Role of 2nd sphere H-bonding residues in tuning the kinetics of CO2 reduction to CO by iron porphyrin complexes

Pritha Sen, Biswajit Mondal, Dibyajyoti Saha, Atanu Rana and Abhishek Dey

Dalton Trans., 2019, 48, 5965
DOI: 10.1039/C8DT03850C

Structural and functional models in molybdenum and tungsten bioinorganic chemistry: description of selected model complexes, present scenario and possible future scopes

Amit Majumdar

Dalton Trans., 2014, 43, 8990
DOI: 10.1039/c4dt00631c

Rapid preparation of a Fe coordination structure adjustable ORR catalyst using microwaves with a half-wave potential above 0.9 V

Qingtao Wang, Xia Hu, Kai Cui, Yanxia Wu, Guofu Ma, Ziqiang Lei and Shufang Ren

Inorg. Chem. Front., 2024, 11, 5666
DOI: 10.1039/D4QI00952E

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2ndsphere interactions in catalysis

Sk Amanullah, Paramita Saha, Abhijit Nayek, Md Estak Ahmed and Abhishek Dey

Chem. Soc. Rev., 2021, 50, 3755
DOI: 10.1039/D0CS01405B

Highly exposed Fe–N4active sites in porous poly-iron-phthalocyanine based oxygen reduction electrocatalyst with ultrahigh performance for air cathode

Ganesan Anandhababu, Syed Comail Abbas, Jiangquan Lv, Kui Ding, Qin Liu, Dickson D. Babu, Yiyin Huang, Jiafang Xie, Maoxiang Wu and Yaobing Wang

Dalton Trans., 2017, 46, 1803
DOI: 10.1039/C6DT04705J

The ferrocene effect: enhanced electrocatalytic hydrogen production using meso-tetraferrocenyl porphyrin palladium(ii) and copper(ii) complexes

D. Sirbu, C. Turta, E. A. Gibson and A. C. Benniston

Dalton Trans., 2015, 44, 14646
DOI: 10.1039/C5DT02191J

Spectroscopic characterization of a phenolate bound FeII–O2adduct: gauging the relative “push” effect of a phenolate axial ligand

Pradip Kumar Das, Kaustuv Mittra and Abhishek Dey

Chem. Commun., 2014, 50, 5218
DOI: 10.1039/C3CC47528J

Recent developments in the synthesis of bio-inspired iron porphyrins for small molecule activation

Sk Amanullah, Paramita Saha and Abhishek Dey

Chem. Commun., 2022, 58, 5808
DOI: 10.1039/D2CC00430E

Mechanism of oxidative stress and neurotoxicity associated with heme and copper–Aβ relevant to Alzheimer's disease

Chinmay Dey, Madhuparna Roy, Puja Pal, Rimi Ghosh and Somdatta Ghosh Dey

Chem. Soc. Rev., 2025, 54, 9457
DOI: 10.1039/D5CS00544B

Effect of hydrogen bonding on innocent and non-innocent axial ligands bound to iron porphyrins

Asmita Singha, Kaustuv Mittra and Abhishek Dey

Dalton Trans., 2019, 48, 7179
DOI: 10.1039/C8DT03852J

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Zuozhong Liang, Hong-Yan Wang, Haoquan Zheng, Wei Zhang and Rui Cao

Chem. Soc. Rev., 2021, 50, 2540
DOI: 10.1039/D0CS01482F

Small-molecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies

Elodie Anxolabéhère-Mallart, Julien Bonin, Claire Fave and Marc Robert

Dalton Trans., 2019, 48, 5869
DOI: 10.1039/C9DT00136K

Tuning the thermodynamic onset potential of electrocatalytic O2reduction reaction by synthetic iron–porphyrin complexes

Sk Amanullah, Pradip Kumar Das, Subhra Samanta and Abhishek Dey

Chem. Commun., 2015, 51, 10010
DOI: 10.1039/C5CC01938A

Molecular engineering of metalloporphyrins and phthalocyanines for homogeneous and heterogeneous CO2 electroreduction

Aakash Santra, Arnab Ghatak, Zhiyuan Chen, Jing Shen, Joost Helsen, Yuvraj Birdja, Ally Aukauloo and Chanjuan Zhang

Chem. Sci., 2026
DOI: 10.1039/D5SC07983G

Analogues of oxy-heme Aβ: reactive intermediates relevant to Alzheimer's disease

Manas Seal, Soumya Mukherjee, Debajyoti Pramanik, Kaustuv Mittra, Abhishek Dey and Somdatta Ghosh Dey

