A Rh(III) catalyzed perimidine directed C–H activation strategy to achieve [4 + 1] and [4 + 2] annulations with two distinct classes of alkenes for the synthesis of perimidine-linked spiro-succinimides and isoquinolines has been developed.
A sustainable dehydrogenative approach for synthesizing perimidine derivatives has been established, employing a phosphine-free cobalt complex.
The synthesis of single phase δ-MnO2 NPs was carried out utilising an environmentally benign biogenic method. The prepared catalyst was utilized for benzimidazoles and dihydroperimidines synthesis and the dye removal study with exceptional catalytic activity.
A newly synthesized Hg(II)–perimidine-2-thione complex catalyzes the Beckmann rearrangement across a broad range of oximes, enabling high-yield access to amides and lactams.
This comprehensive review delves into the intricate world of triazines, including their structures and the chemical diversity of their isomers.