An operationally practical visible-light-driven heptafluoroisopropylation of diverse anilines and heterocyclic aromatics with the readily accessible heptafluoroisopropyl iodide (iC3F7-I) by an electron-donor–acceptor (EDA) strategy is presented.
PFAS degradation in a plasma is modeled by combining calculations of electron impact excitation cross sections and molecular decomposition pathways in a 0-dimensional plasma chemistry model.
A facile preparation of deprotonizable calix[4]crowns with enhanced properties to stably coordinate Ba2+ and Ra2+ inclusive radiolabeling is described. Binding properties of these ions were investigated by DFT calculations to support the findings.
A simple activation of perfluoroalkyl iodides by tBuONa or KOH allows the promotion of α-sp3 C–H amidation reactions of alkyl ethers and benzylic hydrocarbons, C–H iodination of heteroaryl compounds, and perfluoroalkylations of electron-rich π bonds.
In current research, two functional components, i.e., hydrazone and bisphenol sulfide were combined to get useful supramolecules in medicinal chemistry.