Chem. Commun., 2013, 49, 1091
DOI: 10.1039/c2cc37626a

Ammonium tetrathiomolybdate as a novel electrode material for convenient tuning of the kinetics of electrochemical O2 reduction by using iron–porphyrin catalysts

Sudipta Chatterjee, Kushal Sengupta, Sabyasachi Bandyopadhyay and Abhishek Dey

J. Mater. Chem. A, 2016, 4, 6819
DOI: 10.1039/C5TA10544G

A biomimetic photoelectrocatalyst of Co–porphyrin combined with a g-C3N4 nanosheet based on π–π supramolecular interaction for high-efficiency CO2 reduction in water medium

Jibo Liu, Huijie Shi, Qi Shen, Chenyan Guo and Guohua Zhao

Green Chem., 2017, 19, 5900
DOI: 10.1039/C7GC02657A

Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water

Benjamin D. Matson, Colin T. Carver, Amber Von Ruden, Jenny Y. Yang, Simone Raugei and James M. Mayer

Chem. Commun., 2012, 48, 11100
DOI: 10.1039/c2cc35576k

A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

Kaustuv Mittra, Sudipta Chatterjee, Subhra Samanta, Kushal Sengupta, Hridaynath Bhattacharjee and Abhishek Dey

Chem. Commun., 2012, 48, 10535
DOI: 10.1039/c2cc35162e

Nature-inspired electrocatalysts and devices for energy conversion

Panagiotis Trogadas and Marc-Olivier Coppens

Chem. Soc. Rev., 2020, 49, 3107
DOI: 10.1039/C8CS00797G

Functional adlayers on Au electrodes: some recent applications in hydrogen evolution and oxygen reduction

Samir Chattopadhyay, Ankita Sarkar, Sudipta Chatterjee and Abhishek Dey

J. Mater. Chem. A, 2018, 6, 1323
DOI: 10.1039/C7TA09179F

Influence of the distal guanidine group on the rate and selectivity of O2 reduction by iron porphyrin

Arnab Ghatak, Snehadri Bhakta, Sarmistha Bhunia and Abhishek Dey

Chem. Sci., 2019, 10, 9692
DOI: 10.1039/C9SC02711D

Iron porphyrins with a hydrogen bonding cavity: effect of weak interactions on their electronic structure and reactivity

Kaustuv Mittra, Asmita Singha and Abhishek Dey

Dalton Trans., 2016, 45, 18796
DOI: 10.1039/C6DT03597C

Enhanced Molecular CO2 Electroreduction Enabled by a Flexible Hydrophilic Channel for Relay Proton Shuttling

Caroline K. Williams, Amir Lashgari, Jingchao Chai and Jianbing “Jimmy” Jiang

ChemSusChem, 2020, 13, 3412
DOI: 10.1002/cssc.202001037

Bioinorganic Chemistry on Electrodes: Methods to Functional Modeling

Abhijit Nayek, Md Estak Ahmed, Soumya Samanta, Souvik Dinda, Suman Patra, Somdatta Ghosh Dey and Abhishek Dey

J. Am. Chem. Soc., 2022, 144, 8402
DOI: 10.1021/jacs.2c01842

Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction

Yuanyuan Jiang, Yizhong Lu, Xiangyu Lv, Dongxue Han, Qixian Zhang, Li Niu and Wei Chen

ACS Catal., 2013, 3, 1263
DOI: 10.1021/cs4001927

H2O2 Synthesis with Molecular Electrocatalysts Enables Substantial Current Densities in a Flow Cell Using Gas Diffusion Electrodes

Phebe H. van Langevelde, Nathalie E. G. Ligthart, Pim G. J. van Duren, David A. Vermaas and Dennis G. H. Hetterscheid

ACS Electrochem., 2025, 1, 2326
DOI: 10.1021/acselectrochem.5c00179

Proton reduction in the presence of oxygen by iron porphyrin enabled with 2nd sphere redox active ferrocenes

Biswajit Mondal, Pritha Sen and Abhishek Dey

Chinese Journal of Catalysis, 2021, 42, 1327
DOI: 10.1016/S1872-2067(20)63761-5

Induction of Enzyme-like Peroxidase Activity in an Iron Porphyrin Complex Using Second Sphere Interactions

Snehadri Bhakta, Abhijit Nayek, Bijan Roy and Abhishek Dey

Inorg. Chem., 2019, 58, 2954
DOI: 10.1021/acs.inorgchem.8b02707

Direct observation of intermediates formed during steady-state electrocatalytic O 2 reduction by iron porphyrins

