A catalyst-free protocol for the reductive desulfurization of thioamides using ammonia borane (AB) has been successfully developed.
Hydroxylamine hydrochloride-catalyzed transamidation of primary thioamides with primary and secondary amines via C(S)–N bond cleavage and formation has been reported.
A sugar-based surfactant AGA8 was designed and demonstrated to promote the synthesis of disulfides and thioamides in water.
The IGM can isolate the n → π* interaction in δg isosurfaces. The interaction is identified as a green flat disc in the middle of the interaction zone. However, is not able to reproduce the trends in the relative force found in NBO results.
A new method for chemoselective transition-metal-free acylation of thioamides with ketones by N–C(S) bond cleavage is reported.