Issue 3, 2012
From the journal:

Chemical Communications

Highly enantioselective Friedel–Crafts alkylation reaction catalyzed by rosin-derived tertiary amine–thiourea: synthesis of modified chromanes with anticancer potency†‡

Xianxing Jiang,§ab   Lipeng Wu,§b   Yanhong Xing,§b   Long Wang,b   Shoulei Wang,b   Zongyao Chenb  and  Rui Wang*ab  

* Corresponding authors

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
E-mail: wangrui@lzu.edu.cn

b Key Laboratory of Preclinical Study for New Drugs of Gansu Province, State Key Laboratory of Applied Organic Chemistry, Institute of Biochemistry and Molecular Biology, Lanzhou University, Lanzhou 730000, China
E-mail: wangrui@lzu.edu.cn
Fax: (86)-931-8911255

Abstract

We present herein for the first time the synthesis and preliminary biological evaluation of various modified chromanesvia a rosin-derived tertiary amine–thiourea-catalyzed highly enantioselective Friedel–Crafts alkylation reaction.

Graphical abstract: Highly enantioselective Friedel–Crafts alkylation reaction catalyzed by rosin-derived tertiary amine–thiourea: synthesis of modified chromanes with anticancer potency

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Article information

DOI
https://doi.org/10.1039/C1CC14379D
Article type
Communication
Submitted
20 Jul 2011
Accepted
01 Nov 2011
First published
14 Nov 2011

Chem. Commun., 2012,48, 446-448

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Highly enantioselective Friedel–Crafts alkylation reaction catalyzed by rosin-derived tertiary amine–thiourea: synthesis of modified chromanes with anticancer potency

X. Jiang, L. Wu, Y. Xing, L. Wang, S. Wang, Z. Chen and R. Wang, Chem. Commun., 2012, 48, 446 DOI: 10.1039/C1CC14379D

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