Kushal Sengupta, Sudipta Chatterjee, Subhra Samanta and Abhishek Dey

Proc. Natl. Acad. Sci. U.S.A., 2013, 110, 8431
DOI: 10.1073/pnas.1300808110

Electrocatalytic oxygen reduction reaction with metalloporphyrins

Tao Liu, Qingxin Zhang, Hongbo Guo, Zuozhong Liang and Rui Cao

Sci. Sin.-Chim, 2022, 52, 1306
DOI: 10.1360/SSC-2022-0056

Homogeneous Electrocatalytic CO2Reduction Using a Porphyrin Complex with Flexible Triazole Units in the Second Coordination Sphere

Nilakshi Devi, Caroline K. Williams, Ashwin Chaturvedi and Jianbing “Jimmy” Jiang

ACS Appl. Energy Mater., 2021, 4, 3604
DOI: 10.1021/acsaem.1c00027

A Minimalist Iron Porphyrin Which Can Catalyze Both Peroxidation and Oxygen Reduction Reaction

Souvik Dinda, Triparna Roy, Srijan Sengupta, Pritam Baidya and Abhishek Dey

JACS Au, 2025, 5, 6275
DOI: 10.1021/jacsau.5c01252

New developments in chemistry of organometallic porphyrins and their analogs

Andrea Vecchi, Pierluca Galloni, Barbara Floris and Victor N. Nemykin

J. Porphyrins Phthalocyanines, 2013, 17, 165
DOI: 10.1142/S1088424613300012

Second-Sphere Hydrogen-Bond Donors and Acceptors Affect the Rate and Selectivity of Electrochemical Oxygen Reduction by Iron Porphyrins Differently

Arnab Ghatak, Soumya Samanta, Abhijit Nayek, Sudipta Mukherjee, Somdatta Ghosh Dey and Abhishek Dey

Inorg. Chem., 2022, 61, 12931
DOI: 10.1021/acs.inorgchem.2c02170

Acid-Induced Mechanism Change and Overpotential Decrease in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex

Dipanwita Das, Yong-Min Lee, Kei Ohkubo, Wonwoo Nam, Kenneth D. Karlin and Shunichi Fukuzumi

J. Am. Chem. Soc., 2013, 135, 4018
DOI: 10.1021/ja312256u

The secondary coordination sphere and axial ligand effects on oxygen reduction reaction by iron porphyrins: a DFT computational study

Takehiro Ohta, Perumandla Nagaraju, Jin-Gang Liu, Takashi Ogura and Yoshinori Naruta

J Biol Inorg Chem, 2016, 21, 745
DOI: 10.1007/s00775-016-1380-9

Fabrication of 1D long chain-like metal porphyrin-based coordination complexes for high-efficiency hydrogen evolution and photoelectric response

Xiaohan Li, Yanzhi Zhang, Weixuan Wang, Junjing Meng, Kuang Li, Wenxin Lin, Zhiqin Peng, Junmin Wan and Zhiwen Hu

International Journal of Hydrogen Energy, 2019, 44, 18072
DOI: 10.1016/j.ijhydene.2019.05.059

Rational Design of Mononuclear Iron Porphyrins for Facile and Selective 4e–/4H+ O2 Reduction: Activation of O–O Bond by 2nd Sphere Hydrogen Bonding

Sarmistha Bhunia, Atanu Rana, Pronay Roy, Daniel J. Martin, Michael L. Pegis, Bijan Roy and Abhishek Dey

J. Am. Chem. Soc., 2018, 140, 9444
DOI: 10.1021/jacs.8b02983

Wei Zhang, Wenzhen Lai and Rui Cao

Chem. Rev., 2017, 117, 3717
DOI: 10.1021/acs.chemrev.6b00299

Characteristic Electronic Perturbation by Asymmetric Arrangements of p-Aminophenyl Substituents in Free-Base Porphyrins

Sung Cho, Yunhui Lee, Hyoung Soon Han, Hyo Kyoung Lee and Seungwon Jeon

J. Phys. Chem. A, 2014, 118, 4995
DOI: 10.1021/jp505072x

Reduction of CO2 to CO by an Iron Porphyrin Catalyst in the Presence of Oxygen

Biswajit Mondal, Pritha Sen, Atanu Rana, Dibyajyoti Saha, Purusottom Das and Abhishek Dey

ACS Catal., 2019, 9, 3895
DOI: 10.1021/acscatal.9b00529

Four-Electron Electrocatalytic O2 Reduction by a Ferrocene-Modified Glutathione Complex of Cu

