chem. Commun., 2017, 53, 9598
DOI: 10.1039/C7CC05362B

Bridging different Co4–calix[4]arene building blocks into grids, cages and 2D polymers with chiral camphoric acid

Kongzhao Su, Feilong Jiang, Jinjie Qian, Jiandong Pang, Falu Hu, Salem M. Bawaked, Mohamed Mokhtar, Shaeel A. Al-Thabaiti and Maochun Hong

CrystEngComm, 2015, 17, 1750
DOI: 10.1039/C4CE02186J

In search of molecules displaying ferromagnetic exchange: multiple-decker Ni12 and Ni16 complexes from the use of pyridine-2-amidoxime

Constantinos G. Efthymiou, Luís Cunha-Silva, Spyros P. Perlepes, Euan K. Brechin, Ross Inglis, Marco Evangelisti and Constantina Papatriantafyllopoulou

Dalton Trans., 2016, 45, 17409
DOI: 10.1039/C6DT03511F

Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(ii)-based porous cages

Meaghan M. Deegan, Tonia S. Ahmed, Glenn P. A. Yap and Eric D. Bloch

Chem. Sci., 2020, 11, 5273
DOI: 10.1039/D0SC01833C

Sequestration of orange G and methylene blue from aqueous solutions using a Co(ii) coordination polymer

Cressa Ria P. Fulong and Timothy R. Cook

RSC Adv., 2017, 7, 26532
DOI: 10.1039/C7RA02286G

Controlling phase in low-nuclearity calixarene-capped porous coordination cages with ligand functionalization

Michael R. Dworzak, Casey A. Rowland, Glenn P. A. Yap and Eric D. Bloch

CrystEngComm, 2022, 24, 6315
DOI: 10.1039/D2CE00861K

pH-dependent formation of different coordination cages based on Co4-TC4A secondary building units and bridging ligands

Xinxin Hang, Shentang Wang, Xiaofei Zhu, Haitao Han and Wuping Liao

CrystEngComm, 2016, 18, 4938
DOI: 10.1039/C6CE00028B

Hexadecanuclear isobutyrate nanoclusters with a {CoII14CoIII2} core

Dumitru Stati, Jan van Leusen, Victor Ch. Kravtsov, Karl Krämer, Shi-Xia Liu, Silvio Decurtins, Paul Kögerler and Svetlana G. Baca

CrystEngComm, 2024, 26, 4264
DOI: 10.1039/D4CE00637B

Discrete polynuclear manganese(ii) complexes with thiacalixarene ligands: synthesis, structures and photophysical properties

Yan Suffren, Niall O'Toole, Andreas Hauser, Erwann Jeanneau, Arnaud Brioude and Cédric Desroches

Dalton Trans., 2015, 44, 7991
DOI: 10.1039/C5DT00827A

Thiacalix[4]arene-supported molecular clusters for catalytic applications

Xinxin Hang and Yanfeng Bi

Dalton Trans., 2021, 50, 3749
DOI: 10.1039/D0DT04233A

Edge-centred chirality-induced enantiopure square-like sulfonylcalix[4]arene-{Coii16} cages for selective (+)-/(−)-α-pinene adsorption

Ilia D. Shutilov, Pavel A. Volodin, Alexander S. Ovsyannikov, Ilya M. Zinoviev, Vladimir Yu. Guskov, Daut R. Islamov, Timur A. Mukhametzyanov, Meijin Lin, Pavel V. Dorovatovskii, Georgy S. Peters, Elizaveta S. Kulikova, Vladimir A. Burilov, Svetlana E. Solovieva and Igor S. Antipin

Chem. Commun., 2026, 62, 1986
DOI: 10.1039/D5CC05936D

Stimuli-responsive metal–organic supercontainers as synthetic proton receptors

Cheng-Zhe Sun, Li-Ji Cheng, Yupu Qiao, Li-Yi Zhang, Zhong-Ning Chen, Feng-Rong Dai, Wei Lin and Zhenqiang Wang

