Photoelectrochemical iron–cobalt synergistic catalysis for C(sp3)–H alkenylation

Jia-Lin Tu, Ao-Men Hu, Chao Yang, Lin Guo and Wujiong Xia

Org. Chem. Front., 2025, 12, 2732
DOI: 10.1039/D5QO00017C

Photo- and electro-chemical synthesis of substituted pyrroles

Binbin Huang

Green Chem., 2024, 26, 11773
DOI: 10.1039/D4GC04495A

Visible-light induced direct C(sp3)–H bond disulfidation of saturated N-heterocycles through a hydrogen atom transfer (HAT) process

Junlei Wang, Guocheng Gao, Chengcheng Shi, Han Gao, Ji Luo, Guofen Wei, Daohai Zhang, Hongqing Li, Tonghao Yang and Binbin Huang

Org. Chem. Front., 2025, 12, 2286
DOI: 10.1039/D4QO02384F

Synthetic versatility: the C–P bond odyssey

Peng Zhang, Yinan Wang, Zixin Deng and Jiangtao Gao

Org. Biomol. Chem., 2025, 23, 546
DOI: 10.1039/D4OB01461H

Visible-light-induced 1,3-difunctionalization of allylboronic esters enabled by a 1,2-boron shift

Panjie Xiang, Kai Sun, Anzai Shi, Jiangzhen An, Xiaolan Chen, Lingbo Qu and Bing Yu

Green Chem., 2025, 27, 1820
DOI: 10.1039/D4GC06330A

Photoinduced ligand-to-metal charge transfer (LMCT) in organic synthesis: reaction modes and research advances

Yingying Yang, Xinxiang Huang and Yi Jin

Chem. Commun., 2025, 61, 1944
DOI: 10.1039/D4CC06099G

Visible-light induced direct C(sp3)–H functionalization: recent advances and future prospects

Jia-Lin Tu, Yining Zhu, Pengcheng Li and Binbin Huang

Org. Chem. Front., 2024, 11, 5278
DOI: 10.1039/D4QO01179A

Photoinduced decatungstate-catalyzed C(sp3)–H thioetherification by sulfinate salts

Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang and Wujiong Xia

Org. Biomol. Chem., 2024, 22, 3420
DOI: 10.1039/D4OB00394B

Iron‐Photocatalyzed Anti‐Markovnikov Hydrochlorination of Alkenes Based on Ligand‐to‐Metal Charge Transfer

Subrata Mukherjee, Ayako Kubota, Shintaro Kawamura and Mikiko Sodeoka

ChemistryEurope, 2025, 3
DOI: 10.1002/ceur.202500258

Photo‐enabled α‐C(sp3)‐H Functionalization of Sulfides

Peng Cheng, Jie Ding and Zhenda Tan

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202502638

Construction of C–P Bonds from Free Cyclobutanone Oximes and Chlorophosphines via Radical–Radical Coupling

LuLu Yang, Jiale Wu, Yang Li, Yuhai Tang, Jing Li and Silong Xu

Org. Lett., 2024, 26, 3208
DOI: 10.1021/acs.orglett.4c00799

Recent progress in metal-catalyzed C(sp³)-P bond formation

Jia-Lin Tu, Zhengjia Shen and Binbin Huang

Tetrahedron, 2024, 168, 134352
DOI: 10.1016/j.tet.2024.134352

Iron-Catalyzed Photochemical Defluorinative Functionalization of Polyfluorinated Aromatics

Ke Wang, Jia-Lin Tu, Ao-Men Hu, Mei Li, Lin Guo, Chao Yang and Wujiong Xia

Org. Lett., 2025, 27, 10049
DOI: 10.1021/acs.orglett.5c03114

Benzylic C(sp3)−H Phosphonylation via Dual Photo and Copper Catalysis

Heng‐Hui Li, Yuwen Liu and Søren Kramer

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420613

Photoinduced C−O Bond Formation through C−C Bond Cleavage of Alcohols by Suppressing Alcohol Oxidation

Qiang Wu and Peng Hu

Adv Synth Catal, 2024, 366, 1595
DOI: 10.1002/adsc.202301437

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

Xinghua Wang, Jing He, Ya-Nan Wang, Zhenyan Zhao, Kui Jiang, Wei Yang, Tao Zhang, Shiqi Jia, Kangbao Zhong, Linbin Niu and Yu Lan

Chem. Rev., 2024, 124, 10192
DOI: 10.1021/acs.chemrev.4c00188

Benzylic C(sp3)−H Phosphonylation via Dual Photo and Copper Catalysis

Heng‐Hui Li, Yuwen Liu and Søren Kramer

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420613

Direct Benzylic Phosphination of Toluenes Enabled by a Heterobimetallic LiN(SiMe3)2/Cs2SO4 System

Junyu Ma, Yan-En Wang, Yunfei Gao, Yuanyun Gu, Xingtao Chen, Yaqi Yuan, Dan Xiong and Jianyou Mao