Profulla Mondol and Christopher J. Barile

ACS Appl. Energy Mater., 2021, 4, 9611
DOI: 10.1021/acsaem.1c01753

Silver nanostructure-modified graphite electrode for in-operando SERRS investigation of iron porphyrins during high-potential electrocatalysis

Samir Chattopadhyay, Soumya Samanta, Ankita Sarkar, Aishik Bhattacharya, Suman Patra and Abhishek Dey

The Journal of Chemical Physics, 2023, 158
DOI: 10.1063/5.0136333

Amine Groups in the Second Sphere of Iron Porphyrins Allow for Higher and Selective 4e–/4H+ Oxygen Reduction Rates at Lower Overpotentials

Sarmistha Bhunia, Arnab Ghatak, Atanu Rana and Abhishek Dey

J. Am. Chem. Soc., 2023, 145, 3812
DOI: 10.1021/jacs.2c13552

Breaking the Linear Scaling Relations for the Oxygen Reduction Reaction with a Dual‐Atom Catalyst Composed of a MnFe‐Porphyrrole Aerogel

Eliana Lebowitz, Prasenjit Das, Łukasz Kielesiński, Leigh Peles‐Strahl, David A. Cullen, Ilya Grinberg, Daniel T. Gryko and Lior Elbaz

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202514013

Recent Progress in Surface and Interface Engineering for Electrocatalytic CO2 Reduction

Xiaokang Hu, Jiuyi Hu, Shaohui Zheng, Yun Fan, Hongfeng Li, Suoying Zhang, Wenjing Liu, Baoli Zha, Fengwei Huo and Faisal Saleem

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200990

Synthesis and Functionalization of Porphyrins through Organometallic Methodologies

Satoru Hiroto, Yoshihiro Miyake and Hiroshi Shinokubo

Chem. Rev., 2017, 117, 2910
DOI: 10.1021/acs.chemrev.6b00427

Pyrolysis of a flash nanoprecipitated tannic acid–metal@polymer assembly to create an electrochemically active metal@nanocarbon catalyst

Jianhong Wang, Zhijie Zhang, Jing Zhao and Rui Liu

Polym J, 2020, 52, 539
DOI: 10.1038/s41428-020-0305-1

Electrocatalytic O2 Reduction Reaction by Synthetic Analogues of Cytochrome P450 and Myoglobin: In-Situ Resonance Raman and Dynamic Electrochemistry Investigations

Sudipta Chatterjee, Kushal Sengupta, Subhra Samanta, Pradip Kumar Das and Abhishek Dey

Inorg. Chem., 2013, 52, 9897
DOI: 10.1021/ic401022z

A Superior Oxygen Reduction Reaction Electrocatalyst Based on Reduced Graphene Oxide and Iron(II) Phthalocyanine-Supported Sub-2 nm Platinum Nanoparticles

Shuo Wang, Fan Li, Yan Wang, Dan Qiao, Chunwen Sun and Jingbo Liu

ACS Appl. Nano Mater., 2018, 1, 711
DOI: 10.1021/acsanm.7b00173

Effect of Axial Ligand, Spin State, and Hydrogen Bonding on the Inner-Sphere Reorganization Energies of Functional Models of Cytochrome P450

Sabyasachi Bandyopadhyay, Atanu Rana, Kaustuv Mittra, Subhra Samanta, Kushal Sengupta and Abhishek Dey

Inorg. Chem., 2014, 53, 10150
DOI: 10.1021/ic501112a

Tailor made iron porphyrins for investigating axial ligand and distal environment contributions to electronic structure and reactivity

Sk Amanullah, Asmita Singha and Abhishek Dey

Coordination Chemistry Reviews, 2019, 386, 183
DOI: 10.1016/j.ccr.2019.01.021

Molecular Catalysis of O2 Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways

Cyrille Costentin, Hachem Dridi and Jean-Michel Savéant

J. Am. Chem. Soc., 2015, 137, 13535
DOI: 10.1021/jacs.5b06834

Intermediates Involved in the 2e–/2H+ Reduction of CO2 to CO by Iron(0) Porphyrin

Biswajit Mondal, Atanu Rana, Pritha Sen and Abhishek Dey

J. Am. Chem. Soc., 2015, 137, 11214
DOI: 10.1021/jacs.5b05992

Catalytic H2O2 Disproportionation and Electrocatalytic O2 Reduction by a Functional Mimic of Heme Catalase: Direct Observation of Compound 0 and Compound I in Situ

