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DOI: 10.1039/A802844C (Paper) Reference Section for: Chem. Commun., 1998, 1513-1514

Rare M7O2 double tetrahedral core in molecular species: preparation, structure and properties of [Zn7O2(O2CMe)10(1-Meim)2] (1-Meim = 1-methylimidazole)

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Nikolia Lalioti, Spyros P. Perlepes, Evy Manessi-Zoupa, Catherine P. Raptopoulou, Aris Terzis, Abil E. Aliev and Ioannis P. Gerothanassis

Abstract

The 2:1 reaction between Zn(O2CMe)2·2H2O and 1-Meim in refluxing MeCN gives [Zn7O2(O2CMe)10(1-Meim)2] 1 which comprises two vertex-sharing tetranuclear Zn4(µ4-O)(η1: η1:µ2-O2CMe)5(1-Meim) units; solid-state 13C and 15N NMR spectra reveal structural details of the complex.

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