Dalton Trans., 2018, 47, 10256
DOI: 10.1039/C8DT01900B

Self-assembly of two high-nuclearity manganese calixarene-phosphonate clusters: diamond-like Mn16 and drum-like Mn14

Kongzhao Su, Feilong Jiang, Jinjie Qian, Jie Pan, Jiandong Pang, Xiuyan Wan, Falu Hu and Maochun Hong

RSC Adv., 2015, 5, 33579
DOI: 10.1039/C5RA02530C

Sensitive and selective urinary 1-hydroxypyrene detection by dinuclear terbium-sulfonylcalixarene complex

Cheng-Zhe Sun, Li-Yi Zhang, Jin-Yun Wang, Zhong-Ning Chen and Feng-Rong Dai

Dalton Trans., 2018, 47, 8301
DOI: 10.1039/C8DT01604F

Assembly of {Co14} nanoclusters from adenine-modified Co4-thiacalix[4]arene units

Yanan Yu, Zhao Wang, Ziping Li, Xinxin Hang and Yanfeng Bi

CrystEngComm, 2021, 23, 4382
DOI: 10.1039/D1CE00440A

A new family of anionic organic–inorganic hybrid doughnut-like nanostructures

Zhuxiu Zhang, Wen-Yang Gao, Lukasz Wojtas, Zhenjie Zhang and Michael J. Zaworotko

Chem. Commun., 2015, 51, 9223
DOI: 10.1039/C5CC02719E

Syntheses, structures, luminescence and magnetic properties of three high-nuclearity neodymium compounds based on mixed sulfonylcalix[4]arene-phosphonate ligands

Kongzhao Su, Feilong Jiang, Mingyan Wu, Jinjie Qian, Jiandong Pang, Daqiang Yuan and Maochun Hong

CrystEngComm, 2016, 18, 4921
DOI: 10.1039/C6CE00092D

Impact of flexible succinate connectors on the formation of tetrasulfonylcalix[4]arene based nano-sized polynuclear cages: structural diversity and induced chirality study

Mariia V. Kniazeva, Alexander S. Ovsyannikov, Aida I. Samigullina, Daut R. Islamov, Aidar T. Gubaidullin, Pavel V. Dorovatovskii, Vladimir A. Lazarenko, Svetlana E. Solovieva, Igor S. Antipin and Sylvie Ferlay

CrystEngComm, 2022, 24, 628
DOI: 10.1039/D1CE01482J

Covalent modification of surfaces with porous metal–organic materials

Christine M. Montone, Michael R. Dworzak, Glenn P. A. Yap and Eric D. Bloch

J. Mater. Chem. A, 2023, 11, 23888
DOI: 10.1039/D3TA04662A

Switching on Supramolecular Catalysis via Cavity Mediation and Electrostatic Regulation

Yupu Qiao, Long Zhang, Jia Li, Wei Lin and Zhenqiang Wang

Angew Chem Int Ed, 2016, 55, 12778
DOI: 10.1002/anie.201606847

A magnesium-based coordination container as a multi-drugs co-loaded system for boosting anti-inflammatory therapy in joints

Xuzhuo Chen, Can He, Tianpu Sheng, Zhenqiang Wang, Weifeng Xu, Fengrong Dai and Shanyong Zhang

Chemical Engineering Journal, 2021, 415, 128939
DOI: 10.1016/j.cej.2021.128939

Synthesis and Characterization of an Isoreticular Family of Calixarene-Capped Porous Coordination Cages

Michael R. Dworzak, Meaghan M. Deegan, Glenn P. A. Yap and Eric D. Bloch

Inorg. Chem., 2021, 60, 5607
DOI: 10.1021/acs.inorgchem.0c03554

A Novel Cobalt‐Based Molecular Container for pH‐Responsive Delivery and Synergistic Enhancement of Sorafenib Antitumor Efficacy