Kushal Sengupta, Sudipta Chatterjee and Abhishek Dey

ACS Catal., 2016, 6, 1382
DOI: 10.1021/acscatal.5b02668

Photophysical and ligand binding studies of metalloporphyrins bearing hydrophilic distal superstructure

Sudipta Chatterjee, Kushal Sengupta, Sohini Bhattacharyya, Amrit Nandi, Subhra Samanta, Kaustuv Mittra and Abhishek Dey

J. Porphyrins Phthalocyanines, 2013, 17, 210
DOI: 10.1142/S1088424613500119

Effect of axial ligands on electronic structure andO2reduction by iron porphyrin complexes: Towards a quantitative understanding of the "push effect"

Subhra Samanta, Pradip Kumar Das, Sudipta Chatterjee and Abhishek Dey

J. Porphyrins Phthalocyanines, 2015, 19, 92
DOI: 10.1142/S1088424615300049

Synthesis of a Novel Zinc(II) Porphyrin Complex, Halide Ion Reception, Catalytic Degradation of Dyes, and Optoelectronic Application

Soumaya Nasri, Mouhieddinne Guergueb, Jihed Brahmi, Youssef O. Al-Ghamdi, Frédérique Loiseau and Habib Nasri

Crystals, 2023, 13, 238
DOI: 10.3390/cryst13020238

Breaking the Linear Scaling Relations for the Oxygen Reduction Reaction with a Dual‐Atom Catalyst Composed of a MnFe‐Porphyrrole Aerogel

Eliana Lebowitz, Prasenjit Das, Łukasz Kielesiński, Leigh Peles‐Strahl, David A. Cullen, Ilya Grinberg, Daniel T. Gryko and Lior Elbaz

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202514013

Selectivity in Electrochemical CO2 Reduction

Paramita Saha, Sk Amanullah and Abhishek Dey

Acc. Chem. Res., 2022, 55, 134
DOI: 10.1021/acs.accounts.1c00678

N- and S-doped nanoporous carbon framework derived from conjugated microporous polymers incorporation with ionic liquids for efficient oxygen reduction reaction

Rui Jiao, Wanli Zhang, Hanxue Sun, Zhaoqi Zhu, Zifeng Yang, Weidong Liang and An Li

Materials Today Energy, 2020, 16, 100382
DOI: 10.1016/j.mtener.2020.100382

Second Sphere Control of Redox Catalysis: Selective Reduction of O2 to O2– or H2O by an Iron Porphyrin Catalyst

Subhra Samanta, Kaustuv Mittra, Kushal Sengupta, Sudipta Chatterjee and Abhishek Dey

Inorg. Chem., 2013, 52, 1443
DOI: 10.1021/ic3021782

Second Sphere Effects on Oxygen Reduction and Peroxide Activation by Mononuclear Iron Porphyrins and Related Systems

Sarmistha Bhunia, Arnab Ghatak and Abhishek Dey

Chem. Rev., 2022, 122, 12370
DOI: 10.1021/acs.chemrev.1c01021

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e–/4H+ O2-Reduction

Sudipta Chatterjee, Kushal Sengupta, Shabnam Hematian, Kenneth D. Karlin and Abhishek Dey

J. Am. Chem. Soc., 2015, 137, 12897
DOI: 10.1021/jacs.5b06513

Resonance Raman and Electrocatalytic Behavior of Thiolate and Imidazole Bound Iron Porphyrin Complexes on Self Assembled Monolayers: Functional Modeling of Cytochrome P450

Kushal Sengupta, Sudipta Chatterjee, Subhra Samanta, Sabyasachi Bandyopadhyay and Abhishek Dey

Inorg. Chem., 2013, 52, 2000
DOI: 10.1021/ic302369v

Attaching Cobalt Corroles onto Carbon Nanotubes: Verification of Four-Electron Oxygen Reduction by Mononuclear Cobalt Complexes with Significantly Improved Efficiency

Jia Meng, Haitao Lei, Xialiang Li, Jing Qi, Wei Zhang and Rui Cao

ACS Catal., 2019, 9, 4551
DOI: 10.1021/acscatal.9b00213

Concerted Proton–Electron Transfer in Electrocatalytic O2 Reduction by Iron Porphyrin Complexes: Axial Ligands Tuning H/D Isotope Effect

Sudipta Chatterjee, Kushal Sengupta, Subhra Samanta, Pradip Kumar Das and Abhishek Dey