Org. Lett., 2026, 28, 2248
DOI: 10.1021/acs.orglett.5c05125

Photocatalytic Applications of Chlorophosphines

Ming Zhang, Xi Chen, Lifen Hou, Peng Liu, Kai Sun, Xiao‐Lan Chen, Lingbo Qu and Bing Yu

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500304

A Nickel-Catalyzed Method for Csp3–P(III) Bond Formation: Efficient Transformation of Chlorophosphines with Alkyl Bromides

Qiu-Quan Pan, Juan Wang, Pei Zhang, Ya-Nan Ding, Ruchun Yang, Xian-Rong Song and Qiang Xiao

ACS Catal., 2026, 16, 4892
DOI: 10.1021/acscatal.5c08800

Generation of Carbamoyl Radicals and 3,4-Dihydroquinolin-2(1H)-ones Enabled by Iron Photoredox Catalysis

Yanhua Fu, Chao Zhang, Tao Cai and Gaofeng Feng

Synlett, 2025, 36, 166
DOI: 10.1055/s-0043-1763753

Palladium-Catalyzed Coupling of Aryl Chlorides with Secondary Phosphines to Construct Unsymmetrical Tertiary Phosphines

Yuxuan Xiao, Xun Yang, Haiyan Li, Ying Yin, Jiahui Du, Jing Liang, Wengui Duan and Lin Yu

Org. Lett., 2024, 26, 10564
DOI: 10.1021/acs.orglett.4c03951

Acidic Ionic Liquids‐Catalyzed Dehydration Cross‐Coupling Reaction of Allyl Alcohols with Phosphine Oxides

Li Guo, Yingning Qin, Feiyang Lan, Chaofan Han, Xinye Zhang, Xirui Ding and Feng Han

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202400811

Iron-Catalyzed Photochemical Synthesis of Sulfinamides from Aliphatic Hydrocarbons and Sulfinylamines

Guang-Da Xia, Run Li, Long Zhang, Yi Wei and Xiao-Qiang Hu

Org. Lett., 2024, 26, 3703
DOI: 10.1021/acs.orglett.4c00612

Photoinduced Ligand-to-Metal Charge Transfer Enables Iron-Catalyzed Site-Selective Oxime Ether Construction at C(sp3)–H Bonds of Silanes

Zhijun Hao, Xiushan Liu, Yunfei Cai and Huifeng Yue

Org. Lett., 2025, 27, 13786
DOI: 10.1021/acs.orglett.5c04227

Iron-Catalyzed Photoredox Alcohol α-C–H Alkylation and Tandem Intramolecular Cyclization: Facile Access to Multisubstituted 2,3-Dihydrofurans and γ-Butyrolactones

Jiajin Chen, Ziyu Gan, Yongqiang Zhang, Ziyang Chen, Shuyang Liu, Rongqi Cui, Zhiyan Xue, Haoxiang Sun, Lei Shi, Wen-Feng Jiang and Yunhe Jin

Org. Lett., 2024, 26, 5329
DOI: 10.1021/acs.orglett.4c01719

Selective Functionalization of White Phosphorus with Alkyl Bromides under Photocatalytic Conditions: A Chlorine-Free Protocol to Dialkyl and Trialkyl Phosphine Oxides

Jialiang Peng, An Wang, Yan Liu, Fushan Chen, Guo Tang and Yufen Zhao

Org. Lett., 2024, 26, 9316
DOI: 10.1021/acs.orglett.4c03494

Iron‐Catalyzed Reductive Alkylation of Imines via Ligand‐to‐Metal Charge Transfer

Serik Zhumagazy, Kuntal Pal and Magnus Rueping

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202501210

Photoinduced Deacylative Phosphorylation of Unstrained Ketones

Long Zhang, Jianing Yu, Xiaoyun Hu, Yuan Chen, Xiying Lai, Linghe Li, Yi Wei and Xiao-Qiang Hu

Org. Lett., 2026
DOI: 10.1021/acs.orglett.6c00848

Light-induced transition-metal-catalysed hydrogen atom transfer in organic transformations

Kallol Mukherjee, Ayala Ben David, Hasmik Nikoghosyan, Robert Hakobyan and Vladimir Gevorgyan

Nat Catal, 2025, 8, 1146
DOI: 10.1038/s41929-025-01431-5

Iron-Catalyzed Multicomponent C–H Alkylation of in Situ Generated Imines via Photoinduced Ligand-to-Metal Charge Transfer

Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Yining Zhu, Jiawen Yin, Lin Guo, Chao Yang and Wujiong Xia

Org. Lett., 2024, 26, 6347
DOI: 10.1021/acs.orglett.4c01986

Sustainable Minisci-Type Acylation of N-Heteroarenes via HAT Using Chlorine Radicals Generated by LMCT Excitation

Mingyang Wan, Jiatian Zhuo, Yuchen Pan, Min Zhou, Lin Ma and Min Zhang

J. Org. Chem., 2026, 91, 477
DOI: 10.1021/acs.joc.5c02539

Undirected Primary CH Functionalization of Alkanes via Hydrogen Atom Transfer

Jie Qin, Jingjing Xia, Yating Zhao and Wujiong Xia

Eur J Org Chem, 2026
DOI: 10.1002/ejoc.202500887