Zerui Lei, Jing Guo, Xinyue Wang, Han Zhang, Xu Zhang, Shuangyuan Chen, Jixing Zhao, Dongmei Qin, Zhenqiang Wang, Hui Tang and Cheng‐Zhe Sun

Applied Organom Chemis, 2025, 39
DOI: 10.1002/aoc.70461

Manipulation of Charged Porous Cages as Tunable Platforms for Strong Gas Adsorption

Meaghan M. Deegan, Alexandra M. Antonio, Kyle J. Korman, Andrew A. Ezazi, Kaushalya Korathotage, Merissa N. Morey, Jahidul Hoq, Duleeka Dissanayake, Dewni D. Fernando, Glenn P. A. Yap, David C. Powers and Eric D. Bloch

Chem. Mater., 2025, 37, 2404
DOI: 10.1021/acs.chemmater.4c02269

Switching on Supramolecular Catalysis via Cavity Mediation and Electrostatic Regulation

Yupu Qiao, Long Zhang, Jia Li, Wei Lin and Zhenqiang Wang

Angewandte Chemie, 2016, 128, 12970
DOI: 10.1002/ange.201606847

Hydrogen Storage in Porous Cages

Meaghan M. Deegan, Gregory R. Lorzing, Kyle J. Korman, Casey A. Rowland, Michael R. Dworzak, Alexandra M. Antonio and Eric D. Bloch

ACS Mater. Au, 2023, 3, 66
DOI: 10.1021/acsmaterialsau.2c00051

A window frame-like square constructed by bridging Co 4 -(TC4A-SO 2 ) SBUs with 1,3-bis(2H-tertazol-5-yl)benzene

Guoshuai Zhang, Xiaofei Zhu, Mei Liu and Wuping Liao

Journal of Molecular Structure, 2018, 1151, 29
DOI: 10.1016/j.molstruc.2017.09.024

Sensitive and Specific Guest Recognition through Pyridinium‐Modification in Spindle‐Like Coordination Containers

Nagarajan Bhuvaneswari, Feng‐Rong Dai and Zhong‐Ning Chen

Chemistry A European J, 2018, 24, 6580
DOI: 10.1002/chem.201705210

Charge Manipulation of Porous Coordination Cages Tunes the Efficiency and Selectivity in Electrochemical Synthesis

Zhifang Su, Kang‐Kai Liu, Yu‐Qi Xu, Bing Yan, Shuangyin Wang, Zong‐Jie Guan, Yuqin Zou and Yu Fang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420945

Biomimetic supercontainers for size-selective electrochemical sensing of molecular ions

Nathan L. Netzer, Indrek Must, Yupu Qiao, Shi-Li Zhang, Zhenqiang Wang and Zhen Zhang

Sci Rep, 2017, 7
DOI: 10.1038/srep45786

Biomedical Applications of Sulfonylcalix[4]arene-Based Metal–Organic Supercontainers

Ya-Wen Fan, Meng-Xue Shi, Zhenqiang Wang, Feng-Rong Dai and Zhong-Ning Chen

Molecules, 2024, 29, 1220
DOI: 10.3390/molecules29061220

Gas Storage in Porous Molecular Materials

Meaghan M. Deegan, Michael R. Dworzak, Aeri J. Gosselin, Kyle J. Korman and Eric D. Bloch

Chemistry A European J, 2021, 27, 4531
DOI: 10.1002/chem.202003864

Post-modified thiacalix[4]arene-based Ni16-NH2 cluster by ferrocene for synergistic photothermal conversion property

Dan Wang, Mengchun Zhu, Guiyan Zhao, Baokuan Chen and Yanfeng Bi

Inorganica Chimica Acta, 2023, 555, 121587
DOI: 10.1016/j.ica.2023.121587

Generalized Synthesis of Calixarene-Based High-Nuclearity M4n Nanocages (M = Ni or Co; n = 2–6)