Inorg. Chem., 2015, 54, 2383
DOI: 10.1021/ic5029959

Synthetic heme dioxygen adducts: electronic structure and reactivity

Asmita Singha, Kaustuv Mittra and Abhishek Dey

Trends in Chemistry, 2022, 4, 15
DOI: 10.1016/j.trechm.2021.10.008

Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode

Zaki N. Zahran, Eman A. Mohamed, Ashraf Abdel Haleem and Yoshinori Naruta

Chemistry A European J, 2018, 24, 10606
DOI: 10.1002/chem.201704143

A Single Iron Porphyrin Shows pH Dependent Switch between “Push” and “Pull” Effects in Electrochemical Oxygen Reduction

Sudipta Mukherjee, Abhijit Nayek, Sarmistha Bhunia, Somdatta Ghosh Dey and Abhishek Dey

Inorg. Chem., 2020, 59, 14564
DOI: 10.1021/acs.inorgchem.0c02408

Effect of Pendant Distal Residues on the Rate and Selectivity of Electrochemical Oxygen Reduction Reaction Catalyzed by Iron Porphyrin Complexes

Arnab Ghatak, Sarmistha Bhunia and Abhishek Dey

ACS Catal., 2020, 10, 13136
DOI: 10.1021/acscatal.0c02836

Iron (II) phthalocyanine nanoclusters - Graphene sandwich composite for oxygen reduction reaction catalysts

Yan Zhang, Haikun Wu, Wen Zhao, Xiaomin Li, Rui Yin, Lei Qian, Yuanyuan Qi and Kaijing Yang

Materials & Design, 2017, 130, 366
DOI: 10.1016/j.matdes.2017.05.074

Molecular electrocatalysts for the oxygen reduction reaction

Subal Dey, Biswajit Mondal, Sudipta Chatterjee, Atanu Rana, Sk Amanullah and Abhishek Dey

Nat Rev Chem, 2017, 1
DOI: 10.1038/s41570-017-0098

Mn/Cu nanoclusters-grafted N-doped carbon nanotubes: Robust oxygen electrode catalysts for Zn-air batteries

Li Wang, Lili Cui, Xin Ge, Nailin Yue, Xingquan He, Wei Zhang and Tewodros Asefa

International Journal of Hydrogen Energy, 2020, 45, 27230
DOI: 10.1016/j.ijhydene.2020.07.083

Enzyme-inspired molecular electrocatalysts for the oxygen reduction reaction

Jinghui Zhao, Yongmeng Wu, Cuibo Liu, Bin Zhang and Ying Gao

Electrochimica Acta, 2024, 479, 143891
DOI: 10.1016/j.electacta.2024.143891

Metallocenes meet porphyrinoids: Consequences of a “fusion”

Andrea Vecchi, Pierluca Galloni, Barbara Floris, Semyon V. Dudkin and Victor N. Nemykin

Coordination Chemistry Reviews, 2015, 291, 95
DOI: 10.1016/j.ccr.2015.02.005

Electrocatalytic oxygen reduction on metalloporphyrins. Second coordination sphere substituents on the ligand: Electronic and steric effects through pocket and extended structures and their effect on the electrocatalytic activity

Carlos P. Silva, Carolina P. Candia, Mauricio Paredes, Elizabeth Imbarack, Fabian Martínez-Gómez, Camila F. Olguín, Geraldine Jara, José H. Zagal, Jorge Pavez and Nicolás Agurto

Journal of Catalysis, 2024, 430, 115365
DOI: 10.1016/j.jcat.2024.115365

Functionalization of A3B-type porphyrin with Fe3O4 MNPs. Supramolecular assemblies, gas sensor and catalytic applications

Carmen A. Mak, Miquel A. Pericas and Eugenia Fagadar-Cosma

Catalysis Today, 2018, 306, 268
DOI: 10.1016/j.cattod.2017.01.014

Redox Mediators in Homogeneous Co-electrocatalysis

Amelia G. Reid and Charles W. Machan

J. Am. Chem. Soc., 2023, 145, 2013
DOI: 10.1021/jacs.2c10033

Density Functional Theory Study of Iron Phthalocyanine Porous Layer Deposited on Graphene Substrate: A Pt-Free Electrocatalyst for Hydrogen Fuel Cells

Sean Mussell and Pabitra Choudhury

J. Phys. Chem. C, 2016, 120, 5384
DOI: 10.1021/acs.jpcc.5b10327

Organic hybrid of cobalt phthalocyanine embedded graphene as an efficient catalyst for oxygen reduction reaction