Kongzhao Su, Feilong Jiang, Jinjie Qian, Yanli Gai, Mingyan Wu, Salem M. Bawaked, Mohamed Mokhtar, Shaeel A. AL-Thabaiti and Maochun Hong

Crystal Growth & Design, 2014, 14, 3116
DOI: 10.1021/cg5003836

Engineering solid-state porosity of synthetic supercontainers via modification of exo-cavities

Li-Ji Cheng, Xin-Xia Fan, Yi-Peng Li, Qiao-Hua Wei, Feng-Rong Dai, Zhong-Ning Chen and Zhenqiang Wang

Inorganic Chemistry Communications, 2017, 78, 61
DOI: 10.1016/j.inoche.2017.03.005

Permanently Microporous Metal–Organic Polyhedra

Aeri J. Gosselin, Casey A. Rowland and Eric D. Bloch

Chem. Rev., 2020, 120, 8987
DOI: 10.1021/acs.chemrev.9b00803

Assembly of Metal-Calixarene Compounds with a Ditetrazole Linker: From Isolated Cluster, Coordination Chain to Coordination Cage

Xiaofei Zhu, Shentang Wang, Haitao Han, Xinxin Hang, Wenbing Xie and Wuping Liao

Crystal Growth & Design, 2018, 18, 225
DOI: 10.1021/acs.cgd.7b01127

Triphenylamine-Functionalized Coordination Cage as a Supramolecular Fluorescence Sensor for Sequential Detection of Aluminum Ions and Nitrofurantoin

Tian-Pu Sheng, Cheng-Zhe Sun and Feng-Rong Dai

ACS Appl. Mater. Interfaces, 2023, 15, 29252
DOI: 10.1021/acsami.3c01422

Multiplexed analysis of molecular and elemental ions using nanowire transistor sensors

Xi Chen, Qitao Hu, Si Chen, Nathan L. Netzer, Zhenqiang Wang, Shi-Li Zhang and Zhen Zhang

Sensors and Actuators B: Chemical, 2018, 270, 89
DOI: 10.1016/j.snb.2018.05.018

A Calixarene‐based {Co9} Coordination Triangle as an Efficient Heterogenous Catalyst

Shentang Wang, Yanfeng Bi, Xinxin Hang, Xiaofei Zhu and Wuping Liao

Zeitschrift anorg allge chemie, 2017, 643, 160
DOI: 10.1002/zaac.201600409

Macrocyclic arene-based metal-organic cages

Yujuan Zhou, Jie Yang and Kecheng Jie

Coordination Chemistry Reviews, 2025, 539, 216726
DOI: 10.1016/j.ccr.2025.216726

pH‐Modulated Molecular Assemblies and Surface Properties of Metal–Organic Supercontainers at the Air–Water Interface

Nathan L. Netzer, Feng‐Rong Dai, Zhenqiang Wang and Chaoyang Jiang

Angewandte Chemie, 2014, 126, 11145
DOI: 10.1002/ange.201406733

Charge Manipulation of Porous Coordination Cages Tunes the Efficiency and Selectivity in Electrochemical Synthesis

Zhifang Su, Kang‐Kai Liu, Yu‐Qi Xu, Bing Yan, Shuangyin Wang, Zong‐Jie Guan, Yuqin Zou and Yu Fang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420945

A sulfonylcalix[4]arene-based metal–organic cage with octahedral porous structure for guest adsorption and separation

Cai-Xia Wang, Nian Si, Lei Wen, Hong-Yang Zan, Xiao-Xiao Wang and Wei-Long Shan

Inorganic Chemistry Communications, 2023, 153, 110874
DOI: 10.1016/j.inoche.2023.110874

Synthetic Supercontainers Exhibit Distinct Solution versus Solid State Guest-Binding Behavior

Feng-Rong Dai, Uma Sambasivam, Alex J. Hammerstrom and Zhenqiang Wang

J. Am. Chem. Soc., 2014, 136, 7480
DOI: 10.1021/ja502839b

Cooperative Binding and Stepwise Encapsulation of Drug Molecules by Sulfonylcalixarene-Based Metal-Organic Supercontainers