Shambhulinga Aralekallu, Sowmyashree Hadimane, Shantharaja, Manjunatha Nemakal and Lokesh Koodlur Sannegowda

Fuel, 2024, 361, 130736
DOI: 10.1016/j.fuel.2023.130736

“Click”-reaction: An alternative tool for new architectures of porphyrin based derivatives

Kalliopi Ladomenou, Vasilis Nikolaou, Georgios Charalambidis and Athanassios G. Coutsolelos

Coordination Chemistry Reviews, 2016, 306, 1
DOI: 10.1016/j.ccr.2015.06.002

In Situ Mechanistic Investigation of O2 Reduction by Iron Porphyrin Electrocatalysts Using Surface-Enhanced Resonance Raman Spectroscopy Coupled to Rotating Disk Electrode (SERRS-RDE) Setup

Kushal Sengupta, Sudipta Chatterjee and Abhishek Dey

ACS Catal., 2016, 6, 6838
DOI: 10.1021/acscatal.6b01122

Atropisomeric Effects of Second Coordination Spheres on Electrocatalytic CO2 Reduction

Caroline K. Williams, Amir Lashgari, Jenny A. Tomb, Jingchao Chai and Jianbing Jimmy Jiang

ChemCatChem, 2020, 12, 4886
DOI: 10.1002/cctc.202000909

Noble-Metal-Free Fe–N/C Catalyst for Highly Efficient Oxygen Reduction Reaction under Both Alkaline and Acidic Conditions

Ling Lin, Qing Zhu and An-Wu Xu

J. Am. Chem. Soc., 2014, 136, 11027
DOI: 10.1021/ja504696r

Cobalt‐Porphyrin‐Catalyzed Oxygen Reduction Reaction: A Scanning Tunneling Microscopy Study

Zhen‐Feng Cai, Xiang Wang, Dong Wang and Li‐Jun Wan

ChemElectroChem, 2016, 3, 2048
DOI: 10.1002/celc.201600435

Recent advances in Porphyrin-based metal organic frameworks and composites for photocatalytic hydrogen evolution and water treatment

Garima Rana, Pooja Dhiman, Amit Kumar, Tongtong Wang and Gaurav Sharma

Chemical Engineering Research and Design, 2023, 199, 620
DOI: 10.1016/j.cherd.2023.10.008

Second sphere control of spin state: Differential tuning of axial ligand bonds in ferric porphyrin complexes by hydrogen bonding

Kaustuv Mittra, Kushal Sengupta, Asmita Singha, Sabyasachi Bandyopadhyay, Sudipta Chatterjee, Atanu Rana, Subhra Samanta and Abhishek Dey

Journal of Inorganic Biochemistry, 2016, 155, 82
DOI: 10.1016/j.jinorgbio.2015.11.013

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Yuliang Li, Ni Wang, Haitao Lei, Xialiang Li, Haoquan Zheng, Hongyan Wang, Wei Zhang and Rui Cao

Coordination Chemistry Reviews, 2021, 442, 213996
DOI: 10.1016/j.ccr.2021.213996

Selective 4e–/4H+ O2 Reduction by an Iron(tetraferrocenyl)Porphyrin Complex: From Proton Transfer Followed by Electron Transfer in Organic Solvent to Proton Coupled Electron Transfer in Aqueous Medium

Kaustuv Mittra, Sudipta Chatterjee, Subhra Samanta and Abhishek Dey

Inorg. Chem., 2013, 52, 14317
DOI: 10.1021/ic402297f

Effect of Support on Oxygen Reduction Reaction Activity of Supported Iron Porphyrins

Qi Hua, Kenneth E. Madsen, Anne Marie Esposito, Xinyi Chen, Toby J. Woods, Richard T. Haasch, Shuting Xiang, Anatoly I. Frenkel, Timothy T. Fister and Andrew A. Gewirth

ACS Catal., 2022, 12, 1139
DOI: 10.1021/acscatal.1c04871

Proton Relay Effects on Oxygen Reduction Reaction Catalyzed by Dinuclear Cobalt Polypyridyl Complexes with OH Groups on Bipyridine Ligands

Hiroaki Arima, Takashi Nakazono and Tohru Wada

Bulletin of the Chemical Society of Japan, 2022, 95, 1100
DOI: 10.1246/bcsj.20220104

Synergistic Catalytic Effect of MoS2 Nanoparticles Supported on Gold Nanoparticle Films for a Highly Efficient Oxygen Reduction Reaction