Tian-Pu Sheng, Xin-Xia Fan, Guo-Zong Zheng, Feng-Rong Dai and Zhong-Ning Chen

Molecules, 2020, 25, 2656
DOI: 10.3390/molecules25112656

1D morning glory-like calixarene-based coordination polymers as a support for Au/Ag nanoparticles

Shentang Wang, Xinxin Hang, Xiaofei Zhu, Haitao Han, Guoshuai Zhang and Wuping Liao

Polyhedron, 2017, 130, 75
DOI: 10.1016/j.poly.2017.03.062

pH‐Modulated Molecular Assemblies and Surface Properties of Metal–Organic Supercontainers at the Air–Water Interface

Nathan L. Netzer, Feng‐Rong Dai, Zhenqiang Wang and Chaoyang Jiang

Angew Chem Int Ed, 2014, 53, 10965
DOI: 10.1002/anie.201406733

Sulfonylcalixaren-Based ortho-Dicarboxylate-Bridged Coordination Containers for Guest Encapsulation and Separation

Cheng-Zhe Sun, Tian-Pu Sheng, Feng-Rong Dai and Zhong-Ning Chen

Crystal Growth & Design, 2019, 19, 1144
DOI: 10.1021/acs.cgd.8b01633

Thiacalix[4]arene macrocycles as versatile building blocks for the rational design of high-nuclearity metallic clusters, metallamacrocycles, porous coordination cages and containers

Ivan V. Khariushin, Véronique Bulach, Svetlana E. Solovieva, Igor S. Antipin, Alexander S. Ovsyannikov and Sylvie Ferlay

Coordination Chemistry Reviews, 2024, 513, 215846
DOI: 10.1016/j.ccr.2024.215846

Iodine Adsorption via Porous Molecular Solids Based on Coordination Containers Derived from Naphthalene-1,8-dicarboxylate

Jin-Yan Liu, Tian-Pu Sheng, Chang Li, Zhenqiang Wang, Feng-Rong Dai and Zhong-Ning Chen

Crystal Growth & Design, 2022, 22, 3182
DOI: 10.1021/acs.cgd.2c00039

Exo- and endo-cavities modulated coordination cages for consecutive supramolecular catalysis

Chang Li, Tian-Pu Sheng, Zhenqiang Wang and Feng-Rong Dai

Sci. China Chem., 2026, 69, 1840
DOI: 10.1007/s11426-025-3004-8

Decahexanuclear Zinc(II) Coordination Container Featuring a Flexible Tetracarboxylate Ligand: A Self-Assembly Supermolecule for Highly Efficient Drug Delivery of Anti-Inflammatory Agents

Can He, Xuzhuo Chen, Cheng-Zhe Sun, Li-Yi Zhang, Weifeng Xu, Shanyong Zhang, Zhenqiang Wang and Feng-Rong Dai

ACS Appl. Mater. Interfaces, 2021, 13, 33812
DOI: 10.1021/acsami.1c06311

Crystalline Assembly and Solvent‐induced Solid‐state Transformation of 1D Zigzag Chains Based on Sulfonylcalix[4]arene Trinuclear Co(II) and Zn(II) Clusters

Mariia V. Kniazeva, Alexander S. Ovsyannikov, Daut R. Islamov, Aida I. Samigullina, Aidar T. Gubaidullin, Pavel V. Dorovatovskii, Svetlana E. Solovieva, Igor S. Antipin and Sylvie Ferlay

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200464

Calix[4]arene type macrocyclic arene-containing metal-organic cages

Yujuan Zhou and Kecheng Jie

Sci. Sin.-Chim, 2023
DOI: 10.1360/SSC-2023-0168

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

Timothy R. Cook and Peter J. Stang

Chem. Rev., 2015, 115, 7001
DOI: 10.1021/cr5005666