Tanyuan Wang, Junqiao Zhuo, Ye Chen, Kuangzhou Du, Pagona Papakonstantinou, Zhiwei Zhu, Yuanhua Shao and Meixian Li

ChemCatChem, 2014, 6, 1877
DOI: 10.1002/cctc.201402038

Hydrodechlorination of Dichloromethane by a Metal‐Free Triazole‐Porphyrin Electrocatalyst: Demonstration of Main‐Group Element Electrocatalysis**

Caroline K. Williams, Amir Lashgari, Nilakshi Devi, Marcus Ang, Ashwin Chaturvedi, Pranita Dhungana and Jianbing Jimmy Jiang

Chemistry A European J, 2021, 27, 6240
DOI: 10.1002/chem.202005012

Rejigging Electron and Proton Transfer to Transition between Dioxygenase, Monooxygenase, Peroxygenase, and Oxygen Reduction Activity: Insights from Bioinspired Constructs of Heme Enzymes

Manjistha Mukherjee and Abhishek Dey

JACS Au, 2021, 1, 1296
DOI: 10.1021/jacsau.1c00100

Factors Determining the Rate and Selectivity of 4e–/4H+ Electrocatalytic Reduction of Dioxygen by Iron Porphyrin Complexes

Sudipta Chatterjee, Kushal Sengupta, Biswajit Mondal, Subal Dey and Abhishek Dey

Acc. Chem. Res., 2017, 50, 1744
DOI: 10.1021/acs.accounts.7b00192

A Cheap Polypyrrole-Derived Fe-N-C Electrocatalyst with Ultrahigh Oxygen Reduction Activity in Alkaline Electrolyte

Yao Liug, Xiaojing Liug, Junli Liu, Chaozhong Guo, Yanrong Li, Jin Zhang and Zhongbin Li

International Journal of Electrochemical Science, 2019, 14, 5820
DOI: 10.20964/2019.06.76

Mechanism of Reduction of Ferric Porphyrins by Sulfide: Identification of a Low Spin FeIII–SH Intermediate

Kaustuv Mittra, Asmita Singha and Abhishek Dey

Inorg. Chem., 2017, 56, 3916
DOI: 10.1021/acs.inorgchem.6b02878

Enhanced Electrocatalytic Activity of a Zinc Porphyrin for CO2 Reduction: Cooperative Effects of Triazole Units in the Second Coordination Sphere

Amir Lashgari, Caroline K. Williams, Jenna L. Glover, Yueshen Wu, Jingchao Chai and Jianbing “Jimmy” Jiang

Chemistry A European J, 2020, 26, 16774
DOI: 10.1002/chem.202002813

Hydrothermal synthesis of Fe 2 O 3 /polypyrrole/graphene oxide composites as highly efficient electrocatalysts for oxygen reduction reaction in alkaline electrolyte

Suzhen Ren, Shaobo Ma, Ying Yang, Qing Mao and Ce Hao

Electrochimica Acta, 2015, 178, 179
DOI: 10.1016/j.electacta.2015.07.181

Activating Fe(I) Porphyrins for the Hydrogen Evolution Reaction Using Second-Sphere Proton Transfer Residues

Atanu Rana, Biswajit Mondal, Pritha Sen, Subal Dey and Abhishek Dey

Inorg. Chem., 2017, 56, 1783
DOI: 10.1021/acs.inorgchem.6b01707

In-situ ECSTM investigation of H2O2 production in cobalt—porphyrin-catalyzed oxygen reduction reaction

Ya-Chen Feng, Xiang Wang, Zhen-Yu Yi, Yu-Qi Wang, Hui-Juan Yan and Dong Wang

Sci. China Chem., 2023, 66, 273
DOI: 10.1007/s11426-022-1465-8

Artificial Peroxidase Based on the Biotin–Streptavidin Technology that Rivals the Efficiency of Natural Peroxidases

Manjistha Mukherjee, Valerie Waser, Elinor F. Morris, Nico V. Igareta, Alec H. Follmer, Roman P. Jakob, Dilbirin Üzümcü, Timm Maier and Thomas R. Ward

ACS Catal., 2024, 14, 16266
DOI: 10.1021/acscatal.4c03208

A Supramolecular Porous Organic Cage Platform Promotes Electrochemical Hydrogen Evolution from Water Catalyzed by Cobalt Porphyrins

Peter T. Smith, Bahiru Punja Benke, Lun An, Younghoon Kim, Kimoon Kim and Christopher J. Chang

ChemElectroChem, 2021, 8, 1653
DOI: 10.1002/celc.202100331